• Title/Summary/Keyword: Nano-Composites

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Realistic adsorption behaviors of the copper onto the functionalized CNTs

  • Park, Mi-Na;Kim, Byeong-Hyeon;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.476-476
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    • 2011
  • Introduction of CNTs into a metal matrix has been considered to improve the mechanical properties of the metal matrix. However, the binding energy between metals and pristine CNTs wall is known to be so small that the interfacial slip between CNTs and the matrix occurs at a relatively low external stress. The interfacial strength between CNT and metal matrix is thus one of the key factors for successful development of the CNT/metal composites. Defective or functionalized CNT has been considered to enhance the interfacial strength of nanocomposites. In the present work, we design the various realistic hybrid structures of the single wall CNT/Cu complexes and characterize the interaction between single wall CNTs and Cu nano-particle and Cu13 cluster using first principle calculations. The characteristics of functionalized CNTs with various surface functional groups, such as -COOH, -OH, and -O interacting with Cu are investigated. We found that the binding energy can be enhanced by the surface functional group including oxygen since the oxygen atom can mediate and reinforce the interaction between carbon and Cu. These results strongly support the recent experimental work which suggested the oxygen on the interface playing an important role in the excellent mechanical properties of the CNT/Cu composite.

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A Study on Finite Element Analysis and Aging Test for Automotive Grommet (자동차 그로멧의 유한요소해석 및 노화시험에 대한 연구)

  • Lee, Seong-Beom;Yeom, Sang-Hoon;Han, Chang-Yong;Woo, Chang-Su
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.201-209
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    • 2012
  • Grommet is one of the Automotive rubber components and is made from EPDM(Ethylene Propylene Diene monomer M-class) rubber and the nonlinear hyperelastic material properties of rubber are important to predict the behavior of rubber product. In this study, the stable stress-strain relations were obtained from the uni-axial tension test and the equi-biaxial tension test. Finite element analysis for grommet was carried out and heat aging test for the lifetime prediction of grommet was introduced.

Analysis of Mechanical Characteristics of Polymer Sandwich Panels Containing Injection Molded and 3D Printed Pyramidal Kagome Cores

  • Yang, K.M.;Park, J.H.;Choi, T.G.;Hwang, J.S.;Yang, D.Y.;Lyu, M.-Y.
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.275-279
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    • 2016
  • Additive manufacturing or 3D printing is a new manufacturing process and its application is getting growth. However, the product qualities such as mechanical strength, dimensional accuracy, and surface quality are low compared with conventional manufacturing process such as molding and machining. In this study not only mechanical characteristics of polymer sandwich panel having three dimensional core layer but also mechanical characteristics of core layer itself were analyzed. The shape of three dimensional core layer was pyramidal kagome structure. This core layer was fabricated by two different methods, injection molding with PP resin and material jetting type 3D printing with acrylic photo curable resin. The material for face sheets in the polymer sandwich panel was PP. Maximum load, stiffness, and elongation at break were examined for core layers fabricated by two different methods and also assembled polymer sandwich panels. 3D printed core showed brittle behavior, but the brittleness decreased in polymer sandwich panel containing 3D printed core. The availability of 3D printed article for the three dimensional core layer of polymer sandwich panel was verified.

Multiphase Simulation of Rubber and Air in the Cavity of Mold

  • Woo, Jeong Woo;Yang, Kyung Mi;Lyu, Min-Young
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.263-268
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    • 2016
  • In the polymer shaping process that uses molds, the quality of the molded products is determined not only by the flow of the (molten) polymer but also by the air venting in the cavity. Inadequate air venting in the cavity can cause defects in the product, such as voids, short shot, or black streaks. As it is critical to consider the location and size of the vents for proper venting of the air in the cavity, a method that predicts the flow of air and material is required. The venting of air by the flow of rubber inside the cavity was simulated by using a multi-phase computational fluid dynamics method. Through computer simulation, the interface of rubber and air over time was predicted. Then, the velocity and pressure distribution of the venting air were observed. Our research proposes a fundamental method for analyzing the multi-phase flow of polymer materials and air inside the cavity of a mold.

