• Title/Summary/Keyword: Na-24

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Conversion of Beef Tallow and Its Mixed Fat into Biodiesel by Alkali Catalysts (알칼리 촉매에 의한 우지(Beef Tallow)와 그 혼합지방의 Biodiesel화)

  • Hyun, Young-Jin;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.190-195
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    • 2007
  • The transesterifications of beef tallow and the mixture of beef tallow and rapeseed oil were conducted at $65^{\circ}C$ respectively using TMAH, NaOH and their mixed catalysts. The reactants were emulsified with 1vol% emulsifier and propylene glycol. The overall conversion of beef tallow was 95% at such optimum conditions as the 1:8 of molar ratio and 0.8 wt% TMAH. The overall conversion of mixed fat at the 1:8 of molar ratio and mixed catalyst of 70 wt% TMAH 30 wt% NaOH was close to 97% which appeared at 0.8 wt% TMAH in 80min. And the kinematic viscosity of biodiesel mixture using the mixed catalyst was $6.5mm^2/s$ at $40^{\circ}C$.

AN EXPERIMENTAL STUDY ON EFFECT OF BLEACHING (표백효과에 관한 실험적 연구)

  • Lee, Myung-Chong;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.2 no.1
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    • pp.11-14
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    • 1976
  • The purpose of this study was to the observe effects of the various bleaching agents on blood clot. Absorbent papers(N9.5) were coated with O type blood and were dried in shadow for 72 hours. Bleaching agents used were 5% NaOCl 30% $H_2O_2$, saturated solutions of $NaBO_3$ $4H_2O$, $Ca(OCl)_2$ and $Na_2O_2$ at $20^{\circ}C$. After the specimens, blood cloted papers were dipped in 10CC of solution for 1 minute, 5 minutes, 30 minutes, 2 hours and 24 hours, specimens were washed with distilled water and dried. Hue Value/Chroma contrived by Munsell was measured in each specimen. The following results were obtained. 1. Superoxol changes 2.5YR 4.5/2 into N9.5 (white) after 24 hours. 2. All bleaching agents except superoxol change YR into Y.

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A Study on Renin-Angiotensin System and Total Exchangeable Sodium in Hypertension (고혈압(高血壓)에 있어서 Renin-Angiotensin계(系) 및 총교환(總交換) 나트륨에 관(關)한 연구(硏究))

  • Choe, Kang-Won;Park, Jung-Sik;Lee, Jung-Sang;Koh, Chang-Soon
    • The Korean Journal of Nuclear Medicine
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    • v.10 no.1
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    • pp.1-14
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    • 1976
  • The etiologic role of renin-angiotensin system and sodium-volume status in the pathophysiology of various forms of hypertension was investigated. Plasma renin activity (PRA) was measured by radioimmunoassay, while sodium-volume status was evaluated by the determination of total exchangeable sodium(NaE) using isotope dilution method. The subjects consisted of 25 controls, 24 patients with essential hypertension, with chronic renal failure (13 with hypertension, 9 without hypertension) and with malignant hypertension. The results were as follows: 1. An inverse correlation between NaE and PRA was noted in control subjects (r=-0.598, p<0.001) and normal renin essential hypertension(r=-0.551, p<0.05) and the chronic renal failure with hypertension. (r=-0.790, p<0.001) 2. NaE increased markedly the in chronic renal failure with hypertension ($66.9{\pm}8.69mEq/kg$ of LBM, p<0.001) and the chronic renal failure without hypertension ($54.9{\pm}9.28mEq/kg$ of LBM, p<0.05), while mild increase was noted in malignant hypertension ($51.7{\pm}6.24mEq/kg$ of LBM, 0.05$50.1{\pm}7.24mEq$) as well as in its renin subgroups.(p>0.1) 3. Absolute value of PRA was not deviated significantly from control group ($2.53{\pm}1.416ng/ml/hr$) except in malignant hypertension ($6.09{\pm}2.042$, p<0.001). But PRA was inappropriately high in relation to prevailing NaE in the chronic renal failure with hypertension (eleven of thirteen patients) and malignant hypertension (ten of fourteen patients), while PRA variatiation was within physiologic range in the chronic renal failure without hypertension. 4. The NaE-PRA product was markedly increased in the chronic renal failure with hypertension ($514.4{\pm}42.10$, p<0.001) and in malignant hypertension ($442.7{\pm}55.03$, p<0.001), while moderately increased NaE-PRA product was noted in the chronic renal failure without hypertension ($402.6{\pm}59.67$, p<0.001). No significant difference in NaE-PRA product was noted in essential hypertension ($354.4{\pm}62.38$, p>0.1). It is suggested that renin-angiotensin system plays a predominant role in the pathogenesis of malignant hypertension and in hypertension of chronic renal failure, though sodium retention is also contributing factor. PRA variation in essential hypertension does not appear to be associated with any consistent change in Na-volume status, suggesting the existence of another mechanism in the genesis of hypertension and PRA variation.

