• Title/Summary/Keyword: NR-SBR

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Studies on it's practical Application to Auto Pneumatic tyre and Manufacture of CBR (Part 1.) On the Blend of CBR and SBR (CBR의 제조(製造) 및 이를 자동차(自動車) tyre에 활용(活用)하는데 관(關)한 연구(硏究)(제1보(第一報)) CBR와 SBR의 Blend에 관(關)하여)

  • Lee, Hyan-O;Lee, Young-Kil
    • Elastomers and Composites
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    • v.6 no.1
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    • pp.53-70
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    • 1971
  • We have studied the blending effects of cis-1,4-polybutadiene (CBR) and styrene-tutadiene rubber at various blending ratios of 100 : 0, 70 30, 50 : 50, 30 : 70, 0 : 100, and of carbon black ISAF and HAP at various compounding ratios of 45 PHR, 55 PHR, 65 PHR, for tyre tread rubber. The results obtained are summerized as follows; 1. For tyre tread rubber, it was found to increased efficiency to use SBR polymer only than to use the blending ratio CB/SBR=30/70 below. But it was observed that the latter was adapted for the bus or truck tyre and the former for the passenger tyre. 2. Excellent efficiency was obtained in case of carbon black compounding ratio of 55%, and also the compounding of ISAF made better efficiency than that of HAF. 3. Carbon black was more efficient to SBR than to CB. 4. For the aging ratio, the compounding rubber of NR was the highest, and the ratio was decreased in order of the compounding rubber of oil-extended SBR or CB polymer only, the compounding rubber of non oil-extended SBR or CB polymer only, and the blending rubber.

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Studies on the Quality Reinforcement for Pneumatic Tire and Tube (Part 7) Physical properties of various portions of SBR high contained tire (Tire 및 Tube의 품질보강(品質補强)에 관(關)한 연구(硏究) (제7보(第7報)) 합성(合成)고무를 다량혼용(多量混用)한 각부위(各部位)의 이화학적(理化學的) 성능(性能))

  • Kim, Joon-Soo;Lee, Myung-Whan;Yum, Hong-Chan;Lee, Chin-Bum;Park, Chang-Ho;Hong, Jong-Myung;Im, Dong-Ho;Lee, Hai-Ryong
    • Elastomers and Composites
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    • v.5 no.2
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    • pp.181-187
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    • 1970
  • In vulcanizates of NR/SBR blending compounds, the physical properties decrease as the contents of SBR increase for the most part. but the abrasives showed reverse performance. However, since these conditions enough satisfy the requirements of tread, carcass and sidewall of tire, we found it was possible to take use of the quantity of SBR contained high on tire manufacturing.

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Studies on the Quality Reinforcement for Pneumatic Tire and Tube (Part 4). Physical Properties of Various Portions of a Tire made of NR-Syn. R. blends (Tire 및 Tube의 품질보강(品質補强)에 관(關)한 연구(硏究)(제4보(第4報)) 천연(天然)고무에 합성(合成)고무를 혼용(混用)한 각(各) 부위(部位)의 응용배합(應用配合)에 따른 성능(性能))

  • Kim, Joon-Soo;Lee, Myung-Whan;Yum, Hong-Chan;Lee, Chin-Bum;Park, Chang-Ho;Hong, Chong-Myung;Im, Dong-Ho
    • Elastomers and Composites
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    • v.4 no.1
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    • pp.83-88
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    • 1969
  • As a part of a series of previous studies, physical properties of various portions of a tire made of NR-Syn. R bloods were studied. 1. It was found, in general, most effective for tire tread when 50 parts of HAF black was blended with NR and Syn. R with a ratio of 70/30. 2. It was found that the use of SBR 1712 has an advantage in price, easy processing and physical properties than other synthetic rubber. 3. A technical compounding of various portions of a tire has to be determined for optimum cure conditions.

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Elastomeric High Barrier Materials for Vehicle (고차단성 자동차 부품용 고무소재)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.2-9
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    • 2011
  • Permeability to gases and vapors is an important function in tires, rubber tubes and diaphragms. It mainly depends on the rubber material. Generally, permeability increases in the following order: silicone rubber > NR > EPDM > SBR > NBR > FPM > ECO > IIR. And, for an elastomer permeability is also very much dependent on compounding. Many research works are reported in the area of gas permeability for formed rubber,$^{1-7}$ however, few studies are found for unformed elastomer products. Incorporation of nano-particles, use of thermoplastic elastomers and applying high barrier multilayer coatings are the main approaches to obtain a high barrier elastomeric product. In this paper, barrier article for vehicle is introduced.

