• Title/Summary/Keyword: NaCl solution

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An Experimental Study on Corrosion Fatigue Strength of TMCP Steel in Consideration of NaCl Salinity (염분농도변화에 따른 TMCP강의 부식피로강도에 관한 실험적 연구)

  • 강성원;김철현;이해우
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.3
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    • pp.54-60
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    • 2003
  • Fatigue strength of offshore structures or ship structures is significantly decreased due to corrosive environment condition such as sea water and/or coal, crude oil of cargoes, compared to that of on shore structures. In corrosive environment, fatigue strength of structures also depends on characteristics of weld material heat affected zone(HAZ). In this research work, rotary bending fatigue tests of parent material and HAZ of TMCP steel were performed in order to investigate the initiation and propagation of cracks both in air and in NaCl solution. Comparison of fatigue strength In relation with the salinity of NaCl were carried out as well. According to the test results weld material or HAZ of TMCP steel showed higher fatigue strength than that of the parent material. The fatigue strength of TMCP steel decreases drastically in NaCl solution compared to that of in air environment. In particular, more reduced fatigue strength is observed in 1% NaCl solution than in 3% NaCl solution.

Effect of Acid and Salt on Weight toss of Polyester (PET) fabric by Sodium Hydroxide (산과 염이 폴리에스터 직물의 알칼리 감량에 미치는 영향)

  • Do, Sung-Guk;Cho, Hwan
    • Textile Coloration and Finishing
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    • v.4 no.3
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    • pp.65-73
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    • 1992
  • To control the hydrolysis rate of PET fabric with NaOH, HCl and $CH_3$COOH(HAc), as regulating reagent, were added to the 0.5 M NaOH solution. The concentrations of acids in 0.5 M NaOH were varied. PET fabrics were treated with aqueous solutions of acids in 0.5 M NaOH under different conditions. The weight loss of PET fabric, the rate of hydrolysis, the apparent activation energy (E$_{\alpha}$), the handle value, the etched surface of treated PET fabric, and the effect of salts such as NaCl, $CH_3$COONa(NaAc), and NH$_4$Cl on the weight loss were discussed. Acids in the aqueous 0.5 M NaOH solution decreased the weight loss of PET fabric bacause of neutralization of OH- and the weight loss of PET fabrics treated with corresponding concentration of aqueous NaOH solution to the concentrations of the aqueous solutions of acids in 0.5 M NaOH was lower than that of PET fabrics treated with aqueous solutions of acids in 0.5 M NaOH. The addition of NaCl to aqueous NaOH solution accelerated the reaction of OH- with PET greatly, the addition of NaAc increased the weight loss slightly, but the addition of NH$_4$Cl decreased the weight loss. It was thought that the very remarkable result that NaCl in aqueous NaOH solution promoted the hydrolysis of PET with NaOH would contribute to the conservation of energy and NaOH in the weight loss finishing process of PET fabric. The etched surface and the handle value of treated PET fabric were independent of the difference in the kinds of acids and salts added.nd salts added.

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Preparation of Chlorine Dioxide Aqueous Solution by Un-divided Electrochemical Cell using RuO2 anode (RuO2를 양전극으로 사용한 무격막 전해셀에서의 이산화염소수 제조)

  • Kwon, Tae Ok;Park, Bo Bae;Roh, Hyun Cheul;Moon, Il Shik
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.296-300
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    • 2009
  • Generation of chlorine dioxide ($ClO_2$) was studied by the un-divided electrochemical cell system using $RuO_2$ anode material. Sodium chlorite ($NaClO_2$) was used as a precursor compound of chlorine dioxide. Effect of various operating parameters such as feed solution flow rate, initial solution pH, $NaClO_2$ and NaCl conc., and applied current density on the produced chlorine dioxide concentration and solution pH were investigated in un-divided electrochemical cell system. Produced chlorine dioxide concentration and solution pH were strongly depends on the initial solution pH and feed solution flow rate. Sodium chloride (NaCl) was not only good electrolyte, it was also used as a raw material of chlorine dioxide with $NaClO_2$. Observed optimum conditions were flow rate of feed solution (90 mL/min), initial pH (2.3), $NaClO_2$ concentration (4.7 mM), NaCl concentration (100 mM), and current density ($5A/dm^2$). Produced chlorine dioxide concentration was around 350 mg/L and solution pH was around 3.

