• Title/Summary/Keyword: Nano size

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Photocatalytic Property of Nano-Structured TiO$_2$ Thermal Splayed Coating - Part I: TiO$_2$ Coating - (나노구조 TiO$_2$ 용사코팅의 미세조직 제어 공정기술 개발과 광촉매 특성평가 - Part I: TiO$_2$코팅 -)

  • 이창훈;최한신;이창희;김형준;신동우
    • Journal of Welding and Joining
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    • v.21 no.4
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    • pp.39-45
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    • 2003
  • Nano-TiO$_2$ photocatalytic coatings were deposited on the stainless steel 304(50$\times$70$\times$3mm) by the APS(Atmospheric Plasma Spraying). Photocatlytic reaction was tested in MB(methylene blue) aqueous solution. For applying nano-TiO$_2$ powders by thermal spray, the starting nano-TiO$_2$ powder with 100% anatase crystalline was agglomerated by spray drying. Plasma second gas(H$_2$) flow rate and spraying distance were used as principal process parameters which are known to control heat enthalpy(heat input). The relationship between process parameters and the characteristics of microstructure such as the anatase phase fraction and grain size of the TiO$_2$ coatings were investigated. The photo-decomposition efficiency of TiO$_2$ coatings was evaluated by the kinetics of MB aqueous solution decomposition. It was found that the TiO$_2$ coating with a lower heat input condition had a higher anatase fraction, smaller anatase grain size and a better photo-decomposition efficiency.

Emission Characteristics of Nano-sized Particles in Bio-ethanol Fuelled Engine with Different Injection Type (바이오-에탄올연료 및 분사방식에 따른 엔진 나노입자 배출 특성)

  • Lee, Jin-Wook;Patel, Rishin;Ladommatos, Nicos
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.4
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    • pp.55-62
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    • 2009
  • As an experiment investigation, the effects of ethanol blended gasoline fuel with different injection method on nano-sized particle emission characteristics were examined in a 0.5L spark-ignited single-cylinder engine with a compression ratio of 10. Because this engine nano-particles are currently attracting interest due to its adverse health effects and their impact on the environments. So a pure gasoline and an ethanol blended gasoline fuels, namely E85 fuel, used for this study. And, as a particle measuring instrument, a fast-response particle spectrometer (DMS 500) with heated sample line was used for continuous measurement of the particle size and number distribution in the size range of 5 to 1000nm (aerodynamic diameter). As this research results, we found that the effect of ethanol blending gasoline caused drastic decrease of nano-particle emissions when port fuel injection was used for making better air-fuel mixture than direct fuel injection. Also injection timing, specially direct fuel injection, could be a dominant factor in controlling the exhaust particle emissions.

In-Plane Switching Liquid Crystal Display using Two Transistors (두 개의 트랜지스터로 구동되는 In-Plane Switching (IPS) 액정 디스플레이)

  • Jung, Jun-Ho;Park, Ji-Woong;Kim, Min-Su;Ha, Kyung-Su;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.308-309
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    • 2008
  • We have proposed a high performance liquid crystal display using two thin film transistors (TFTs) for the large size TFT-LCD desirably 42inch WXGA panel for TVs. The device generates stronger electric fields to reorient liquid crystals than that in the conventional IPS device because the voltages with opposite polarity with respect to the common electrode are applied to each finger-type electrode. As a result, the operation voltage of 2Tr-IPS mode can be decreased and the transmittance can be increased compared to conventional IPS device. Consequently, the 2Tr-IPS has all the advantages over conventional IPS from large size point of view.

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Characterization and Manufacturing for Solar Cells $CuInS_2$ Nanopowder by polyol process (Polyol process를 이용한 태양전지용 $CuInS_2$ 나노분말 제조 및 특성평가)

