• Title/Summary/Keyword: Nano size

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Hydrogenation Properties of MgH2-CaO Composites Synthesized by Hydrogen-Induced Mechanical Alloying

  • Kim, Min Gyeom;Han, Jeong-Heum;Lee, Young-Hwan;Son, Jong-Tae;Hong, Tae Whan
    • Korean Journal of Metals and Materials
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    • v.56 no.11
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    • pp.829-834
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    • 2018
  • Although magnesium-based alloys are attractive materials for hydrogen storage applications, their activation properties, hydrogenation/dehydrogenation kinetics, thermodynamic equilibrium parameters, and degradation characteristics must be improved for practical applications. Further, magnesium poses several risks, including explosion hazard, environmental pollution, insufficient formability, and industrial damage. To overcome these problems, CaO-added Mg alloys, also called Eco-Mg (environment-conscious Mg) alloys, have been developed. In this study, $Eco-MgH_x$ composites were fabricated from Mg-CaO chips by hydrogen-induced mechanical alloying in a high-pressure atmosphere. The balls-to-chips mass ratio (BCR) was varied between a low and high value. The particles obtained were characterized by X-ray diffraction (XRD), and the absorbed hydrogen was quantified by thermogravimetric analysis. The XRD results revealed that the $MgH_2$ peaks broadened for the high BCR. Further, PSA results revealed particles size were decreased from $52{\mu}m$ to $15{\mu}m$.

Semiconductor coupled solar photo-Fenton's treatment of dyes and textile effluent

  • Raji, Jeevitha R.;Palanivelu, Kandasamy
    • Advances in environmental research
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    • v.5 no.1
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    • pp.61-77
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    • 2016
  • $NanoTiO_2$ was synthesized by ultrasonication assisted sol-gel process and subjected to iron doping and carbon-iron codoping. The synthesized catalysts were characterized by XRD, HR-SEM, EDX, UV-Vis absorption spectroscopy and BET specific surface area analysis. The average crystallite size of pure $TiO_2$ was in the range of 30 - 33 nm, and that of Fe-$TiO_2$ and C-Fe $TiO_2$ was in the range of 7 - 13 nm respectively. The specific surface area of the iron doped and carbon-iron codoped nanoparticles was around $105m^2/g$ and $91m^2/g$ respectively. The coupled semiconductor photo-Fenton's activity of the synthesized catalysts was evaluated by the degradation of a cationic dye (C.I. Basic blue 9) and an anionic dye (C.I. Acid orange 52) with concurrent investigation on the operating variables such as pH, catalyst dosage, oxidant concentration and initial pollutant concentration. The most efficient C-Fe codoped catalyst was found to effectively destruct synthetic dyes and potentially treat real textile effluent achieving 93.4% of COD removal under minimal solar intensity (35-40 kiloLUX). This reveals the practical applicability of the process for the treatment of real wastewater in both high and low insolation regimes.

Synthesis and characterization of polyamide thin-film nanocomposite membrane containing ZnO nanoparticles

  • AL-Hobaib, A.S.;El Ghoul, Jaber;El Mir, Lassaad
    • Membrane and Water Treatment
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    • v.6 no.4
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    • pp.309-321
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    • 2015
  • We report in this study the synthesis of mixed matrix reverse osmosis membranes by interfacial polymerization (IP) of thin film nanocomposite (TFNC) on porous polysulfone supports (PS). This paper investigates the synthesis of ZnO nanoparticles (NPs) using the sol-gel processing technique and evaluates the performance of mixed matrix membranes reached by these aerogel NPs. Aqueous m-phenyl diamine (MPD) and organic trimesoyl chloride (TMC)-NPs mixture solutions were used in the IP process. The reaction of MPD and TMC at the interface of PS substrates resulted in the formation of the thin film composite (TFC). NPs of ZnO with a size of about 25 nm were used for the fabrication of the TFNC membranes. These membranes were characterized and evaluated in comparison with neat TFC ones. Their performances were evaluated based on the water permeability and salt rejection. Experimental results indicated that the NPs improved membrane performance under optimal concentration of NPs. By changing the content of the filler, better hydrophilicity was obtained; the contact angle was decreased from $74^{\circ}$ to $32^{\circ}$. Also, the permeate water flux was increased from 26 to 49 L/m2.h when the content of NPs is 0.1 (wt.%) with the maintaining of lower salt passage of 1%.

