• Title/Summary/Keyword: Nano-Sized Particles

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A Study on the PTC Thermistor Characteristics of Polyethylene and Polyethylene Copolymer Composite Systems in Melt and Solution Manufacturing Method (용액 및 용융 가공방법에 따른 PE 및 PE 공중합물의 PTC 서미스터 특성 연구)

  • 김재철;박기헌;남재도
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.812-820
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    • 2002
  • The positive temperature coefficient (PTC) characteristics of polymer composites were investigated with the nano-sized carbon black particles using solution tasting and melt compounding methods. The polymeric PTC composites should the electrical threshold at 35 wt% for the melt compounding method and 40 wt% for the solution casting method. The ethylene vinylacetate copolymer (EVA) composite showed a gradual increase of resistance as a function of temperature and showed a maximum at the polymer molting point. The resistance of the high-density polythylene (HDPE) composite remains unchanged with temperature but started to Increase sharply near the melting point of HDPE and showed a maximum resistance at the melting point of HDPE. The dispersion of nano-sized carbon black particles was investigated by scanning electron microscopy (SEM) and low resistance after electrical threshold, and both methods exhibited a well dispersed morphology. When the electric current was applied to the PTC composites, the resistance started increasing at the curie temperature and further increased until the trip temperature was roached. Then the resistance remained stable over the trip temperature. The secondary increase started at T$\sub$m/ of matrix polymer and kept increasing up to the trip temperature.

Gas Sensing Characteristics of Nano Sized SnO2 Sensors for Various Co and Ni Concentration (Co, Ni 농도 변화에 따른 나노 SnO2 센서의 감응 특성)

  • Lee, Ji-Young;Yu, Yoon-Sic;Yu, Il
    • Korean Journal of Materials Research
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    • v.21 no.10
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    • pp.546-549
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    • 2011
  • Nano-sized $SnO_2$ thick films were prepared by a screen-printing method onto $Al_2O_3$ substrates. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box as a function of the detection gas. The nano-sized $SnO_2$ thick film sensors were treated in a $N_2$ atmosphere. The structural properties of the nano $SnO_2$with a rutile structure according to XRD showed a (110) dominant $SnO_2$ peak. The particle size of $SnO_2$:Ni nano powders at Ni 8 wt% was about 45 nm, and the $SnO_2$ particles were found to contain many pores according to the SEM analysis. The sensitivity of the nano $SnO_2$-based sensors was measured for 5 ppm $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in the target gases. The results showed that the best sensitivity of $SnO_2$:Ni and $SnO_2$:Co sensors for $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature was observed in $SnO_2$:Ni sensors doped with 8 wt% Ni. The response time of the $SnO_2$:Ni gas sensors was 10 seconds and recovery time was 15 seconds for the $CH_4$ and $CH_3CH_2CH_3$ gases.

Comparative study on the effects of micro- and nano-sized zinc oxide supplementation on zinc-deficient mice

  • Ja-Seon Yoon;Sang Yoon Nam;Beom Jun Lee;Hyun Jik Lee
    • Journal of Veterinary Science
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    • v.24 no.1
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    • pp.3.1-3.13
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    • 2023
  • Background: Zinc (Zn) is an essential cofactor for physiological homeostasis in the body. Zn oxide (ZnO), an inorganic compound that supplies Zn, exists in various sizes, and its bioavailability may vary depending on the size in vivo. However, comparative studies on the nutritional effects of micro-sized ZnO (M-ZnO) and nano-sized ZnO (N-ZnO) supplementation on Zn deficiency (ZnD) animal models have not been reported. Objectives: This study investigated the nutritional bioavailability of N-ZnO and M-ZnO particles in dietary-induced ZnD mice. Methods: Animals were divided into six experimental groups: normal group, ZnD control group, and four ZnO treatment groups (Nano-Low, Nano-High, Micro-Low, and MicroHigh). After ZnD induction, N-ZnO or M-ZnO was administered orally every day for 4 weeks. Results: ZnD-associated clinical signs almost disappeared 7 days after N-ZnO or M-ZnO administration. Serum Zn concentrations were higher in the Nano-High group than in the ZnD and M-ZnO groups on day 7 of ZnO treatment. In the liver and testis, Nano-Low and Nano-High groups showed significantly higher Zn concentrations than the other groups after 14-day treatment. ZnO supplementation increased Mt-1 mRNA expression in the liver and testis and Mt-2 mRNA expression in the liver. Based on hematoxylin-and-eosin staining results, N-ZnO supplementation alleviated histological damage induced by ZnD in the testis and liver. Conclusions: This study suggested that N-ZnO can be utilized faster than M-ZnO for nutritional restoration at the early stage of ZnD condition and presented Mt-1 as an indicator of Zn status in the serum, liver, and testis.

