• Title/Summary/Keyword: Nano template

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Method to control the Sizes of the Nanopatterns Using Block Copolymer (블록 공중합체를 이용한 나노패턴의 크기제어방법)

  • Kang, Gil-Bum;Kim, Seong-Il;Han, Il-Ki
    • Journal of the Korean Vacuum Society
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    • v.16 no.5
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    • pp.366-370
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    • 2007
  • Nano-scopic holes which are distributed densely and uniformly were fabricated on $SiO_2$ surface. Self-assembling resists were used to produce a layer of uniformly distributed parallel poly methyl methacrylate (PMMA) cylinders in a polystyrene (PS) matrix. The PMMA cylinders were degraded and removed by acetic acid rinsing. Subsequently, PS nanotemplates were fabricated. The patterned holes of PS template were approximately $8{\sim}30\;nm$ wide, 40 nm deep, and 60 nm apart. The porous PS template was used as a dry etching mask to transfer the pattern of PS template into the silicon oxide thin film during reactive ion etching (RIE) process. The sizes of the patterned holes on $SiO_2$ layer were $9{\sim}33\;nm$. After pattern transfer by RIE, uniformly distributed holes of which size were in the range of $6{\sim}22\;nm$ were fabricated on Si substrate. Sizes of the patterned holes were controllable by PMMA molecular weight.

Phase Transitions of Template Synthesized $PbTiO_{3}$ Nano-structures (형판 합성된 $PbTiO_{3}$ 나노-구조의 상전이)

  • Chang, Ki-Seog;Bu, Sang-Don;Hernandez Bernadez A.;Fisher Ellen R.;Dorbout Peter K.
    • Korean Journal of Crystallography
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    • v.16 no.2
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    • pp.128-137
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    • 2005
  • We report on the phase transitions of the perovskite nanostructures made by sol-gel template synthesis. The lead titanate ($PbTiO_{3}$) nanostructures were prepared with a chelate sol-gel of titanium tetrabutoxide ($Ti(O^{i}Pr){4}$) and lead acetate ($Pb(OAc)_{2}-3H_{2}O$). $Whatman^{\circledr}$ anodisc membranes (with about 200 nm pore size) served as the template. The template was dipped into the sol, allowed to air dry, and then calcined at $650^{\circ}C$. We have characterized the temperatures of the phase transitions in the $PbTiO_{3}$ nano-structures using DSC, DTA, and second harmonic generation (SHG).

The study on properties of AAO(Anodic Aluminum Oxide) structures using nano indentation (나노 인텐테이션을 이용한 산화알루미늄(AAO, Anodic Aluminum Oxide)구조물의 물성치에 대한 연구)

  • Ko, Seung-Hyun;Lee, Dae-Woong;Jee, Sang-Eun;Park, Hyun-Chul;Lee, Kun-Hong;Hwang, Woong-Bong
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.144-149
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    • 2004
  • Porous anodic alumina has been used widely for corrosion protection of aluminum surfaces or as dielectric material in micro-electronics applications. It exhibits a homogeneous morphology of parallel pores which can easily be controlled between 10 and 400nm. It has been applied as a template for fabrication of the nanometerscale composite. In this study, mechanical properties of the AAO structures are measured by the nano indentation method. Nano indentation technique is one of the most effective method to measure the mechanical properties of nano-structures. Basically, hardness and elastic modulus can be obtained by the nano-indentation. Using the nano-indentation method, we investigated the mechanical properties of the AAO structure with different size of nano-holes. In results, we find the hole effect that changes the mechanical properties as size of nano hole.

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Fabrication of high ordered nano-sphere array on curved substrate by nanoimprint lithography

  • Hong, Seong-Hun;Bae, Byeong-Ju;Lee, Heon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.127-127
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    • 2008
  • The replica of highly ordered nano-sphere array patterns were fabricated using hot embossing method. The polymer replica was coated with silcon dioxide layer and self-assembled monolayer. Using UV nanoimprint lithography with the template, highly ordered nano-sphere array patterns were clearly fabricated on curved substrate.