Rubber Material Development and Performance Evaluation of Diaphragm Seal for Steam Generator Nozzle Dam

  • Woo, Chang-Su;Song, Chi-Sung;Lee, Han-Chil;Kwon, Jin-Wook
    • Elastomers and Composites
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    • v.55 no.3
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    • pp.222-228
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    • 2020
  • Rubber materials, used in nuclear power plants, need high heat-oxidation resistance to curing or cracking under a heat aging environment. This is because they are applied to environments with high temperature, high humidity, and radiation exposure. Nuclear radiation causes additional hardening or degradation, therefore, rubber materials need radiation resistance that satisfies the general and any accidental conditions produced in the power plant. Therefore, in this study, we developed a rubber material with excellent heat and radiation resistance for the diaphragm seal of a nuclear steam generator nozzle dam. The rubber material greatly improved the reliability of the steam generator nozzle dam. In addition, 30 inch and 42 inch diaphragm seals were manufactured using the developed rubber material. A nozzle dam was installed in a nuclear power plant and tested under the same conditions as a steam generator to evaluate safety and reliability. In the future, the performance and safety of diaphragm seals developed through field tests of nuclear power plants will be evaluated and applied to currently operating and new nuclear power plants.

Manufacturing and Characterization of Red algae fiber/Polypropylene Biocomposites (홍조류섬유보강 폴리프로필렌 바이오복합재료의 제조 및 특성 분석)

  • Lee, Min-Woo;Seo, Yung-Bum;Han, Seong-Ok
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.04a
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    • pp.178-182
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    • 2008
  • The bleached red algae fiber(BRAF) showed very similar crystallinity to the cellulose, furthermore, it has higher thermal decomposition temperature than that of the microcrystalline cellulose(MCC). Polypropylene biocomposites reinforced with BRAF have been fabricated with various BRAF contents by compression molding method and their mechanical and thermomechanical properties have been studied. The mechanical strength as tensile, impact and flexural modulus of BRAF/PP biocomposites were gradually improved with increasing the BRAF content, and thermal property which against the thermal expansion was markdly improved, especially. These results are compared with chopped non-woody fibers as Henequen or Kenaf, BRAF was more effective for fabrication of biocomposites reinforced small-sized fibers. The red algae fiber reinforced biocomposites has the applicability such as electronics, biodegradable products and small-structure composites.

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Effect of Blade Materials on Wear Behaviors of Styrene-Butadiene Rubber and Butadiene Rubber

  • Lee, Gi-Bbeum;Shin, Beomsu;Han, Eunjung;Kang, Dawon;An, Dae Joon;Nah, Changwoon
    • Elastomers and Composites
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    • v.56 no.3
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    • pp.172-178
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    • 2021
  • The wear behavior of styrene-butadiene rubber (SBR) and butadiene rubber (BR) was investigated using a blade-type abrader with a steel blade (SB), Ti-coated tungsten carbide blade (TiB), or zirconia blade (ZB). The wear rate of SBR against SB and TiB decreased with increasing number of revolutions because of the blunting of the blades during wear. However, the wear rate of SBR against ZB remained nearly constant with little blade blunting. Generally, the wear rate of BR was largely unaffected by the blade material used for abrasion. The wear rate and frictional coefficient of SBR were found to be higher than those of BR at similar levels of frictional energy input. A power-law relationship was found between the wear rate and frictional energy input during abrasion. A well-known Schallamach pattern was observed for SBR, while a much finer pattern was observed for BR. The blade material affects the wear rate of the rubbers because the macromolecular free radicals and blade tend to undergo mechano-chemical reactions. The inorganic ZB was found to be the most inert for such a mechanism.