Studies on the Inflammability and Heat Resistance of Conveyer Rubber Belts (콘베어 고무벨트의 난연성(難燃性) 및 내열성(耐熱性)에 관(關)한 연구(硏究))

  • Oh, Pyoung-Je
    • Elastomers and Composites
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    • v.16 no.4
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    • pp.211-216
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    • 1981
  • A series of conveyer rubber belts has been made by blending natural rubber(NR), styrene butadiene rubber(SBR), chloroprene rubber(CR) and additives on nylon cords, and their respective flammability has been investigated. It has been observed that: 1. By adding an antiflame agent to the belt, in addition to 70% chlorinated paraffine and antimony oxide($Sb_{2}O_{3}$), the inflammability is improved remarkably to O - 2 seconds due to the synergistic effect, while a sample without antiflame B fails to pass the KS M 6678 test. 2. Physical properties, such as tensile strength, elongation at break and adhesion strength, of the sample belts have been studies by varying ratios of NR/CR from 20 to 100, and it has been observed that the higher ratios have the better physical properties.

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Carbofuran Cytotoxicity on Rat Fibroblast Cells and Compensation Effects of Phenobarbital Sodium and 3-Methycholanthrene on Its Toxicity (살충제 Carbofuran이 쥐의 NIH3T3 섬유모세포에 끼치는 독성 및 Phenobarbital Sodium과 3-Methylcholanthrene에 의한 보상효과)

  • Han, Seong-Soo;Rim, Yo-Sup
    • Korean Journal of Environmental Agriculture
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    • v.16 no.2
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    • pp.149-155
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    • 1997
  • This study was carried out to investigate the effects of phenobarbital sodium(PB) and 3-methylcholanthrene(3-MC) on carbofuran cytotoxicity and to develop antitoxic agents based on the effectivness. Experimental groups for carbofuran cytotoxicity were divided into five groups ; medium alone and four treatments of carbofuran (1, 25, 50 and $100{\mu}M)$, and those for compensation effects were divided into six groups ; medium alone, $IC_{50}$ carbofuran and four combinations of carbofuran and PB or 3-MC($IC_{50}$ carbofuran plus 1, 25, 50, $100{\mu}M$ of PB and 3-MC, respectively). After incubation for 48 hrs under the same conditions, MTT(Tetrazolium MTT), NR(Neutral red) and SRB(Sulforhodamine B protein) assay were performed. Fifty percentage inhibition of MTT, NR, and SRB against carbofuran in rat fibroblast cell were 60.7, 82.5 and $87.0{\mu}M$, respectively. At the combination treatments of $IC_{50}$ of carbofuran and $100{\mu}M$ of PB, the significant compensation effects were observed from the results of MTT and NR but not from that of SRB absorbance. And at the combination treatments of $IC_{50}$ of carbofuran and 3-MC, the relatively significant compensation effects were found at $50{\mu}M$ 3-MC from the results of MTT and at $100{\mu}M$ 3-MC from that of NR and SRB absorbances, respectively. From the results of light microscopy, combination treatments of $carbofuran(IC_{50})$ and PB or 3-MC showed good regeneration in carbofuran toxicity of rat fibroblast cells. These results suggest that PB or 3-MC can compensate the cytotoxity of carbofuran insecticide in rat NIH3T3 fibroblast cells.

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Studies on analysis of Rubber Vulcanizates by Pyrolysis-Gas Chromatography (II) (NBR, CR, and EPDM Vulcanizates) (Pyrolysis-Gas Chromatography를 이용한 가황 고무의 열분석에 관한 연구(II) (NBR, CR 및 EPDM 가황체))

  • Huh, D.S.;Kim, J.S.;Kim, K.J.;Ahn, B.K.;Suh, S.K.
    • Elastomers and Composites
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    • v.22 no.4
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    • pp.314-323
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    • 1987
  • A blend ratio of rubber vulcanzates comprising NBR, CR, EPDM, NR, BR, and SBR alone or blended is determind through a P.G.C. It is found that a characteristic peak of elastomer is proportional to the content of each elastomer when they are pyrolysed. It is also classified to the different AN content in NBR vulcanizates, identification of sulfur-modified and non-sulfur bearing CR polymers, and the content of ethylene, propylene monomer and the third monomer in EPDM vulcanizetes.

