• 제목/요약/키워드: NOx concentration

검색결과 451건 처리시간 0.026초

First Simultaneous Visualization of SO2 and NO2 Plume Dispersions using Imaging Differential Optical Absorption Spectroscopy

  • Lee, Hanlim;Noh, Youngmin;Kwon, Soonchul;Hong, Hyunkee;Han, Kyung-Soo
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권4호
    • /
    • pp.1191-1194
    • /
    • 2014
  • Imaging Differential Optical Absorption Spectroscopy (Imaging-DOAS) has been utilized in recent years to provide slant column density (SCD) distributions of several trace gas species in the plume. The present study introduces a new method using Imaging-DOAS data to determine two-dimensional plume structure from the plume emissions of power plant in conditions of negligible aerosol effects on radiative transfer within the plume. We demonstrates for the first time that two-dimensional distributions of sulfur dioxide ($SO_2$) and nitrogen dioxide ($NO_2$) in power plant emissions can be determined simultaneously in terms of SCD distribution. The $SO_2$ SCD values generally decreased with increasing distance from the stack and with distance from the center of the plume. Meanwhile, high $NO_2$ SCD was observed at locations several hundred meters away from the first stack due to the ratio change of NO to $NO_2$ in NOx concentration, attributed to the NO oxidation by $O_3$. The results of this study show the capability of the Imaging-DOAS technique as a tool to estimate plume dimensions in power plant emissions.

부실식 정적연소실내 층상혼합기의 연소특성(II) (Combustion Characteristics of Stratified Mixture in a Constant Volume Combustion Chamber with Sub-chamber (II))

  • 김봉석;권철홍;류정인
    • 한국자동차공학회논문집
    • /
    • 제3권5호
    • /
    • pp.122-134
    • /
    • 1995
  • The present study was investigated combustion characteristics of methane-air mixtures at stratified charge in a constant volume combustion chamber. The main results obtained from this study can be summarized as follows. In case of ${\phi}_s=1.0$, total burning times greatly affected rather than initial time of pressure increase and maximum combustion pressure. In case of ${\phi}_t=1.0$, initial time of pressure increase and total burning times were affected considerably in comparison with the case of ${\phi}_s=1.0$. Also, even the very lean mixture which total equivalence ratio is ${\phi}_t=0.69$(${\phi}_s=1.0$, ${\phi}_m=0.65$), by changing configuration of the critical passage-hole and using a stratified mixture, it is possible to decrease substantially the initial time of pressure increase. total burning times and NOx concentration without deteriorating combustion characteristics such as maximum combustion pressure, rate of heat release etc. in comparison with the use of single chamber(in case of ${\phi}=1.0$) only. Specifically, our trends were revealed remarkably in the case of Type D which is reduced a flame contact area of sub-chamber side of the passage-hole.

  • PDF

V8형 TCI 디젤기관의 배출가스저감 및 성능개선에 관한 연구 (A Study on the Emission Reduction and Performance Improvement in a V8 Type TCI D.I. Diesel Engine)

  • 윤준규;임종한
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제29권4호
    • /
    • pp.443-452
    • /
    • 2005
  • The purpose of this study is experimentally to analyze the effects of intake port swirl, injection system and turbocharger on the engine performance and the emission characteristics in a V8 type turbocharger intercooler D.I. diesel engine of the displacement 16.7L, and to suggest the improvement of engine performance. Generally to enhance engine power, TCI diesel engine is put to practically use turbocharged intercooler in order to increase volume efficiency which is cooled boost air. As results of considering the factors of the intake port of swirl ratio 2.25, compression ratio 17.5. re-entrant $8.5^{\circ}$ combustion bowl, nozzle hole diameter ${\phi}0.33{\ast}3+{\phi}0.35{\ast}2$. nozzle protrusion 3.18mm, injection timing BTDC $12^{\circ}CA$ and turbocharger(compressor 0.6A/R+46Trim. turbine 1.0 A/R+57Trim) is the best in the full load in the engine performance and the exhaust characteristics of NOx concentration. Therefore. their factors are appropriated as intake system, injection and turbocharger system.