Permeation Effect of NaCl into Shell Egg with Concentration of NaCl Solution, Salting Time and Salting Pressure (염지액농도, 염지시간 및 염지압력에 따른 계란의 염 침투효과)

  • 전기홍;유익종;장윤희;강통삼
    • Korean Journal of Poultry Science
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    • v.20 no.3
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    • pp.125-131
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    • 1993
  • This study was performed to find the desirable conditions for processing salted hard-boiled egg without cracking egg shell in NaCl solution under pressure. Among the many factors affecting saltiness of the shell egg, concentration of NaCl solution(0~40%), different salting time(0~45h) and salting pressure (0~4.5kg/$\textrm{cm}^2$) were employed to identify the permeability of NaCl into shell egg at ambient temperature. The saltiness of the shell egg was proportionally risen as concentration of NaCl solution, salting time and pressure increased. The most desirable saltiness was observed at the 0.70~1.00% of NaCl in albumen and 0.40~0.45% in yolk, Besides the saltiness, sensory evaluation of the shell egg were carried out to evaluate the quality of the salted shell egg. The effect of various concentration of NaCl solution, salting time and pressure on sensory scores of hard-boiled salted eggs showed that 20~40% of NaCl solution, 12~20 h of salting time, 3~4.5 kg/$\textrm{cm}^2$ of salting pressure were proper conditions for processing the product. These results indicate that the desirable condition to get salted hard-boiled shell egg were ; 30% of NaCl solution, 16h of salting time and 4.0kg/$\textrm{cm}^2$ of salting pressure.

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Appearance Contamination of EPDM Article from Water Solution (EPDM 소재의 수용액으로부터의 외관 오염)

  • Choi, Sung-Seen;Chung, Hye-Seung;Joo, Yong-Tae;Yang, Kyung-Mo;Lee, Seong-Hoon
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.100-105
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    • 2010
  • An EPDM article was aged in air, distilled water, tap water, NaCl/$CaCl_2$ solution, and $CaCl_2/FeCl_3$ solution for 7 days. The aging temperature was $90^{\circ}C$. The samples aged in air and distilled water did not appear the whitening, those aged in tap water, NaCl/$CaCl_2$ solution, and $CaCl_2/FeCl_3$ solution showed the whitening. Soluble organic materials were analyzed using GC/MS to identify the whitening materials, surface morphology of the aged sample surface was examined using image analyzer and SEM, and elemental analysis of the materials accumulated on the sample surface was performed using EDX. Principal reason to cause whitening might be formation of metal salt of fatty acid by reaction between metal cation and fatty acid.

Solution Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp. (호 알칼리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 용액 특성)

  • 이신영;강태수김갑수
    • KSBB Journal
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    • v.10 no.4
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    • pp.386-392
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    • 1995
  • The high viscous ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) from alkalophilic Alcaligenes sp. was purified and its solution property was investigated. The intrinsic viscosities for Na+ form and H+ form of ${\gamma}$-PGA were 31.1 and 0.38d$\ell$/g, respectively. The viscosity of H+-PGA was not influenced by pH or salts while that of Na+-PGA was influenced. The intrinsic viscosity of Na+-PGA solution decreased remarkably at the alkaline or acidic pH and showed the sharp decrease when salts were added. ${\gamma}$-PGA exhibited the property of the polyelectrolyte showing the .sharp decrease of intrinsic viscosity by the addition of NaCl, and intrinsic viscosity of dilute solution with the low concentration of NaCl was exponentially dependent on temperature and its temperature dependency increased with increasing NaCl concentration. The chain stiffness, coil overlap parameter and critical concentration of Na+-PGA were 0.08, 5.25 and 0.07g/d$\ell$, respectively.

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Effect of Different Conditions of Sodium Chloride Treatment on the Characteristics of Kenaf Fiber-Epoxy Composite Board

