• Title/Summary/Keyword: NaCl solution

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Electrogravimetric and Electrochemical Ac Response of Polypyrrole Films

  • Yang, Haesik;Lee, Hochun;Kwak, Juhyoun
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.663-668
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    • 1995
  • Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.

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Growth Characteristics and Photosynthesis of Soybean Seedling to NaCl stress in Sand Culture (콩의 유묘기에 있어서 NaCl Stress에 의한 생육특성과 광합성 반응)

  • Cho, Jin-Woong;Kim, Choong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.18 no.4
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    • pp.361-365
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    • 1999
  • This atudy was conducted to determine the growth characteristics and photosynthesis of soybean (Glycine max L. cv. Keumjongkongl) 30 day old seedling to 100mM NaCl concentration containing 1/2 Hoagland`s nutrient solution in sand culture. The nodule formation of root is not found perfectly with NaCl stress. The leaf dry matter weight (g/plant) of stressed plant is more reduction in 77% to control than any other characters. The water content (%) is tend to increase but water potential (MPa) is tend to decrease at NaCl stress. The chlorophyll content (SPAD) is tend to increase at growing leaf age of control but decrease at NaCl stress. The photosynthesis, stomatal conductance and transpiration are tend to decrease sharply at NaCl stress.

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Chloride Ion Effects on Anodic Dissolution of Copper in Aqueous NaCl Solutions under Argon Atmosphere (아르곤 분위기의 NaCl 수용액에서 구리의 산화 용해반응에 미치는 염화이온의 영향)

  • Chon, Jung-Kyoon;Kim, Youn-Kyoo
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.159-164
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    • 2008
  • We investigated chloride ion effects on anodic dissolution of copper using potentiodynamic method, cyclic voltammtery, chronoamperometry and chronocoulometry. The anodic dissolution reaction of copper in NaCl solution under argon atmosphere is $Cu+2Cl^{-}{\rightleftharpoons}{CuCl_2}^{-}+e^-$ and chloride ion adsorption process in copper surface can be explained by Temkin isotherm.

A Study on Relationship between Corrosion Characteristics and Salt Concentration of Anti-corrosive Paint (방청도료의 부식특성과 염분농도의 상관관계에 관한 연구)

  • Moon, Kyung-Man;Lee, Myeong-Woo;Lee, Myeong-Hoon;Kim, Hye-Min;Baek, Tae-Sil
    • Journal of the Korean institute of surface engineering
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    • v.51 no.2
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    • pp.95-103
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    • 2018
  • Recently, many types of constructional steels have been often exposed to under severe corrosive environments due to acid rain with increasing environmental contamination. In order to inhibit their corrosion in severe corrosive environments, a painting method has been widely applied to numerous constructional steels of land as well as marine. Therefore, development of paint having a good quality of corrosion resistance is considered to be very important. In this study, four types of anti-corrosive paints (AP: Phenol epoxy, AC: Ceramic epoxy, AT: Coal tar epoxy, AH: High solid epoxy) were coated to the specimens, and then, were immerged in various salt solutions (0.1, 0.3, 3, 6, 9 and 15% NaCl solutions) for 11 days. And, the corrosion resistance of these samples by effect of osmotic pressure with salt concentration was investigated with electrochemical methods such as measurement of corrosion potential, impedance and corrosion current density. The corrosion current densities of all samples (AC, AT and AH) submerged in 3% NaCl solution exhibited the smallest values compared to other salt solutions. However, in the case of lower values of salt solutions than 3% NaCl solution, the corrosion current density increased again because it makes easier for water, dissolved oxygen and chloride ion etc. to invade toward inner side of coating film due to increasing of the osmotic pressure than 3% NaCl solution, but in the case of higher values of salt solutions than 3% NaCl solution, the coating film is easily deteriorated due to high concentration of chloride ion rather than the osmotic pressure, which resulted in increasing the corrosion current density. In particular, the AC sample indicated the best corrosion resistance in 6% NaCl solution compared to other samples. Consequently, it is considered that the corrosion mechanism of the coated steel plate is completely different from bare steel plate, and the corrosion resistance of coating film by osmotic pressure and chloride ion depend on various types of epoxy of paint in NaCl solution.