소형 어선용 디젤기관의 운전조건과 부탄올 혼합유의 배기 배출물 특성에 관한 연구 (A study on exhaust emission characteristics according to operating conditions and butanol blended fuels in a small diesel engine for fishing vessel)

  • 김상암;왕우경
    • 수산해양기술연구
    • /
    • 제57권3호
    • /
    • pp.256-263
    • /
    • 2021
  • In this study, blending oils of diesel oil and butanol were used as fuel oil for diesel engine to measure combustion pressure, fuel consumption, air ratio and exhaust gas emission due to various operating conditions such as engine revolution and torque. Using these data, the results of analyzing the engine performance, combustion characteristics and exhaust emission characteristics such as NOx (nitrogen oxides), CO2 (carbon dioxide), CO (carbon monoxide) and soot were as follows. The fuel conversion efficiency at each load was highest when driven in the engine revolution determined by a fixed pitch propeller law. Except 30% butanol blending oil, fuel conversion efficiency of the other fuel oils increased as the load increased. Compared to diesel oil, using 10% and 20% butanol blending oil as fuel oil was advantageous in terms of thermal efficiency, but it did not have a significant impact on the reduction of exhaust gas emissions. On the other hand, future research is needed on the results of the 20% butanol blending oil showing lower or similar levels of smoke concentration and carbon monoxide emission rate other than those types of diesel oil.

황산암모늄 주입시 CFBC 보일러의 오염물질 특성 연구 (A Study on the Characteristics of Pollutants in CFBC Boiler with Ammonium Sulfate Injection)

  • 이창열;정복화;정진도
    • 한국폐기물자원순환학회지
    • /
    • 제35권8호
    • /
    • pp.754-761
    • /
    • 2018
  • There is growing concern over the effects of global warning. In response, the power generation sector must consider a wider range of systems and fuels to generate power. One of the classes of solid fuels that is being increasingly developed is biomass. However, one of the most serious problems that biomass plants face is severe corrosion. To mitigate the problem, various approaches have been proposed in terms of additive utilization. This study is based on the results obtained during the co-combustion of wood chip and waste wood in a circulating fluidized bed boiler (CFBC boiler). The KCl concentration was reduced from 59.9 ppm to 3.9 ppm during the injection of ammonium sulfate, and NOx was reduced by 25.5 ppm from 30.6 ppm to 5.1 ppm. However, SOx increased by 110.2 ppm from 33.2 ppm to 143.4 ppm, and HCl increased by 71.5 ppm from 340.5 ppm to 412.0 ppm. Thus, we confirmed that the attitude of the superheater tube was reduced by 87 ~ 93%, and the injection of ammonium sulfate was effective in preventing high-temperature corrosion.

Removal of NOx using electron beam process with NaOH spraying

  • Shin, Jae Kyeong;Jo, Sang-Hee;Kim, Tae-Hun;Oh, Yong-Hwan;Yu, Seungho;Son, Youn-Suk;Kim, Tak-Hyun
    • Nuclear Engineering and Technology
    • /
    • 제54권2호
    • /
    • pp.486-492
    • /
    • 2022
  • Nitrogen oxides (NOx; NO and NO2) are major air pollutants and can cause harmful effects on the human body. Electron Beam Flue Gas Treatment (EBFGT) is a technology that generates electrons with an energy of 0.5-1 MeV using electron accelerators and effectively processes exhaust gases. In this study, NOx was removed using an electron beam accelerator with spraying additives (NaOH and NH4OH). NO and NO2 were 100% and more than 94% removed, respectively, at an electron beam absorbed dose of 20 kGy and an additive concentration of 0.02 M (mol/L). In most cases, NOx was removed better with lower initial NOx concentrations and higher electron beam absorbed doses. As the irradiation strength (mA) of the electron beam increases, the probability of electron impact on the material accordingly rises, which may lead to increase removal efficiency. The results of the present study show that the continuous electron beam process using additives achieved more effective removal efficiency than either individual process (wet-scrubbing or EB irradiation only).

고농도 알코올 혼합 석유제품이 자동차 성능 및 배출가스에 미치는 영향 연구 (The Study on Effect of Emissions and Performance of a Conventional Vehicle using the High Concentration Alcohol Blended Petroleum Product)

  • 김성우;도진우;김기호;하종한
    • 한국수소및신에너지학회논문집
    • /
    • 제26권6호
    • /
    • pp.629-637
    • /
    • 2015
  • As concern about energy security and global warming many countries have been making effort to reduce fossil fuel. In the case of US, as one of the efforts, the standards of the alcohol vehicle fuels(including blended with gasoline) have been established. Alcohol is known that make some trouble concerning startability, durability and corrosion when using as fuel of a conventional vehicle. For these reason, alcohol usage needs not only the fuel standard, but also a modified car. In the case of Korea, although there are no the standard and the modified vehicle yet, high concentration alcohol blended fuel has being sold at illegal market. In this study, exhaust gas and performance of the conventional vehicle that alcohol(methanol and isopropyl alcohol) blends were fueled were measured to notify danger of using them without preparation of institutional arrangements. Also, to analyze correlation characteristics of the fuels and them, property test of the fuels was conducted. The test result show that bad-startability caused by low RVP and high T10 affected increase in NMOG and CO. NOx was increased under the highest short term fuel trim caused by high Oxygen content and low NHV of alcohol. According to increasing as alcohol content, fuel economy and acceleration ability were decreased but $CO_2$ was not significantly decreased.