  • Lee, Dae-Girl;Lee, Nam-Hee;Oh, Hyo-Jin;Yun, Yeong-Ung;Hwang, Jong-Sun;Kim, Sun-Jae
    • Proceedings of the KIEE Conference
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    • 2009.04a
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    • pp.30-32
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    • 2009
  • In this study, $CuInS_2$ powders have been synthesized using polyol process of a mixture of copper nitrate, indium nitrate, and thiourea with various stoichiometric molar ratios in ethylene glycol at 196$^{\circ}C$. As boiling time goes by, the color of metal ion mixed solutions were changed transparent green to dark green and finally fumed to black by reduction of $OH^-$ radicals. The prepared powders were fully characterized by SEM, XRD and UV-Vis. The particle shape of black colored powders showed sphere with about 30 nm in particle size compared to those with dark green colored powders showed irregular shape with about 1 ${\mu}m$ in particle size. The XRD results showed highly crystallized $CuInS_2$. The UV-Vis spectra showed broad shoulder at 430 and 780 nm corresponding to 2.78 and 1.58 eV for the dark green colored one and black colored one, respectively.

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Hepatoprotective Effects of Amorphous and Nnno-Particle Pyeparations of Ursodeoxycholic Acid in CC4-Induced Mice : Effects of Three Types of Fine Grinding Mills (Ursodeoxycholic acid의 무정형 초미립자제제들의 CC4 유도 간손상 생쥐에 대한 보호 효과)

  • 정한영;곽신성;김현일;최우식;이지현;김애라;박태현;정해영;김유정
    • Biomolecules & Therapeutics
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    • v.10 no.1
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    • pp.1-6
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    • 2002
  • The particle size of medicinal materials is an Important physical property that affects the phar-maceutical behaviors such as dissolution, chemical stability, and bioavailability of solid dosage forms. The size reduction of raw medicinal powder is needed to formulate insoluble drugs or slightly soluble medicines and to improve the pharmaceutical properties such as the solubility, the pharmaceutical mixing, and the dispersion. The objective of the present study is to evaluate physiological activity of amorphous and nano-particle prep-arations of insoluble drug, ursodeoxycholic acid (UDCA), which were made by three types of fine grinding mills. The change of physical properties of ground UDCA was conformed by Mastersiger microplus and X-ray diffraction. We have investigated hepatoprotective effects of the nano-particle preparations of UDCA by plan-etary mill, vibration rod mill and jet mill in $CCI_4$-induced oxidatively injured mouse liver. The results showed that nano-particle preparations of UDCA all decreased reactive oxygen sepecies generation and lipid peroxi-dation in $CCI_4$-induced oxidative stress mice. Among them, nano-particle preparations by vibration rod mill and jet mill showed more significantly hepatoprotective effects compared to intact UDCA and planetary mill-ground UDCA. These results suggest that ground UDCA with vibration rod mill and jet mill shows a high amorphous state and the improved dissolution.

Comparison of HVOF Thermal Spray Coatings of T800 and WC-Co Powders

  • Cho, T.Y.;Yoon, J.H.;Kim, K.S.;Baek, N.K.;Song, K.O.;Youn, S.J.;Hwang, S.Y.;Chun, H.G.
    • Journal of Surface Science and Engineering
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    • v.39 no.6
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    • pp.295-301
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    • 2006
  • Hard chrome plating has been used in surface hard coating over 50 years both for applying hard coating and re-building of worn components. Hard chrome plating solution and mist pollute environment with very toxic $Cr^{6+}$(hex-Cr) known as carcinogen which causes lung cancer, High velocity oxy-fuel (HVOF) thermal spray coatings of WC base cermet and Co-alloy powders are the most promising candidates for the replacement of the traditional hard chrome plating. Surface properties, wear, and friction behaviors of micron size Co-alloy (T800) and micron size WC-l2Co (WC-Co) have been studied for the application as hard coatings. The temperature dependence of wear and friction behaviors of T800 and WC-Co have been investigated at the temperature of $25^{\circ}C$ and $538^{\circ}C$ for the application to high speed spindle.

Nano Porous Tin Oxide Film Fabricated by Anodization (양극산화법으로 제작된 나노 다공성 주석 산화물 박막)

  • Mun, Kyu-Shik;Cheon, Se-Jon;No, Hee-Kyu;Chun, Seung-Chul;Park, Sung-Yong;Lee, Ro-Un;Park, Yong-Joon;Choi, Won-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.328-328
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    • 2007
  • $SnO_2$ has a high potential for electric and electronic applications. We have anodized pure tin metal and nano porous tin oxide film was obtained on pure Sn. Nano porous tin oxide were grown by anodization in nonaqueous-base electrolytes at different potentials between 5 V and 100 V. Pore size of ~100nm was observed by FE-SEM. Pore sizes as a function of applied voltage and anodizing time were characterized. We obtained nano porous tin oxide film having an uniform pore size at low temperature. High specific surface area of $SnO_2$ will be very useful for gas sensor, lithium battery, and dye sensitized solar cell.

