• Title/Summary/Keyword: Nano-crystal

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Response of a rocksalt crystal to electromagnetic wave modeled by a multiscale field theory

  • Lei, Yajie;Lee, James D.;Zeng, Xiaowei
    • Interaction and multiscale mechanics
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    • v.1 no.4
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    • pp.467-476
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    • 2008
  • In this work, a nano-size rocksalt crystal (magnesium oxide) is considered as a continuous collection of unit cells, while each unit cell consists of discrete atoms; and modeled by a multiscale concurrent atomic/continuum field theory. The response of the crystal to an electromagnetic (EM) wave is studied. Finite element analysis is performed by solving the governing equations of the multiscale theory. Due to the applied EM field, the inhomogeneous motions of discrete atoms in the polarizable crystal give rise to the change of microstructure and the polarization wave. The relation between the natural frequency of this system and the driving frequency of the applied EM field is found and discussed.

A Study on the Liquid Crystal Orientation Characteristics of the Inorganic NiOx Film with Aligned Nanopattern Using Imprinting Process (무기막 NiOx의 정렬 패턴 전사를 이용한 액정의 배향 특성 연구)

  • Oh, Byeong-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.5
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    • pp.357-360
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    • 2019
  • We demonstrate an alignment technology using an imprinting process on an inorganic NiOx film. The aligned nanopattern was fabricated on a silicon wafer by laser interference lithography. The aligned nano pattern was then imprinted onto the sol-gel driven NiOx film using an imprinting process at an annealing temperature of $150^{\circ}C$. After the imprinting process, parallel grooves had been formed on the NiOx film. Atomic force microscopy and water contact angle measurements were performed to confirm the parallel groove on the NiOx film. The grooves caused liquid crystal alignment through geometric restriction, similar to grooves formed by the rubbing process on polyimide. The liquid crystal cell exhibited a pretilt angle of $0.2^{\circ}$, which demonstrated homogeneous alignment.

Estimation of Phase Ratio for TiO2 Powders by XRD and XAS (XRD와 XAS에 의한 TiO2 분말의 상분율 결정)

  • Rha, Sa-Kyun;Lee, Youn Seoung
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.469-474
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    • 2012
  • The crystallinity and phase ratio of anatase to rutile in $TiO_2$ were estimated by x-ray diffraction (XRD) and x-ray absorption spectroscopy (XAS). Traditionally, the structural characterization of $TiO_2$ powders has been carried out by XRD techniques, which are comparatively easy in use and analysis. However, materials with amorphous phase, nano-sized or nano-structured crystallinities cannot be fully characterized by XRD because XRD analysis has a limit for abnormal contributions of the nano-crystal such as the surface contribution. From the comparison with the experimental and calculated Ti K-edge XAS spectra, we found the possibility of efficient estimation in the crystalinites and the phase ratio of anatase to rutile for nano-sized $TiO_2$ mixture.

Control the crystal size by varying concentrations of precursors for the planar perovskite solar cells

  • Xie, Lin;Hwang, Heewon;Kim, Minjung;Kim, Kyungkon
    • Rapid Communication in Photoscience
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    • v.4 no.4
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    • pp.79-81
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    • 2015
  • The influence of the grain size of the $CH_3NH_3PbI_3$ on the solar cell performance is investigated by controlling the ratio between $CH_3NH_3I$ and $PbI_2$ precursors. As the concentration of the precursors increased from 1.0M to 2.0M, the $CH_3NH_3PbI_3$ grain size increased from ~100nm to ~400nm. The solar cell utilizing the $CH_3NH_3PbI_3$ with large grain size shows improved photocurrent compared to the solar cell utilizing $CH_3NH_3PbI_3$ with small grain size, which is ascribed to the reduced recombination at the boundaries of grains.

Origin of Optical Bounce during switching in the FFS Mode using a LC with Positive Dielectric Anisotropy (유전율이 양인 액정을 이용한 FFS모드의 스위칭시 Optical Bounce 발생 원인에 관한 연구)

  • Ha, Kyung-Su;Jung, Jun-Ho;Kim, Min-Su;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04a
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    • pp.63-64
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    • 2009
  • Optical bounce during switching in the fringe field switching (FFS) mode using a liquid crystal (LC) with positive dielectric anisotropy has been observed. According to the analysis, it occurs at two positions which are center and edge of the pixel electrode, which decreases decaying response time. The former is major and mainly associated with increase in twist angle instantaneously during switching off resulted from decrease in tilt angle near by LC molecules at center. This paper discusses the origin of such optical bounces.