CNT and CNF reinforced carbon fiber hybrid composites by electrophoresis deposition (전기영동법에 의한 탄소나노튜브 및 탄소나노섬유 강화 탄소섬유 하이브리드 복합재료)

  • Choi, O-Young;Lee, Won-Oh;Lee, Sang-Bok;Yi, Jin-Woo;Kim, Jin-Bong;Choe, Hyeon-Seong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.7-12
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    • 2010
  • In order to increase the electrical conductivity and the mechanical properties of carbon fabric composites, multi-walled carbon nanotubes (MWCNTs) and carbon nanofibers (CNFs) were deposited on carbon fabrics by anodic and cathodic electrophoretic deposition (EPD) processes. In the cathodic EPD, carbon nano-particles and nano-sized Cu particles were simultaneously deposited on the carbon fabric, which gave a synergetic effect on the enhancement of properties as well as the degree of deposition. The hybridization of carbon nano-particles and micron-sized carbon fiber significantly improved the through-the-thickness electrical conductivity. In addition, both MWCNTs and CNFs were deposited onto the carbon fabric for multi-scale hybrid composites. Multi-scale deposition improved the through-the-thickness electrical conductivity, compared to the deposition of either MWCNTs or CNFs.

Rheological Properties Investigation of Kerosene gels with Nano-Aluminum Particles (알루미늄 나노입자 첨가량에 따른 케로신 젤의 유변학적 특성 변화)

  • Kim, Sijin;Han, Seongjoo;Kim, Jinkon;Kang, Teagon;Moon, Heejang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.469-473
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    • 2017
  • In this study, the rheological characteristics of kerosene based gel propellants were investigated. For the gelling agent, Thixatrol$^{(R)}$ has been used with 100 nm nano-sized aluminium particle addition. Three gellant contents of 2.5 wt%, 5 wt% and 7.5 wt% kerosene gels were first investigated where aluminium particles contents of 10 wt% and 20 wt% were added to 7.5 wt% gellant case. The viscosities of each sample measured by rotational rheometer show that the viscosity augments as gellant or aluminium content increases while the 20 wt% aluminum content resulted in failure of measurement due to the agglomerations of aluminum particles.

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Rheological Investigation of Aluminized Paraffin Wax Fuel on Particle Size and Contents (파라핀/알루미늄 연료의 알루미늄 입자크기 및 함유비 변화에 따른 유변학적 특성)

  • Ryu, Sunghoon;Han, Seongjoo;Moon, Heejang;Kim, Jinkon;Kim, Junhyung;Ko, Seungwon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.2
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    • pp.11-19
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    • 2018
  • Viscosity measurements were conducted to investigate the rheological characteristics of aluminized paraffin wax fuel. To identify the effect of size and contents of the aluminum particles on the variation of viscosity, samples of nano- and micro- sized aluminum particles with an average particle size of 100 nm and $8{\mu}m$ were prepared and measured using a rheometer. The observed viscosity increment patterns of the nano- and micro-sized particles were vey different, and particularly above 10 wt%, where a relatively low overall regression rate is expected for nano- content fuel. It is possible that this phenomenon could cause the reduced entrainment regression rate.