Free vibration analysis of thick cylindrical MEE composite shells reinforced CNTs with temperature-dependent properties resting on viscoelastic foundation

  • Mohammadimehr, Mehdi;Arshid, Ehsan;Alhosseini, Seyed Mohammad Amin Rasti;Amir, Saeed;Arani, Mohammad Reza Ghorbanpour
    • Structural Engineering and Mechanics
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    • v.70 no.6
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    • pp.683-702
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    • 2019
  • The present study aims to analyze the magneto-electro-elastic (MEE) vibration of a functionally graded carbon nanotubes reinforced composites (FG-CNTRC) cylindrical shell. Electro-magnetic loads are applied to the structure and it is located on an elastic foundation which is simulated by visco-Pasternak type. The properties of the nano-composite shell are assumed to be varied by temperature changes. The third-order shear deformation shells theory is used to describe the displacement components and Hamilton's principle is employed to derive the motion differential equations. To obtain the results, Navier's method is used as an analytical solution for simply supported boundary condition and the effect of different parameters such as temperature variations, orientation angle, volume fraction of CNTs, different types of elastic foundation and other prominent parameters on the natural frequencies of the structure are considered and discussed in details. Design more functional structures subjected to multi-physical fields is of applications of this study results.

Analytical solution for analyzing initial curvature effect on vibrational behavior of PM beams integrated with FGP layers based on trigonometric theories

  • Mousavi, S. Behnam;Amir, Saeed;Jafari, Akbar;Arshid, Ehsan
    • Advances in nano research
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    • v.10 no.3
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    • pp.235-251
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    • 2021
  • In the current study, the free vibrational behavior of a Porous Micro (PM) beam which is integrated with Functionally Graded Piezoelectric (FGP) layers with initial curvature is considered based on the two trigonometric shear deformation theories namely SSDBT and Tan-SDBT. The structure's mechanical properties are varied through its thicknesses following the given functions. The curved microbeam is exposed to electro-mechanical preload and also is rested on a Pasternak type of elastic foundation. Hamilton's principle is used to extract the motion equations and the MCST is used to capture the size effect. Navier's solution method is selected as an analytical method to solve the motion equations for a simply supported ends case and by validating the results for a simpler state with previously published works, effects of different important parameters on the behavior of the structure are considered. It is found that although increasing the porosity reduces the natural frequency, but enhancing the volume fraction of CNTs increasing it. Also, by increasing the central angle of the curved beam the vibrations of the structure increases. Designing and manufacturing more efficient smart structures such as sensors and actuators are of the aims of this study.

Geometrically nonlinear thermo-mechanical bending analysis of deep cylindrical composite panels reinforced by functionally graded CNTs

  • Salami, Sattar Jedari;Boroujerdy, Mostafa Sabzikar;Bazzaz, Ehsan
    • Advances in nano research
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    • v.10 no.4
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    • pp.385-395
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    • 2021
  • This research concentrates on the effects of distributions and volume fractions of carbon nanotubes (CNT) on the nonlinear bending behavior of deep cylindrical panels reinforced by functionally graded carbon nanotubes under thermo-mechanical loading, hitherto not reported in the literature. Assuming the effects of shear deformation and moderately high value of the radius-to-side ratio (R/a), based on the first-order shear deformation theory (FSDT) and von Karman type of geometric nonlinearity, the governing system of equations is obtained. The analytical solution of field equations is carried out using the Ritz method together with the Newton-Raphson iterative scheme. The effects of radius-to-side ratio, temperature change, and boundary conditions on the nonlinear response of the functionally graded carbon nanotubes reinforced composite deep cylindrical panel (FG-CNTRC) are investigated. It is concluded that, among the five possible distribution patterns of CNT, FG-V CNTRC deep cylindrical panel is strongest with the highest bending moment and followed by UD, X, O, and Ʌ-ones. Also, considering the present deep cylindrical panel formulation increases the accuracy of the results. Hence, according to the noticeable amount of R/a in FG-CNTRC cylindrical panels, it is mandatory to apply strain-displacement relations of deep cylindrical panels for bending analysis of FG-CNTRC which certainly is desirable for industrial application.