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Study on Electro-opt ic Characteristics in the Optically Compensated Splay Cell with UV-curable Reactive Mesogen

  • Kim, Seong-Su;Jeon, Eun-Jeong;Lee, Myong-Hoon;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.327-329
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    • 2008
  • We have studied the optically compensated splay (OCS) mode using reactive mesogen monomer to reduce critical voltage, setting voltage and phase transition time from initial bend to splay state. The high pretilt angle from vertical alignment was formed through the polymerization of UV curable RM monomer at the surfaces. In this way, orientation of the LC with OCS can be achieved without setting voltage.

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Technology for Efficiency Enhancement of Crystalline Si Solar Cell using Nano Imprint Process (나노 임프린트 공정을 이용한 결정형 실리콘 태양전지 효율 향상 기술)

  • Cho, Young Tae;Jung, Yoon Gyo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.5
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    • pp.30-35
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    • 2013
  • In order to increase cell efficiency in crystalline silicon solar cell, reduction of light reflection is one of the essential problem. Until now silicon wafer was textured by wet etching process which has random patterns along crystal orientation. In this study, high aspect ratio patterns are manufactured by nano imprint process and reflectance could be minimized under 1%. After that, screen printed solar cell was fabricated on the textured wafer and I-V characteristics was measured by solar simulator. Consequently cell efficiency of solar cell fabricated using the wafer textured by nano imprint process increased 1.15% than reference solar cell textured by wet etching. Internal quantum efficiency was increased in the range of IR wave length but decreased in the UV wavelength. In spite of improved result, optimization between nano imprinted pattern and solar cell process should be followed.

Simple Autocorrelation Measurement by Using a GaP Photoconductive Detector

  • Shin, Seong-Il;Lim, Yong-Sik
    • Journal of the Optical Society of Korea
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    • v.20 no.3
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    • pp.435-440
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    • 2016
  • We developed a simple and real-time readout autocorrelator for several tens and sub-10fs pulses, based on the two photon absorption phenomena of a commercial GaP photodetector including a transimpedance amplifier. With a suitable gain adjustment, we demonstrated that the interferometric autocorrelation for sub-nJ pulses delivered as a high output voltage as to resolve all fringes in an autocorrelation trace with features of low noise and a low offset voltage. By fitting the measured quadratic power dependence of output voltages, we obtained the quantum efficiency of TPA for the GaP detector comparable with those of a GaAsP diode and an SHG with a thin BBO crystal. The autocorrelator of a TPA based GaP photodetector is highly suitable for sensitively measuring a few cycle pulses with a broad spectral distribution from 600 nm to 1100 nm.

The Injection of PDLC Solution Mixture in a Reduced Pressure

  • Kim, Kang-Pil;Yang, Kee-Jeong;Kim, Dae-Hwan;Choi, Byeong-Dae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.524-526
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    • 2007
  • Polymer dispersed liquid crystal (PDLC) films consist of micro-droplets of liquid crystals dispersed in a polymer matrix. To make wide area PDLC filled devices, it is necessary to develop reliable method of vacuum injection of PDLC solution instead of the capillary injection. However, well-known 2-ethylhexylacrylate (EHA), main element of a prepolymer, exhibits the volatility problems, when the PDLC solution is placed under the low pressure. In this study, we developed the vacuum injection process to fill a wide area cell. Experimental results indicate that the $V_{90}$(turn-on voltage) of the PDLC cell made by a vacuum injection method are lower than that of the PDLC cell made by a capillary injection method.

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Lead bromide crystal growth from the melt and characterization: the effects of nonlinear thermal boundary conditions on convection during physical vapor crystal growth of mercurous bromide

  • Geug-Tae Kim;Moo Hyun Kwon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.4
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    • pp.160-168
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    • 2004
  • We investigate the effects of solutal convection on the crystal growth rate in a horizontal configuration for diffusive-convection conditions and purely diffusion conditions achievable in a low gravity environment for a nonlinear thermal gradient. It is concluded that the solutally-driven convection due to the disparity in the molecular weights of the component A $(Hg_2Br_2)$ and B (CO) is stronger than thermally-driven convection for both the nonlinear and the linear thermal profiles, corresponding to $Gr_t= 8.5{\times}10^3,\; Gr_s = 1.05{\times}10^5$. For both solutal and thermal convection processes, the growth rates for the linear thermal profile (conducting walls) are greater than for the nonlinear case. With the temperature humps, there are found to be observed in undersaturation for diffusive-convection processes ranging from $D_{AB}$ = 0.087 to 0.87. For the vertical configurations, the diffusion mode is so much dominated that the growth rate and interfacial distribution is nearly regardless of the gravitational accelerations. Also, the diffusion mode is predominant over the convection for the gravity levels less than 0.1 $g_0$ for the horizontally oriented configuration.