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Formation of (TEACOOH)-Montmorillonite Intercalations Complex and Polycondensation between the Layers of the Complex ((TEACOOH)-Montmorillonite 층간화합물의 형성 및 층 내에서의 고분자화 반응)

  • Yun, Do-U;Jo, Seong-Jun
    • The Journal of Engineering Research
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    • v.7 no.1
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    • pp.79-87
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    • 2005
  • [TEACOOH]-Montmorillonite intercalations complex obtained from Na-Montmorillonite and 10-Carboxy-n-decyldimethylethylammonium bromide(organic cation) was reacted with the monomer($\varepsilon$-caprolactone) to achieve the [TEACOOH]-$\varepsilon$-caprolactone-Montmorillonite intercalations complex. From intercalations complex Montmorillonite/Polycaprolactone Nanocomposite in which montmorillonite(inorganic material) is chemically linked with the polycaprolactone(organic polymer) was formed at $220^{\circ}C$ for 48 h. The basal spacing for the sample obtained after polymerization, extraction with methanol and dried at $65^{\circ}C$ in high vacuum for 24 h was 50.7 $\AA$.

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Apatite Formation Behavior on Bioactive Glasses with Glass Composition and Reaction Solution (생체유리에서 유리조성과 반응용액에 따른 아파타이트 형성)

  • 이재희;이정웅;김철영
    • Journal of the Korean Ceramic Society
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    • v.37 no.11
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    • pp.1105-1113
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    • 2000
  • Bioglass 조성 중 45S5 (46.1SiO$_2$.24.4$Na_2$O.26.9CaO.2.6P$_2$O$_{5}$ : 몰비)를 기본 조성으로 하여 46P4 (46.2SiO$_2$.49.5CaO.4.3P$_2$O$_{5}$ : 몰비), 46SF (46.1SiO$_2$24.4$Na_2$O.16.1CaO.2.6P$_2$O$_{5}$.10.8CaF : 몰비) 그리고 55SF (55.1SiO$_2$.9.2$Na_2$O.27.8CaO.3.4P$_2$O$_{5}$.4.5CaF : 몰비)를 제조하여 tris-완충용액 및 유사 생체용액(simulated body fluid)에서 반응시킨 후 생체활성유리의 표면에 생성되는 아파타이트 결정형에 관하여 연구하였다. 45S5 유리를 tris-완충용액에 반응시켰을 경우 6시간 반응시부터 수산화 아파타이트가 생성되었으나 유사 생체용액에 반응시켰을 경우에는 24시간까지도 수산화 아파타이트 결정이 생성되지 못하고 비정질 상태의 칼슘 인산염만 형성되었다. tris-완충용액에 각 조성의 유리를 200시간 반응시킨 경우 불소를 함유하지 않은 유리에서는 잎사귀 모양의 수산화 아파타이트가, 불소를 함유한 유리에서는 구상의 플루오르 아파타이트가 형성되었다. 그러나 유사 생체용액에 각 조성의 유리를 200시간 반응시켰을 경우 불소를 함유하지 않은 유리에서는 누에고치형의 수산화 아파타이트가 형성되었고 불소를 함유한 유리에서는 무정형의 칼슘 인산염이 생성되었다.

