• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 가을 학술논문 발표대회
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• pp.109-110
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• 2021

An attempt has been made on a constructive approach to evaluate the performance of snail shell ash (SSA) for its corrosion performance under marine environments. Corrosion performance of steel rebar in chloride contaminated SSA with (0% to 50%) replacement levels of cement extract medium was examined through electrochemical and weight loss techniques. Initially, snail shell powder (SSP) is made by pulverizing and subsequently SSA is by thermal decomposition methods. A critical level of 20 % SSA improved both corrosion resistance properties of cement extracts. SSA is a suitable replacement material for natural limestone in cement productions.

• 한국건축시공학회지
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• 제19권6호
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• pp.511-520
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• 2019

혼화재 혼입에 따른 콘크리트의 철근부식 임계염화물량의 변화를 실험적으로 평가하였다. 콘크리트 배합조건은 OPC 100%, OPC 70% + GGBFS 30%, OPC 40% + GGBFS 60%, OPC 40% + GGBFS 40% + FA 20% 로 구분하여 4가지 배합의 철근 콘크리트 시험체를 제작하였다. 시험체에 NaCl 수용액을 공급하며, 매립된 철근의 자연전위를 모니터링 하였다. 부식이 발생한 것으로 판단된 시험체는 NaCl 수용액 공급면으로부터 5mm간격으로 절단하여 염소이온량 프로파일을 실시하였다. 콘크리트에 매립된 철근의 부식 개시시기는 시멘트를 혼화재로 치환하여 사용하는 경우 지연되는 것을 확인하였다. 하지만 콘크리트에 매립된 철근의 부식임계염화물량은 혼화재 혼입율 증가에 따라 감소하여, OPC 1.46kg/㎥, S30 0.98kg/㎥, TBC 0.74kg/㎥, S60 0.71kg/㎥ 순으로 높게 나타났다.

• 한국축산식품학회지
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• 제34권4호
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• pp.552-557
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• 2014

This study investigated the effects of ${\gamma}$-aminobutylic acid (GABA) on the quality and sensorial properties of both the GABA/NaCl complex and model meat products. GABA/NaCl complex was prepared by spray-drying, and the surface dimensions, morphology, rheology, and saltiness were characterized. For model meat products, pork patties were prepared by replacing NaCl with GABA. For characteristics of the complex, increasing GABA concentration increased the surface dimensions of the complex. However, GABA did not affect the rheological properties of solutions containing the complex. The addition of 2% GABA exhibited significantly higher saltiness than the control (no GABA treatment). In the case of pork patties, sensory testing indicated that the addition of GABA decreased the saltiness intensity. Both the intensity of juiciness and tenderness of patties containing GABA also scored lower than the control, based on the NaCl reduction. These results were consistent with the quality characteristics (cooking loss and texture profile analysis). Nevertheless, overall acceptability of the pork patties showed that up to 1.5%, patties containing GABA did not significantly differ from the control. Consequently, the results indicated that GABA has a potential application in meat products, but also manifested a deterioration of quality by the NaCl reduction, which warrants further exploration.

• The Korean Journal of Ecology
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• 제20권4호
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• pp.275-283
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• 1997

Vertical and temporal characteristics of desalinized reclaimed soil were analyzed from reclaimed coastal land on the western coast of Korea. Of the vertical changes during desalting, pH valuse were the lowest at the topsoil without regard to reclaimation time. The content of C1 were designated as the early period (the first 2-4 years) which decreased exponentially and the later period(the last 5-7 years) which was almost constant, from top to down. In temporal changes of the soil attributes, pH values increased for 5 years and decreased at 6 year after reclamation. Chlorine leaches more rapidly than Na does, K and Ca are constant but Mg increases as time elapsed after reclamation. Sometimes the content of Ca and K in the reclaimed soil are of higher concentration than that of the seawater after reclamation. During desallinization as exemplified by decreasing EC of the soil, Cl and Na are rapidly leached, but K, Ca and Mg are somewhat enhanced. The ration of Na/Cl in the soil equals 1 when the EC registers 5 mmho and then increases dramatically as the EC decreases. Rapid leaching of $Cl^{-}$ elicits an increasing pH valus. The electrostatic balance of the soil is achived by replacement of $Cl^{-}$ with $OH^{-}$ until stationary or until a decreasing pH value is reached again.