Two-Phase Two-Component Loop Thermosyphon with Nanofluid (나노유체를 이용한 2상유동 2성분 루프형 열사이폰)

  • Rhi Seok-Ho;Park Jong-Chan;Cha Kyeong-Il;Lim Taek-Kyu;Lee Chung-Gu;Shin Dong-Ryun;Park Gi-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.5
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    • pp.384-392
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    • 2006
  • Reported are the heat transfer characteristics of a two-phase loop thermosyphon (TLT) with nanofluids consisted of nano-size silver particles and distilled water as the working fluid. The nanofluids used in the present study are dispersed solutions with various amount of silver nanoparticle in distilled water. It is seen from the present study that the heat transfer performance of the test TLT with nanofluids increased as much as about 2 times higher than that of a TLT with pure water as the working fluid based on same heat flux. The study also showed that there was no deterioration of the TLT performance with time, up to a period of 8 days of continuous operation which implies that there was no coagulation of nanoparticles within the working nanofluid during the operation of the test TLT.

High Speed SD-OCT System Using GPU Accelerated Mode for in vivo Human Eye Imaging

  • Cho, Nam Hyun;Jung, Unsang;Kim, Suhwan;Jung, Woonggyu;Oh, Junghwan;Kang, Hyun Wook;Kim, Jeehyun
    • Journal of the Optical Society of Korea
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    • v.17 no.1
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    • pp.68-72
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    • 2013
  • We developed an SD-OCT (Spectral Domain-Optical Coherence Tomography) system which uses a GPU (Graphics Processing Unit) for processing. The image size from the SD-OCT system is $1024{\times}512$ and the speed is 110 frame/sec in real-time. K-domain linearization, FFT (Fast Fourier Transform), and log scaling were included in the GPU processing. The signal processing speed was about 62 ms using a CPU (Central Processing Unit) and 1.6 ms using a GPU, which is 39 times faster. We performed an in-vivo retinal scan, and reconstructed a 3D visualization based on C-scan images. As a result, there were minimal motion artifacts and we confirmed that tomograms of blood vessels, the optic nerve, and the optic disk are clearly identified. According to the results of this study, this SD-OCT can be applied to real-time 3D display technology, particularly auxiliary instruments for eye operations in ophthalmology.

Immobilization of Prussian blue nanoparticles in acrylic acid-surface functionalized poly(vinyl alcohol) sponges for cesium adsorption

  • Wi, Hyobin;Kang, Sung-Won;Hwang, Yuhoon
    • Environmental Engineering Research
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    • v.24 no.1
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    • pp.173-179
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    • 2019
  • Prussian blue (PB) is known to be an effective material for radioactive cesium adsorption, but its nano-range size make it difficult to be applied for contaminated water remediation. In this study, a simple and versatile approach to immobilize PB in the supporting matrix via surface functionalization was investigated. The commercially available poly vinyl alcohol (PVA) sponge was functionalized by acrylic acid (AA) to change its major functional group from hydroxyl to carboxylic, which provides a stronger ionic bond with PB. The amount of AA added was optimized by evaluating the weight change rate and iron(III) ion adsorption test. The FTIR results revealed the surface functional group changing to a carboxyl group. The surface functionalization enhanced the attachment of PB, which minimized the leaching out of PB. The $Cs^+$ adsorption capacity significantly increased due to surface functionalization from 1.762 to 5.675 mg/g. These findings showed the excellent potential of the PB-PAA-PVA sponge as a cesium adsorbent as well as a versatile approach for various supporting materials containing the hydroxyl functional group.