The Concepts of Nanotoxicology and Risk Assessment of the Nanoparticles (나노 독성의 개념 및 나노입자에 대한 위해성 평가의 필요성)

  • Maeng, Seung-Hee;Yu, Il-Je
    • Toxicological Research
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    • v.21 no.2
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    • pp.87-98
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    • 2005
  • Human exposure to nano-sized particles (NSP) has increased over the last century with anthropogenic sources, and the rapid development of nanotechnology becomes an another source of such exposure. Information regarding the safety of nanotechnology and its product, nanoparticles, is urgently needed when assuming exposure through inhalation, oral intake, and penetration across skin is ever increasing as growing nanotechnology rapidly. The recent advancement of biokinetic studies with NSP and newer epidemiologic and toxicologic studies with ultrafine particles can be the basis for the nanotoxicology. Some concepts of nanotoxicology can be known from the results of these results. Specific small size of NSP, when inhaled, facilitates deposition by difusional mechanism in all regions of the respiratory tract and uptake into cells, ranscytosis across epithelial and endothelial cells into the blood and lymph circulation to reach target sites. Translocation along axons and dendrites of neuron makes an access to CNS and ganglia. These biokinetics are dependent on NSP surface chemistry. Risk assessments of NSP include appropriate and relevant doses/concentration selections, the increase effects in the organism and the benefits of possible desirable effects. An interdisciplinary team approach is desirable for nanotoxicology research and an appropriate risk assessment.

Antimicrobial Activity of Fabrics Treated with Colloidal Silver Solutions Made by Electrolysis and Reduction (제조 방법이 다른 은 콜로이드 용액 처리 직물의 항균효과)

  • Chung Haewon;Kim Boyeon;Yang Heeju
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.6
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    • pp.805-813
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    • 2005
  • In recent years, greatly increased incidences of diseases made people more concerned about their hygienic environment. Since clothes are the closest environment to man, many methods have beef proposed to impart antimicrobial properties to the textiles. Benefits associated with incorporating antimicrobial properties in textiles include protection to the wearer from microbiological attack, and prevention of odor from perspiration. Silver has been known to kill 650 different disease organisms, however, nano-sized silver particles are known as skin friendly and does not cause skin irritation. In this study, we have examined the antimicrobial effects of cotton or polyester fabric, on which nano-sized silver particles were treated. Colloidal silver solution made by electrolysis of $99.9\%$ silver stick was more effective than that by reduction of $AgNO_3.\;0.7\%$ concentration of colloidal silver solution by electrolysis is helpful to give reduction of $99.9\%$ S. aureus and K. pneumoniae on a cotton fabric without the decrease of whiteness. Since the structures of fiber and fabric effect on their antimicrobial property, PET filament fabric didn't have sufficient antimicrobial properly. The fabrics treated with up to $5\%$ colloidal silver solution didn't have the properly of antistatic and electromagnetic shield.

Processing of Nano-Sized Metal Alloy Dispersed $Al_2O_3$ Nanocomposites

  • Oh, Sung-Tag;Seok Namkung;Lee, Jai-Sung;Kim, Hyoung-Seop;Tohru Sekino
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.157-162
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    • 2001
  • An optimum route to fabricate the ferrous alloy dispersed $Al_2O_3$ nanocomposites such as $Al_2O_3$/Fe-Ni and $Al_2O_3$/Fe-Co with sound microstructure and desired properties was investigated. The composites were fabricated by the sintering of powder mixtures of $Al_2O_3$ and nano-sized ferrous alloy, in which the alloy was prepared by solution-chemistry routes using metal nitrates powders and a subsequent hydorgen reduction process. Microstructural observation of reduced powder mixture revealed that the Fe-Ni or Fe-Co alloy particles of about 20 nm in size homogeneously surrounded $Al_2O_3$, forming nanocomposite powder. The sintered $Al_2O_3$/Fe-Ni composite showed the formation of Fe$Al_2O_4$ phase, while the reaction phases were not observed in $Al_2O_3$/Fe-Co composite. Hot-pressed $Al_2O_3$/Fe-Ni composite showed improved mechanical properties and magnetic response. The properties are discussed in terms of microstructural characteristics such as the distribution and size of alloy particles.

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