• The Korean Journal of Physiology and Pharmacology
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• 제8권5호
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• pp.259-264
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• 2004

Cytolysin produced by Vibrio vulnificus has been incriminated as one of the important virulence determinants in V. vulnificus infection. Ion selectivity of cytolysin-induced pores was examined in a CPAE cell, a cell line of pulmonary endothelial cell, using inside-out patch clamp techniques. In symmetrical NaCl concentration (140 mM), intracellular or extracellular application of cytolysin formed ion-permeable pores with a single channel conductance of $37.5{\pm}4.0$ pS. The pore currents were consistently maintained after washout of cytolysin. Replacement of $Na^+$ in bath solution with monovalent ions $(K^+,\;Cs^+\;or\;TEA^+)$ or with divalent ions $(Mg^{2+},\;Ca^{2+})$ did not affect the pore currents. When the NaCl concentration in bath solution was lowered from 140 to 60 and 20 mM, the reversal potential shifted from 0 to -11.8 and -28.2 mV, respectively. The relative permeability of the cytolysin pores to anions measured at $-40\;mV\;was\;Cl^-\;=\;NO_2^-\;{\geq}\;Br^-\;=\;I^-\;> \;SCN^-\;>\;acetate^-\;>\;isethionate^-\;>\;ascorbic acid^-\;>\;EDTA^{2-},$ in descending order. The cytolysin-induced pore current was blocked by $CI^-$ channel blockers or nucleotides. These results indicate that V. vulnificus cytolysin forms anion-selective pores in CPAE cells.

• 대한수의학회지
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• 제38권2호
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• pp.280-289
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• 1998

Voltage-sensitive ion channels contribute to establishment of the cell excitablity and the generation of the cellular function. At hamster oocytes in the primitive stage during developing process, an inward current elicited by voltage pulses was found to be carried mainly by $Ca^{2+}$. Even at present, $Ca^{2+}$ channels serve as the most probable route to pass this inward current but there is no evidence of the presence of this channels in eggs. To date, both the characteristic properties and the physiological role in the early stage of development remain unclear. Here we examined the characteristic properties of the inward current and changes in this currents at unfertilized oocytes, fertilized zygotes and two-cell embryos using whole-cell voltage clamp technique. The inward current carried reportedly by $Ca^{2+}$ was remained following removing external $Ca^{2+}$ but completely abolished by further replacement of impermeants such as tetramethylammonium ion ($TMA^+$) or $choline^+$ instead of $[Na^+]_0$. Tetrodotoxin did not affect on this inward current remained at $[Ca^{2+}]_0$-free condition. Removal of $Na^+$ ion out of the experimental solution clearly decreased the current. After adding 2mM $Ca^{2+}$ to the $Na^+$-free media, the inward current was restored. Interestingly, this current carried by either $Ca^{2+}$ or $Na^+$ was decreased by the reduction of intracellular $Cl^-$ concentration, or by $Cl^-$ channel blockers such as niflumic acid, DIDS and SITS. When $Cl^-$ concentration was lowered without changes in other ionic components, this inward current was reduced. At fertilized oocytes and two-cell embryos, the inward current carried by $Ca^{2+}$ and $Na^+$ was severely reduced. Also $Cl^-$ component could not be observed. From these results, the inward current is composed of $Ca^{2+}$, $Na^+$ and $Cl^-$ component, suggesting that the channel carrying this inward current is not selective specifically to $Ca^{2+}$. During early stage of development, the voltage-sensitive ion current seems not to contribute essentially to the cell cleavage and differentiation. The loss of $Cl^-$ component after fertilization suggests that $Cl^-$ may play a role in maintaining the viability of unfertilized ova.

• 자원환경지질
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• 제29권2호
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• pp.105-117
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• 1996

The Baegjeon Au-Ag and Sb deposits, small of disseminated-type gold deposits are formed as a result of epithermal processes associated a shallow-seated Cretaceous Yeogdun granitoids intrusion. The orebodies are formed by the replacement of carbonate minerals in thin-bedded oolitic limestone beds favorable for mineralization within the upper-most Cambrian Pungchon Limestone Formation. The mineralization can be recognized one stage, ore minerals composed of base metal sulfides, electrum, AgSb-S, Ag-Cu-S, and Sb-S minerals. Gold-bearing minerals consist of electrum and submicroscopic invisible gold in pyrite and arsenopyrite. The composition of electrums ranges from 33.58 to 63.48 atomic % Ag. Fluid inclusion studies reveal that ore fluids were low saline $NaCl-CO_2-H_2O$ system. Temporary fluid mixing and boiling occured in later stage. Fluid inclusion data indicates the homogenization temperatures and salinities of NaCl eqivalent wt% were 176 to $246^{\circ}C$ and from 0.0 to 4.8 wt%, respectively. And $-logfs_2$, of mineralization obtained by thermodynamic considerations as 12.4 to 13.8 atm. The ${\delta}^{34}S_{H_2S}$, values of hydrothermal sulfides were calculated to be 6.8 to 10.2‰ which was of sedimentary origin. The ${\delta}^{18}O_{H_2O}$ and ${\delta}^{13}C_{CO_2}$, range from -3.9 to 9.6‰, from -1.1 to -2.2‰, and ${\delta}D$ range from -89 to -118‰, respectively. The Au deposition during mineralization seems to have occurred as a result of decrease of temperature, $fs_2$, $fo_2$, and pH probably due to oxidation by meteoric water mixing, which destabilized original $Au(HS)^-{_2}$. The mineralization of the Baegjeon deposits is similar to the Carlin-type deposits characterized by sediments-hosted epithermal bedding replacement disseminated gold deposits.