Formation of nanonet structure using polystyrene nanoparticle for high-performances TFT applications (고성능 TFT 소자 응용을 위한 폴리스티렌 나노입자를 이용한 나노 그물망 제작공정 개발)

  • Yoon, Gilsang;Lee, Junyoung;Park, Iksoo;Jin, Bo;Baek, Rock-Hyun;Shin, Hyun-jin;Lee, Jeong-soo
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.36-40
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    • 2018
  • We have developed a nonlithographic patterning technique using polystyrene nanoparticles to form nanonet channel structures which is promising for high-performance TFT applications. Nanoparticles assisted patterning (NAP) is a technique to form uniform nano-patterns by applying lift-off and dry etch process. Oxygen plasma treatment was used to control the diameters of nanonet hole size to realize a branch width down to 100 nm. NAP technology can be very promising to fabricate nanonet structure with advantages of lower manufacturing cost and large-area patterning capability.

Nonlinear vibration of nanosheets subjected to electromagnetic fields and electrical current

  • Pourreza, Tayyeb;Alijani, Ali;Maleki, Vahid A.;Kazemi, Admin
    • Advances in nano research
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    • v.10 no.5
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    • pp.481-491
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    • 2021
  • Graphene Nanosheets play an important role in nanosensors due to their proper surface to volume ratio. Therefore, the main purpose of this paper is to consider the nonlinear vibration behavior of graphene nanosheets (GSs) under the influence of electromagnetic fields and electrical current create forces. Considering more realistic assumptions, new equations have been proposed to study the nonlinear vibration behavior of the GSs carrying electrical current and placed in magnetic field. For this purpose, considering the influences of the magnetic tractions created by electrical and eddy currents, new relationships for electromagnetic interaction forces with these nanosheets have been proposed. Nonlinear coupled equations are discretized by Galerkin method, and then solved via Runge-Kutta method. The effect of different parameters such as size effect, electrical current magnitude and magnetic field intensity on the vibration characteristics of GSs is investigated. The results show that the magnetic field increases the linear natural frequency, and decreases the nonlinear natural frequency of the GSs. Excessive increase of the magnetic field causes instability in the GSs.

Effect of Adhesion layer on the Optical Scattering Properties of Plasmonic Au Nanodisc (접착층을 고려한 플라즈모닉 금 나노 디스크의 광산란 특성)

  • Kim, Jooyoung;Cho, Kyuman;Lee, Kyeong-Seok
    • Korean Journal of Metals and Materials
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    • v.46 no.7
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    • pp.464-470
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    • 2008
  • Metallic nanostructures have great potential for bio-chemical sensor applications due to the excitation of localized surface plasmon and its sensitive response to environmental change. Unlike the commonly explored absorption-based sensing, the optical scattering provides single particle detection scheme. For the localized surface plasmon resonance spectroscopy, the metallic nanostructures with controlled shape and size have been usually fabricated on adhesion-layer pre-coated transparent glass substrates. In this study, we calculated the optical scattering properties of plasmonic Au nanodisc using a discrete dipole approximation method and analyzed the effect of adhesion layer on them. Our result also indicates that there is a trade-off between the surface plasmon damping and the capability of supporting nanostructures in determining the optimal thickness of adhesion layer. Marginal thickness of Ti adhesion layer for supporting Au nanostructures fabricated on a silica glass substrate was experimentally analyzed by an adhesion strength test using a nano-indentation technique.

Rapid Sintering of Nanocrystalline (W,Ti)C-Graphene Composites (나노구조 (W,Ti)C-Graphene 복합재료 급속소결)

  • Kim, Seong-Eun;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.56 no.12
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    • pp.854-860
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    • 2018
  • In spite of the many attractive properties of (W,Ti)C, its low fracture toughness limits its wide application. To improve the fracture toughness generally a second phase is added to fabricate a nanostructured composite. In this regard, graphene was considered as the reinforcing agent of (W,Ti)C. (W,Ti)C-graphene composites that were sintered within 2 min using pulsed current activated heating under a pressure of 80 MPa. The rapid consolidation method allowed retention of the nano-scale microstructure by blocking the grain growth. The effect of graphene on the hardness and microstructure of the (W,Ti)C-graphene composite was studied using a Vickers hardness tester and FE-SEM. The grain size of (W,Ti)C was reduced remarkably by the addition of graphene. Furthermore, the hardness decreased and the fracture toughness improved with the addition of graphene.