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ESTIMATION OF ALUMINUM AND ARGON ACTIVATION SOURCES IN THE HANARO COOLANT

  • Jun, Byung-Jin;Lee, Byung-Chul;Kim, Myung-Seop
    • Nuclear Engineering and Technology
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    • v.42 no.4
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    • pp.434-441
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    • 2010
  • The activation products of aluminum and argon are key radionuclides for operational and environmental radiological safety during the normal operation of open-tank-in-pool type research reactors using aluminum-clad fuels. Their activities measured in the primary coolant and pool surface water of HANARO have been consistent. We estimated their sources from the measured activities and then compared these values with their production rates obtained by a core calculation. For each aluminum activation product, an equivalent aluminum thickness (EAT) in which its production rate is identical to its release rate into the coolant is determined. For the argon activation calculation, the saturated argon concentration in the water at the temperature of the pool surface is assumed. The EATs are 5680, 266 and 1.2 nm, respectively, for Na-24, Mg-27 and Al-28, which are much larger than the flight lengths of the respective recoil nuclides. These values coincide with the water solubility levels and with the half-lives. The EAT for Na-24 is similar to the average oxide layer thickness (OLT) of fuel cladding as well; hence, the majority of them in the oxide layer may be released to the coolant. However, while the average OLT clearly increases with the fuel burn-up during an operation cycle, its effect on the pool-top radiation is not distinguishable. The source of Ar-41 is in good agreement with the calculated reaction rate of Ar-40 dissolved in the coolant.

A Study on Sodium and Potassium Balance of College Women in Seoul (서울지역 일부 여대생의 나트륨과 칼륨평형에 관한 연구)

  • 이영근;승정자;최미경
    • Korean Journal of Community Nutrition
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    • v.4 no.3
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    • pp.375-381
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    • 1999
  • The purpose of this study was to investigate Na and K balances in healthy adult women. Anthropometric assessments, biochemical analysis of blood, 3-day dietary flood records and collections of 3-day food, 24-hr urine and faces were performed to evaluate intakes and excretions of Na and K in 20 college women living in Seoul. The mean BMI and blood pressure of the subjects were 21.08 and 110.25/67.50mmHg, respectively. Mean daily intake of energy was 1578.84kcal, 79% of Korean RDA. Also, daily intakes of Na and K ware 120.86mEq and 44.20mEq. The urinary and fecal excretions of Na were 99.88 and 4.45mEq/day, and those of K were 30.41 and 8.66mEq/day, respectively. The body retention, retention rate, and apparent absorption of Na were 17.11mEq, 13.23%, and 96.31%, and those of K were 5.82mEq, 8.69%, and 80.12%, respectively. The urinary and fecal Na/K ratio were 3.48 and 0.52. There were significantly positive correlations between 1) urinary Na, K excretions and intakes of Na or K, 2) urinary K and BMI, 3) serum K and serum globulin, and 4) urinary Na excretion and serum haptoglobin level, respectively. The results of this study show that Na intake was higher and K intake was lower than those of other advanced nations. Therefore, nutrition education show instruct people to reduce Na intake and to increase K intake.

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A Study on Method for Screening of Hypercalciuria in Children (소아에서 소변 Na/K 비를 통한 칼슘 배설량 예측)

  • Ko Han Seong;Choi Jeong Hoon;Choi Byoung Min;Yoo Kee Hwan;Hong Young Sook;Lee Joo Won;Kim Soon Kyum
    • Childhood Kidney Diseases
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    • v.4 no.1
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    • pp.11-16
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    • 2000
  • Purpose. Urinary calcium excretion using a 24-hr urine colledtion has been used for the diagnosis of hypercalciuria up to now. But It takes a lot of time and costs much. We have investigated on a more simple method for screening of hypercalciuria in children. Methods: We had retrospectively analyzed sodium, potassium, calcium and creatinine in spot urine of eighty-four patients with urinary symptoms from May 1998 to July 1998 in Korea university Guro hospital and compared the urinary Ca/Cr ratio with the Nin ratio. Using a urinary Nan ratio >2.68 as a cutoff value in predicting the occurrence of hypercalciuria, we measured its sensitivity, specificity, positive predictive value and the negative predictive value. Results: A direct relationship was found between urinary Na/K and Ca/Cr ratio (r=0.496, P<0.001, Ca/Cr : Na/K x 0.0167+0.061). Using a urinary Na/K ratio >2.68 as a cutoff value in predicting the occurrence of hypercalciuria, its sensitivity was found to be $100\%$ and its specificity $54.5\%$. The positive predictive value was $37.5\%$ and the negative predictive value $100\%$. Conclusions : Spot urine Na/K ratio is a valuable test for the screening of hypercalciuria in children.