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Preparation and Characterization of Mesoporous Ni Film Made by Electroplating Method (전착법을 이용한 메조포러스 니켈 필름의 제조와 특성 분석)

  • Lee, Ji-Hoon;Baik, Young-Nam;Kim, Young-Seok;Shin, Seung-Han
    • Journal of Surface Science and Engineering
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    • v.40 no.1
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    • pp.16-22
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    • 2007
  • Recently, mesoporous metallic materials are becoming more and more important in various applications like catalysts, electrochemical detectors, batteries, and fuel cells because of their high surface area. Among the various methods for manufacturing mesoporous structure, surfactant templating method followed by electroplating has been tried in this study. A mesoporous metallic film was prepared by electrodeposition from electroplating solution mixed with surfactant template. Nonionic type lyotropic liquid crystalline surfactant, Brij56, and nickel acetate based solution were selected as a template material and electroplating solution, respectively. To determine the content of surfactant forming a hexagonal column structure, the phase diagram of electroplating solution and surfactant mixture has been exploited by polarized optical microscopy equipped with heating and cooling stage. Nickel films were electroplated on Cu foil by stepwise potential input method to alleviate the concentration polarization occurred during the electroplating process. TEM and XRD analyses were performed to characterize the size and shape of mesostructures in manufactured nickel films, and electrochemical characterization was also carried out using cyclic voltammetry.

Manufacture of High-Aspect-Ratio Polymer Nano-Hair Arrays by UV Nano Embossing Process (UV 나노 엠보싱 공정을 이용한 고종횡비 고분자 나노 섬모 어레이 제작)

  • Kim Dong-Sung;Lee Hyun-Sup;Lee Jung-Hyun;Lee Kun-Hong;Kwon Tai-Hun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.7 s.250
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    • pp.773-778
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    • 2006
  • High-aspect-ratio nano-hair or nano-pillar arrays have great potential in a variety of applications. In this study, we present a simple and cost-effective replication method of high-aspect-ratio polymer nano-hair arrays. Highly ordered nano-porous AAO (anodic aluminum oxide) template was utilized as a reusable nano-mold insert. The AAO nano-mold insert fabricated by the two-step anodization process in this study had close- packed straight nano-pores, which enabled us to replicate densely arranged nano-hairs. The diameter, depth and pore spacing of the nano-pores in the fabricated AAO nano-mold insert were about 200nm, $1{\mu}m$ and 450nm, respectively. For the replication of polymer nano-hair arrays, a UV nano embossing process was applied as a mass production method. The UV nano embossing machine was developed by our group for the purpose of replicating nano-structures by means of non-transparent nano-mold inserts. Densely arranged high-aspect-ratio nano-hair arrays have been successfully manufactured by means of the UV nano embossing process with the AAO nano-mold insert under the optimum processing condition.

The Study on Properties of AAO(Anodic Aluminum Oxide) Structures with Hole Effect (Hole effect를 고려한 AAO(Anodic Aluminum Oxide) 구조물의 물성치에 대한 연구)

  • 고성현;이대웅;지상은;박현철;이건홍;황운봉
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.4
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    • pp.186-193
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    • 2004
  • Porous anodic alumina has been used widely for corrosion protection of aluminum surfaces or as dielectric material in micro-electronics applications. It exhibits a homogeneous morphology of parallel pores which can easily be controlled between 10 and 400nm. It has been applied as a template for fabrication of the nanometer-scale composite. In this study, mechanical properties of the AAO structures are measured by the nano indentation method. Nano indentation technique is one of the most effective methods to measure the mechanical properties of nano-structures. Basically, hardness and elastic modulus can be obtained by the nano-indentation. Using the nano-indentation method, we investigated the mechanical properties of the AAO structure with different size of nano-holes. In results, we find the hole effect that changes the mechanical properties as size of nano hole.