Enhancement of L-Lactic Acid Production in Lactobacillus casei from Jerusalem Artichoke Tubers by Kinetic Optimization and Citrate Metabolism

  • Ge, Xiang-Yang;Qian, He;Zhang, Wei-Guo
    • Journal of Microbiology and Biotechnology
    • /
    • 제20권1호
    • /
    • pp.101-109
    • /
    • 2010
  • Efficient L-lactic acid production from Jerusalem artichoke tubers, by Lactobacillus casei G-02, using simultaneous saccharification and fermentation (SSF) in a fed-batch culture, is demonstrated. A kinetic analysis of the SSF revealed that the inulinase activity was subjected to product inhibition, whereas the fermentation activity of G-02 was subjected to substrate inhibition. It was also found that the intracellular NADH oxidase (NOX) activity was enhanced by the citrate metabolism, which dramatically increased the carbon flux of the Embden-Meyerhof-Parnas (EMP) pathway, along with the production of ATP. As a result, when the SSF was carried out at $40^{\circ}C$ after an initial hydrolysis of 1 h and included a sodium citrate supplement of 10 g/l, an L-lactic acid concentration of 141.5 g/l was obtained after 30 h, with a volumetric productivity of 4.7 g/l/h. The conversion efficiency and product yield were 93.6% of the theoretical lactic acid yield and 52.4 g lactic acid/l00 g Jerusalem artichoke flour, respectively. Such a high concentration of lactic acid with a high productivity from Jerusalem artichokes has not been reported previously, making G-02 a potential candidate for the economic production of L-lactic acid from Jerusalem artichokes on a commercial scale.

유동층을 이용한 유,무연탄 혼합 연소로에서 대기오염물질 생성과 연소효율 연구 (A Study on Production of Air Pollutants and Combustion Efficiency of Anthracite-Bituminous Coal Blend Combustor Using Fluidized Bed)

  • 조상원;민병철
    • 공업화학
    • /
    • 제8권3호
    • /
    • pp.517-523
    • /
    • 1997
  • 본 연구는 유동층연소로에서 유,무연탄 혼합연소시 대기오염물질 발생과 연소효율에 관하여 실험하였으며, 실험결과는 다음과 같다. 유동층연소로 높이가 증가할수록 이산화황과 질소산화물의 농도는 증가하는 것으로 나타났으며, 무연탄 혼합비가 증가할수록 이산화황의 농도는 증가하였으나 질소산화물농도는 큰 변화가 없었다. 무연탄 혼합비가 증가할수록 비산유출율도 증가하였고 주입 가연성분에 대한 유출 가연성분비도 증가하였다. 또한, 무연탄 혼합비에 관계없이 비산유출입자의 평균입경에 따른 미연분 함량은 미세입자에서 대체로 높게 나타났다. 한편, 연소효율은 층온도 $850^{\circ}C$, 과잉공기 20% 이상에서 큰 차이를 보이지 않았으므로 유속 0.3m/s, 층온도 $850^{\circ}C$, 과잉공기비 20%의 조건으로 혼합연소시키는 것이 적절한 것으로 나타났다.

  • PDF

디젤엔진에서 배기가스 재순환 방법을 이용한 아산화질소의 배출률 저감 (Reduction of Nitrous Oxide Emission by EGR Method on Diesel Engine)

  • 유동훈
    • 동력기계공학회지
    • /
    • 제19권3호
    • /
    • pp.16-21
    • /
    • 2015
  • Nitrous oxide($N_2O$) concentration in the atmosphere has been constantly increased by the human activities with industrial growth after the industrial revolution. One of factors to increase $N_2O$ concentration in the atmosphere is the $N_2O$ emission caused by the combustion of marine fuel. Especially, a sulfur component included in marine fuel oils is known as increasing the $N_2O$ formation in diesel combustion. Form this point of view, $N_2O$ emission from a ship is not negligible. On the other hand, Exhaust gas recirculation(EGR) that have thermal, chemical and dilution effect is effective method for reducing the NOx emission. In this study, an author investigated $N_2O$ reduction by using EGR on a direct injection diesel engine. The test engine was a 4-stroke diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of the engine was a fixed load of 75%. The experimental oil was a blend-fuel that were adjusted with sulfur ratio of 3.5%, and EGR ratio of 0%, 10%, 20% and 30%. In conclusion, diesel fuel that contained 3.5% sulfur component increased $SO_2$ emission in exhaust gas, and increment of EGR ratio reduced NO emission. Moreover, $N_2O$ emission was decreased as over 50% at EGR ratio of 10% and reduced 100% at EGR ratio of 30% compared with $N_2O$ emission of 0% EGR ratio.