  • SETYAYUNITA, Tamaryska;WIDYORINI, Ragil;MARSOEM, Sri Nugroho;IRAWATI, Denny
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.2
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    • pp.93-103
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    • 2022
  • Currently, biofibers are used as a reinforcement in polymer composites for structural elements and construction materials instead of the synthetic fibers which cause environmental problems and are expensive. One of the chemicals with a pH close to neutral that can be potentially used as a modified fiber material is sodium chloride (NaCl). Therefore, this study aims to investigate the characteristics of a composite board made from NaCl-treated kenaf fiber. A completely randomized design method was used with consideration of two factors: the content of NaCl in the treatment solution (1 wt%, 3 wt%, and 5 wt%) and the duration of immersion of fibers in the solution (1 h, 2 h, and 3 h). The NaCl treatment was conducted by soaking the fibers in the solution for different durations. The fibers were then rinsed with water until the pH of the water reached 7 and subsequently dried inside an oven at 80℃ for 6 h. Kenaf fiber and epoxy were mixed manually with the total loading of 20 wt% based on the dry weight of the fiber. Physical and mechanical properties of the fibers were then evaluated based on JIS A 5908 particleboard standards. The results showed that increasing NaCl content in the fiber treatment solution can increase the physical and mechanical properties of the composite board. The properties of fibers treated with 5 wt% NaCl for 3 h were superior with a modulus of elasticity of 2.085 GPa, modulus of rupture of 19.77 MPa, internal bonding of 1.8 MPa, thickness swelling of 3%, and water absorption of 10.9%. The contact angle of untreated kenaf fibers was 104°, which increased to 80° and 73° on treatment with 1 wt% and 5 wt% NaCl for 3 h, respectively.

Effects of Na2S, NaCl, and H2O2 Concentrations on Corrosion of Aluminum (AA1100의 부식에 미치는 Na2S, NaCl, H2O2 농도의 영향)

  • Lee, Ju Hee;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.312-317
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    • 2019
  • The objective of this study was to investigate the corrosion behavior of aluminum (AA1100) in a mixed solution of 0 ~ 0.1 g/L Na2S + 0.3 ~ 3 g/L NaCl + 0 ~ 10 mL/L H2O2. Potentiodynamic polarization tests were performed. Effects of solution compositions on corrosion potential, corrosion rate, and pitting potential of aluminum were statistically analyzed with a regression model. Results suggested that localized corrosion susceptibility of aluminum was increased in the solution with increasing concentration of NaCl because the pitting potential was lowered linearly with increasing NaCl concentration. On the contrary, H2O2 mitigated the galvanic corrosion of aluminum by increasing the corrosion potential. It also mitigated localized corrosion by increasing the pitting potential of aluminum. Na2S did not exert a noticeable effect on the corrosion of aluminum. These effects of different chemical species at various concentrations were independent of each other. Synergy or offset effect was not observed.

Corrosion Behavior of Rapidly Solidified Mg-Zn-Y Alloys in NaCl Solution

  • Izumi, Shogo;Yamasaki, Michiaki;Sekigawa, Takahiro;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1043-1044
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    • 2006
  • Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the $Mg_{98}Y_2$ (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was $Mg_{97.25}Zn_{0.75_Y_2$, its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. $Mg_{97.25}Zn_{0.75}Y_2$ alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.

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Quality Changes of Vegetables by different Cooking Methods (조리방법에 따른 채소류의 품질 변화)

  • Kim, Byeong-Cheol;Hwang, Jin-Young;Wu, Hyun-Jung;Lee, Se-Mi;Cho, Hyung-Yong;Yoo, Young-Mi;Shin, Hae-Hun;Cho, Eun-Kyung
    • Culinary science and hospitality research
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    • v.18 no.1
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    • pp.40-53
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    • 2012
  • The quality changes of vegetables including cucumbers, young pumpkins, carrots, radishes, onions by different cooking methods in $90^{\circ}C$ water, 0.5% NaCl solution, 1.0% NaCl solution and $400^{\circ}C$ superheated steam were investigated. The changes in pH of cooked vegetables were increased. Hunter color system values for L(lightness), a(redness) and b(yellowness) of the vegetables cooked in $400^{\circ}C$ supetbeated steam for 30 seconds were less compared with those in $90^{\circ}C$ water, 0.5% NaCl solution and 1.0% NaCl solution. The microbial growth was inhibited very effectively when the vegetables cooked in $400^{\circ}C$ superheated steam for 30 seconds. After cooked in $90^{\circ}C$ water, 0.5% NaCl solution, 1.0% NaCl solution, $400^{\circ}C$ superheated steam, vitamin C content decreased by different ratio depending on cooking methods and vegetable varieties. Based on the results of the quality changes of cooked vegetables, the superheated steam cooking method showed a positive effect on sterilization and maintaining pH, color, hardness of vegetable tissues, vitamin C content. The data obtained from this study could be utilized as basic information for the optimum conditions of superheated steam cooking to develope HMR(Home Meal Replacement).

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