• 분석과학
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• 제5권1호
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• pp.1-5
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• 1992

Amberlite XAD 고분자수지 및 고분자수지 대체흡착제인 rice bran, rice straw 그리고 sawdust에 대한 petroleum oil의 흡착량을 최저 흡착조건에서 뱃치법으로 측정하여 조사하였다. Rice bran과 rice straw에 대한 petroleum oil의 흡착량은 XAD계열수지의 흡착량의 약 50% 정도로 흡착성이 우수하였다. 또한 이들 대체흡착제의 흡착능을 증대시키기 위한 탄화시간은 $200^{\circ}C$, 30분이 최적 조건이었다. Sawdust의 경우에는 30% MeOH 매질에서는 흡착성이 매우 약한 반면 0.5M NaCl 매질에서는 XAD수지 흡착능이 약 1/2에 도달하였다. Rice bran과 rice straw는 외관상의 구조차이와는 관계없이 비슷한 흡착능력을 보였다. 따라서 rice bran과 rice straw들은 XAD계열 수지에 대한 대체흡착제로 충분한 흡착능력을 가지고 있는 것으로 보인다.

• Journal of Animal Science and Technology
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• 제47권6호
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• pp.1009-1016
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• 2005

본 연구는 유화형 소시지 제조 시 첨가되는 NaCl을 sodium citrate, potassium lactate 및 calcium ascorbate로 부분(40%) 대체하여 소시지를 제조한 다음 소시지의 품질특성에 미치는 영향을 비교하고자 실시하였다. 소시지의 pH는 sodium citrate 대체 소시지가 대조구와 다른 대체 소시지에 비해 높았다(P<0.05). 소시지의 명도(L*) 값은 sodium citrate 대체 소시지가 대조구와 다른 대체 소시지에 비해 높았다(P<0.05). 적색도(a*) 값은 potassium lactate 대체 소시지가 대조구와 다른 대체 소시지에 비해 높았지만, 황색도(b*) 값은 낮았다(P<0.05). 조직특성에서 단단함 정도를 나타내는 경도와 점착성은 sodium citrate 대체 소시지가 대조구와 다른 대체 소시지에 비해 높았다. NaCl 대체 소시지의 나트륨 함량은 대조구에 비해 낮았고, calcium ascorbate 대체 소시지가 가장 낮은 함량을 나타내었다(P<0.05). 소시지의 칼륨과 철 함량은 potassium lactate 대체 소시지가 대조구와 다른 대체 소시지에 비해 높았다(P<0.05). NaCl 대체 소시지의 칼슘 함량은 대조구에 비해 높았고, calcium ascorbate 대체 소시지가 가장 높은 함량을 나타내었다(P<0.05). 관능평가에서 짠맛은 sodium citrate 대체 소시지가 대조구와 다른 대체 소시지에 비해 높았다(P<0.05). 풍미는 calcium ascorbate 대체 소시지가 대조구에 비해 높았다(P<0.05). 이상의 결과에서, NaCl 대체 소시지는 pH, 색도 및 관능평가에서 대조구와 차이를 보였으며, 나트륨 함량을 낮추고 칼슘 함량이 증가한 건강지향적인 소시지를 생산할 수 있을 것으로 사료된다.

• Tribology and Lubricants
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• 제19권3호
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• pp.159-166
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• 2003

This research for replacement of chlorine or sulfur based EP(extreme pressure) -additives which is restricted materials by environmental regulation. The subject of this study is as follows, 4-ball test and friction coefficient test were experimented in accordance with temperature and velocity, compounding with several organic or inorganic metallic elements. After 4-ball test, wear area of steel ball was analysed by SEM-EDX. As the analysis, organic and inorganic elements make a effect for extreme pressure lubricity. It is shown that the friction coefficient of lubricant which includes chlorine or sulfur additives, the scoring phenomenon is found accord-ing to temperature and the scuffing phenomenon at 200$^{\circ}C$. Applying to Na, P, S, Zn, Ca based on inorganic and organic elements, the result showed that friction coefficient is decreased more and more, as increasing temperature of lubricant. The additive based on S, Cl, P elements is effect far extreme pressure in the sample#1 and Na, P, S, Zn, Ca in sample #2. These elements are environmental contaminants and S, Cl based on EP additives which are very popular in domestic industry, when they are properly composed with non-chlorine based on additives and Na, P, S, Zn, Ca organic or inorganic elements. It is showed that lubricity and excellent anti-wear properties.