Effects of Aspirin on Nitrite Toxicity in Cultured Eel (Anguilla japonica) (양식 뱀장어 (Anguilla japonica)의 아질산 독성에 미치는 aspirin의 투여 효과)

  • Kim, Dong-Wan;Koo, Jae-Geun;Park, Sung -Woo
    • Journal of fish pathology
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    • v.20 no.3
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    • pp.291-297
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    • 2007
  • The effect of aspirin on the recovery of nitrite-induced methemoglobinemia in cultured eels (Anguilla japonica) was studied. Methemoglobinemia was induced by exposing eels to nitrite (120 ㎎ NO2-N/ℓ) for 24 hr. The nitrite exposed eels were bathed in 20 ppm aspirin solution (Aspirin), 0.8 % NaCl solution (NaCl), 20 ppm aspirin plus 0.8% NaCl solution (NaCl + Aspirin) and 50% nitrite free water(control) for 24 hr to recover from nitrite toxicity. Peripheral blood was taken from the arterious bulb from all groups to analyse hematocrit value, hemoglobin concentration, and nitrite concentration of the blood. Histopathological features of gill were also observed. Aspirin and control groups were more effective than NaCl and NaCl + Aspirin groups in recovery of hematocrit value and hemoglobin concentration, methemoglobin rate and nitrite concentration. The histopathological features on the gill of aspirin group were similar to those of normal eels, but other groups showed focal hyperemia in the lamellar carpillaries, epithelial hyperplasia. These results suggested that aspirin was very effective to recover from methemoglobinemia in nitrite-induced cultured eels.

Removal of Alkali Metal Ion and Chlorine Ion Using the Ion Exchange Resin (이온교환수지를 이용한 알칼리 금속 이온 및 염소 이온의 제거)

  • Lee, Kyung-Han;Kil, Bo-Min;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.30 no.4
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    • pp.276-281
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    • 2020
  • A research was conducted on the removal of ion from the solution involving the alkali metal ion and chlorine ion using ion exchange resin. The cation exchange resin and anion exchange resin was used for the remove of metal ion (Na+ and K+) and chlorine ion (Cl-), respectively. In the case of solution A (involving 36,633 ppm of Na+ and 57,921 ppm of Cl-), the Na+ ion and Cl- ion were removed over 99% within 20 min. In the case of solution B (involving 1,638 ppm of K+), the K+ ion was removed over 99% within 3 min.

Assessment of Hydraulic Properties of Bentonite Swelling Agents by Blending with Additives (첨가제 혼합에 의한 벤토나이트 팽윤재의 수리학적 특성평가)

  • Jeon, Han-Yong;Park, Yeoung-Mog;Mok, Mun-Sung
    • Journal of the Korean Geosynthetics Society
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    • v.1 no.1
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    • pp.43-51
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    • 2002
  • In this study, free swell index of betonite was examined in several regeants; distilled water, leachate, seawater and 3% NaCl solution. Free swell index values of bontonite to be added Poly(acrlylic acid), PYA(Polyvinyl Alcohol) or SCMC (Sodium Carboxymethyl Cellulose) were evaluated and compared. From this, it was confirmed that hydraulic conductivities of GCL in seawater were examined and the hydraulic conductivities of GCL in seawater were compared to those in distilled water. The average values of free swell indices of bentonite were decreased in order of distilled water>leachate>seawater. It was shown that no significant differences were occurred for free swell index between seawater and 3% NaCl solution. For bentonite to be added PVA, the other reagents except distilled water didn't affect increase of swelling. Swelling properties of bentonite to be added SCMC were improved except 3% NaCl solution.

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Effect of Jasmonic Acid and NaCl on the Growth of Spearmint(Mentha spicata L.) (Jasmonic Acid 및 NaCl 처리가 스피아민트의 생육에 미치는 영향)

  • Choi, Young;Chiang, Maehee
    • Journal of Bio-Environment Control
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    • v.26 no.2
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    • pp.133-139
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    • 2017
  • This study investigated the effects of NaCl and jasmonic acid (JA) on the growth and physiological responses of spearmint (Mentha spicata L.). Spearmint was hydroponically grown for 3 weeks in modified Hoagland solution containing 0 (untreated control), JA ($20{\mu}M$ JA pretreatment), NaCl (50 mM NaCl treatment) and JA + NaCl ($20{\mu}M$ JA pretreatment + 50 mM NaCl treatment). Growth characteristics, chlorophyll, vitamin C, proline contents, DPPH scavenging activity and inorganic ion contents were evaluated. As a results, there were significant decreases in the plant height, leaf length, leaf width, and fresh weight of plants, treated with NaCl compared with control. On the other hand, the dry matters of shoot and root treated with JA + NaCl combination were better than control or NaCl treatment. Chlorophyll a and b contents in JA treatment was the highest. Vitamin C, antioxidant activity, and proline content in shoot were increased in NaCl treatment which showed low level of growth rate. The K/Na ratio, which is known to indirectly reflect the balance of ion uptake, was higher in a single treatment of JA than the control group, while lower in salt treatment (NaCl and JA + NaCl) because of high $Na^+$ absorption. In conclusion, these results showed that moderate stress treatment such as low level salt treatment and plant growth regulator jasmonic acid (JA) application would be potential strategies to improve the quality of spearmint by inducing the accumulation of secondary metabolites containing high antioxidant activity and essential oil.