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Fabrication of Shingled Design Solar Module with Controllable Horizontal and Vertical Width (가로세로 폭의 제어가 가능한 슁글드 디자인 태양광 모듈 제조)

  • Min-Joon Park;Minseob Kim;Eunbi Lee;Yu-Jin Kim;Chaehwan Jeong
    • Current Photovoltaic Research
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    • v.11 no.3
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    • pp.75-78
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    • 2023
  • Recently, the installation of photovoltaic modules in urban areas has been increasing. In particular, the demand for solar modules installed in a limited space is increasing. However, since the crystalline silicon solar module's size is proportional to the solar cell's size, it is difficult to manufacture a module that can be installed in a limited area. In this study, we fabricated a solar module with a shingled design that can control horizontal and vertical width using a bi-directional laser scribing method. We fabricated a string cell with a width of 1/5 compared to the existing shingled design string cells using a bi-directional laser scribing method, and we fabricated a solar module by connecting three strings in parallel. Finally, we achieved a conversion power of 5.521 W at a 103 mm × 320 mm area.

Plasma Engineering for Nano-Materials

  • Kim, Seong-In;Shin, Myoung-Sun;Son, Byung-Koo;Song, Seok-Kyun;Choi, Sun-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.79-79
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    • 2012
  • A high temperature and a low temperature plasma process technologies were developed and demonstrated for synthesis, hybrid formation, surface treatment and CVD engineering of nano powder. RF thermal plasma is used for synthesis of spherical nano particles in a diameter ranged from 10 nm to 100 nm. A variety of nano particules such as Si, Ni, has been synthesized. The diameter of the nano-particles can be controlled by RF plasma power, pressure, gas flow rate and raw material feed rate. A modified RF thermal plasma also produces nano hybrid materials with graphene. Hemispherical nano-materials such as Ag, Ni, Si, SiO2, Al2O3, size ranged from 30 to 100 nm, has been grown on graphene nanoplatelet surface. The coverage ranged from 0.1 to 0.7 has been achieved uniformly over the graphene surface. Low temperature AC plasma is developed for surface modification of nano-powder. In order to have a three dimensional and lengthy plasma treatment, a spiral type of reactor has been developed. A similar plasma reactor has been modfied for nano plasma CVD process. The reactor can be heated with halogen lamp.

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Assessment of the Mechanical Performance of Nano-Silica and Nano-Calcite Incorporated Limestone Calcined Clay Cement (LC3) Paste (나노실리카와 나노칼사이트 혼입 석회석 소성 점토 시멘트(LC3) 페이스트의 기계적 성능 평가)

  • Kim, Gyeong-Ryul;Cho, Seong-Min;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.151-152
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    • 2023
  • This study investigates the effect of nano-silica and nano-calcite on the hydration properties and mechanical performance of limestone calcined clay cement (LC3) paste. The pastes were synthesized by replacing limestone with nano-silica and nano-calcite in order to enhance the mechanical properties in both early and late stages of hydration. The nano-calcite enhanced the strength of LC3 pastes at 1 day of hydration, however, the strength decreased compared to the ordinary LC3 pastes afterwards due to excessive amount of carboaluminate produced in the pastes. On the other hand, nano-silica improved the mechanical properties of LC3 pastes at all ages of hydration. This is mainly due to the nucleation effect and pozzolanic reaction of nano-silica, affecting the early age and late ages of hydration, respectively. The nucleation effect of both nanomaterials were confirmed by the analysis of hydration heat, supporting the enhanced early age strength of nanomaterial incorporated LC3 pastes. Furthermore, the dense matrix was shown in the pore size distribution, and the increased C-S-H due to the pozzolanic reaction evidence the improved compressive and splitting tensile strength of nano-silica incorporated LC3 pastes.

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