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Development of the Novel Cosmetics Impregnation Material and Study on Makeup W/O Emulsions using It (새로운 화장료 함침재의 개발과 이를 활용한 메이크업 유중수형 에멀전에 관한 연구)

  • Kang, Sungsoo;Kim, Hyeon Jeong;Oh, Se Woong;Park, Sang Wook;Kim, Kyung Seob
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.1
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    • pp.27-33
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    • 2017
  • Up to now, better convenience and portability were important factors in the development of the cosmetics and achieved by immersing low viscosity makeup water-in-oil (W/O) emulsion into the impregnation material. Conventionally, polyurethane sponges having porous network structures and hard textures have been dominantly used. It has an advantage of easy to manufacture because of its good impregnation property due to its structural characteristics. However, it releases emulsion too much at first use, and shows unexpected dramatic decline during the period of usage. In this study, we studied on makeup W/O emulsion with various features and developed the new foaming sponge, which showed excellent formability and proper absorption and discharge ability of cosmetic composition through the combination of natural rubber (NR) and styrene butadiene rubber (SBR). This impregnation material is characterized by the softness of elasticity like a rubber, high elongation and uniform output. We confirmed that this material can be used to develop makeup products using various oils depending on polarity and controlling the viscosity of the makeup W/O emulsion. Thus, it is concluded that these results provide valuable information in developing new cosmetics impregnation materials.

Determination of Strain Energy Function of Rubber Materials Considering Stress Softening Behavior (응력연화거동을 고려한 고무 재료의 변형률 에너지 함수 결정)

  • Kim, W.S.;Hong, S.I.
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.168-176
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    • 2007
  • When the rubber vulcanizates reinforced with carbon black or silica are subjected to cyclic loading from its virgin state, the stress required on reloading is less than that on the initial loading. This stress softening phenomenon is referred to as the Mullins effect. The strain energy function of rubber vulcanizates was investigated using theory of pseudo-elasticity incorporated damage parameter that Ogden and Roxburgh have proposed to describe the damage-induced stress softening effect in rubber-like solids. The quasi-static cyclic loading test was performed using the NR-SBR vulcanizates reinforced with carbon black, and then the effect of a damage parameter to stress-strain curve in reloading and subsequent reloading paths was studied. The strain energy function of the rubber vulcanizates with a different filler content was also evaluated.

Studies on the Vulcanization Characteristics of Rubber-Bound Antioxidants (반응성노화방지제(反應性老化防止劑)의 가황특성(加黃特性)에 관(關)한 연구(硏究))

  • Paik, Nam-Chul
    • Elastomers and Composites
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    • v.14 no.2
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    • pp.83-102
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    • 1979
  • The purpose of this dissertation is to study some of the vulcanization characteristics of rubber-bound antioxidants such as G-1, [N-(3-methacryloyloxy-2-hydroxypropyl)-N'-phenyl-p-phenylene diamine] and acryl, acrylamide & acrylester substituted hindered phenols. The influence of these antioxidants upon vulcanization characteristics in NR and SBR compounds in the presence of vulcanizing accelerators such as MSA, TT, DM, M & D was evaluated by means of Oscillationg Disk Cure Meter. The comparison was also made between the influence of rubber-bound antioxidants and that of conventional non-reactive antioxidants such as N-alkyl substituted PADA series. Regarding the influence of reactive type antioxidant G-1 mixed with accelerator TT upon vulcanization characteristics, rapid onset of vulcanization and higher degree of cross-linking were discovered, whereas in the case of accelerator M and DM, the result was slow onset of vulcanization and lesser degree of cross-linking. The comparison of vulcanizing characteristics among acrylic substituted hindered phenols as antioxidants was made under several vulcanization accelerator systems. Under such systems, MSA-S combined accelerator caused the onset of vulcanization to slow down and lowered the degree of cross-linking. Finally in the case of hindered phenol derivatives containing longer substituent, the delayed onset of vulcanization and the lowered degree of cross-linking could be discerned.

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