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Interaction between norepinephrine and angiotensin II on Na+ uptake in primary cultured rabbit renal proximal tubule cells (초대배양한 토끼 신장 근위세뇨관세포의 Na+ uptake에 대한 norepinephrine 과 angiotensin II의 상호작용)

  • Park, Soo-hyun;Koh, Hyun-ju;Han, Ho-jae
    • Korean Journal of Veterinary Research
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    • v.38 no.3
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    • pp.525-534
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    • 1998
  • 신장 근위세뇨관세포들은 사구체에서 여과된 물질의 재흡수, 분비 및 대사에 관여하는 여러 호르몬들의 수용체들을 가지고 있다. 이들중에서 norepinephrine(NE)과 angiotensin II(ANG II)는 $Na^{+}/H^+$ 상호운반계를 조절함으로써 혈압조절에 관여하는 것으로 알려져 있으나 이들의 상호관계에 대해선 연구보고가 많지 않다. 본 연구는 초대배양한 토끼신장 근위세뇨관세포를 이용한 $Na^+$ uptake 실험을 통하여 NE이 어떠한 수용체를 통하여 $Na^{+}/H^+$ 상호운반계를 조절하는지 그리고 이러한 작용에 있어서 NE과 ANG II의 상호관계를 알아보고자 실시하였다. NE(>$10^{-9}M$)은 $Na^+$ uptake를 유의성 있게 증가시켰다($10^{-9}M$ NE : $27{\pm}4%$ increase vs. Control;p < 0.05). $\alpha$ 길항제(phentolamine, $10^{-10}M$)는 NE($10^{-9}M$)에 의해 유도된 $Na^+$ uptake를 유의성 있게 차단하였으나 (phentolamine+NE : $29{\pm}5%$ inhibition vs. NE ; p〈 0.05), ${\alpha}_1$ (pra-zosin, $10^{-10}M$) 및 ${\alpha}_2$ 길항제(yohimbine, $10^{-10}M$)는 부분적으로 차단하였다. ${\beta}$ 길항제(propra-nolol, $10^{-10}M$)도 역시 NE에 의해 유도된 $Na^+$ uptake를 유의성 있게 차단하였으나(propranolol+NE : $24{\pm}6%$ inhibition vs. NE ; p< 0.05), ${\beta}_1$(atenolol, $10^{-10}M$) 및 ${\beta}_2$ 길항제(butoxamine, $10^{-10}M$)는 부분적으로 차단하였다. 이러한 결과들은 NE에 의해 유도된 $Na^+$ uptake 증가작용은 ${\alpha}$(${\alpha}_1$${\alpha}_2$ )와 ${\beta}$(${\beta}_1$${\beta}_2$) 수용체 모두를 통하여 일어난다는 것을 시사해주고 있다. ANG II($10^{-11}M$) 또는 NE(${\alpha}_1$, ${\alpha}_2$, ${\beta}_1$, ${\beta}_2$ 작동제) 단독처리군의 $Na^+$ uptake는 대조군에 비해 유의성 있게 증가하였으나 (ANG II : $23{\pm}9%$ increase vs. Control; p < 0.05), 병합처리시 상승작용은 나타나지 않았다. ${\alpha}$ 또는 ${\beta}$ 길항제 처리시 NE 및 ANG II에 의해 유도되었던 $Na^+$ uptake 증가는 유의성 있게 차단되었다(phentolamine+NE+ANG II : $25{\pm}3%$ inhibition, propranolol+NE+ANG II : $24{\pm}6%$ inhibition vs. NE+ANG II, respectively ; p〈 0.05). 이 결과들은 $Na^+$ uptake에 있어서 ${\alpha}$(${\alpha}_1$${\alpha}_2$)와 ${\beta}$(${\beta}_1$${\beta}_2$) 수용체와 ANG II의 관련성을 시사해 준다. 결론적으로 토끼 신장 근위세뇨관세포에서 NE은 ${\alpha}_1$, ${\alpha}_2$, ${\beta}_1$${\beta}_2$ 수용체를 통하여 $Na^+$+ uptake를 증가시켰으며 이들 수용체는 ANG II $Na^+$ uptake 증가작용에 관여하였다.

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