• Title/Summary/Keyword: NOx Formation

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Effect of Water Induction on the Performance and Exhaust Emissions in a Diesel Engine (II)

  • Ryu, Kyunghyun;Oh, Youngtaig
    • Journal of Mechanical Science and Technology
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    • v.18 no.9
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    • pp.1640-1647
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    • 2004
  • This study was to investigate the effects of water induction through the air intake system on the characteristics of combustion and exhaust emissions in an IDI diesel engine. The fuel injection timing was also controlled to investigate a method for the simultaneous reduction of smoke and NOx when water was injected into the combustion chamber. The formation of NOx was significantly suppressed by decreasing the gas peak temperature during the initial combustion process because the water played a role as a heat sink during evaporating in the combustion chamber, while the smoke was slightly increased with increased water amount. Also, NOx emission was significantly decreased with increase in water amount. A simultaneous reduction in smoke and NOx emissions was obtained when water was injected into the combustion chamber by retarding more 2$^{\circ}C$A of the fuel injection timing than without water injection.

A Study on the Simultanious Reduction of Smoke and NOx by Water Injection through Intake Port in Diesel Engine (디젤기관에서 흡기관내로의 물 분사에 의한 매연과 NOx의 동시 저감에 관한 연구)

  • Ryu, Kyung-Hyun;Oh, Young-Taig
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.2186-2191
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    • 2003
  • This study is to investigate the effects of water induction through the air intake system on the characteristics of combustion and exhaust emissions in diesel engine. The effects of water induction through the air intake port were considered in IDI diesel engine in this study. The formation of NOx was significantly suppressed by decreasing the gas peak temperature during the initial combustion process because the water play a role as a heat sink during evaporating in the combustion chamber, but the smoke was slightly increased with increased water amount. Also, NOx significantly decreased with increase in water amount. A simultaneous reduction in smoke and NOx emissions can be obtained when water is injected into the combustion chamber by retarding the fuel injection timing more than without water injection.

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Porous Photocatalytic Concrete Filter Manufacturing and Efficiency Evaluation for NOx Reduction (NOx 저감을 위한 다공성 광촉매 콘크리트 필터 제조 및 효율평가)

  • Kim, Jong Kyu
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.223-229
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    • 2022
  • A porous photocatalyst concrete filter was successfully produced to remove NOx, by mixing TiO2 photocatalyst with lightweight aerated concrete. Ultra Fine Bubbles were used to form continuous pores inside the porous photocatalytic concrete filter, which was mixed via a bubble generation experiment. The optimal mixing condition was determined to be with 4 % of the bubble generation agent B. NO removal specimens were prepared for various photocatalytic loading conditions, and the specimen containing 3 % P-25 removed NO at a concentration of 1.03 µmol in 1 h. The NO removal rate of the porous photocatalytic concrete filter prepared in this study was 10.99 %. This photocatalytic filter performance was more than 9 times the amount of NO removed by a general photocatalytic filter. The porous photocatalyst concrete filter for removing NOx developed in this study can be applied to various construction sites and the air quality can be solved by reducing NOx contributing to the formation of fine particles.

Hydrogen Enrichment Effects on NOx Formation in Pre-mixed Methane Flame (수소 첨가가 예혼합 메탄 화염의 NOx 생성에 미치는 영향)

  • Kim, H.S.;Ahn, K.Y.;Gupta, A.K.
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.1
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    • pp.75-84
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    • 2007
  • The effects of hydrogen enrichment to methane on NOx formation have been investigated with swirl stabilized pre-mixed hydrogen enriched methane flame in a laboratory-scale pre-mixed combustor(nominally of 5,000 kcal/hr). The hydrogen enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame stability was examined for different amount of hydrogen addition to the methane fuel, different combustion air flow rates and swirl strengths by comparing equivalence ratio at the lean flame limit. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using gas analyzers, and OH chemiluminescence techniques to provide information about species concentration of emission gases and flowfield. The results of NOx and CO emissions were compared with a diffusion flame type combustor. The results show that the lean stability limit depends on the amount of hydrogen addition and the swirl intensity. The lean stability limit is extended by hydrogen addition, and is reduced for higher swirl intensity at lower equivalence ratio. The addition of hydrogen increases the NOx emission, however, this effect can be reduced by increasing either the excess air or swirl intensity. The NOx emission of hydrogen enriched methane premixed flame was lower than the corresponding diffusion flame under the fuel lean condition.

The Optimization of Fuel Injection Nozzles for the Reduction of NOx Emissions in a Large Diesel Engine (대형 디젤엔진의 NOx 저감을 위한 연료분사노즐 최적화 연구)

  • Yoon, Wook-Hyeon;Kim, Byung-Seok;Kim, Dong-Hun;Kim, Ki-Doo;Ha, Ji-Soo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.6
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    • pp.60-65
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    • 2004
  • Numerical simulations and experiments have been carried out to investigate the effect of fuel injection nozzles on the combustion and NOx formation processes in a medium-speed marine diesel engine. Spray visualization experiment was performed in the constant-volume high-pressure chamber to verify the numerical results on the spray characteristics such as spray angle and spray tip penetration. Time-resolved spray behaviors were captured by high-speed digital camera and analyzed to extract the information on the spray parameters. Spray and combustion phenomena were examined numerically using FIRE code. Wave breakup and Zeldovich models were adopted to describe the atomization characteristics and NOx formation processes. Numerical results were verified with experimental data such as cylinder pressure, heat release rate and NOx emission. Finally, the effects of fuel injection nozzles on the engine performance were investigated numerically to find the optimum nozzle parameters such as fuel injection angle, nozzle hole diameter and number of nozzle holes. From this study, the optimum fuel injection nozzle (nozzle hole diameter, 0.32 mm, number of nozzle holes, 8 and fuel injection angle, $148^{\circ}$) was selected to reduce both the fuel consumption and NOx emission. The reason for this selection could be explained from the highest fuel-air mixing in the early phase of injection due to the longest spray tip penetration and the highest heat release rate after $19^{\circ}$ ATDC due to the increased injection duration.

Assessment and Estimation of Particulate Matter Formation Potential and Respiratory Effects from Air Emission Matters in Industrial Sectors and Cities/Regions (국내 산업 및 시도별 대기오염물질 배출량자료를 이용한 미세먼지 형성 가능성 및 인체 호흡기 영향 평가추정)

  • Kim, Junbeum
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.4
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    • pp.220-228
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    • 2017
  • Since the fine particulate matters occurred from mainly combustion in industry and road transport effect to human respiratory health, the interest and importance are getting increased. In 2013, the World Health Organization (WHO) concluded that outdoor air pollution is carcinogenic to humans, with the particulate matter component ($PM_{10}$ and $PM_{2.5}$) of air pollution most closely associated with increased cancer incidence, especially cancer of the lung. Therefore, many researches have been studied in the quantification and data development of fine particulate matters. Currently, the Ministry of Environment and cities/regions are developing the fine particulate matter data and air emission information. Particularly just $PM_{10}$ and $PM_{2.5}$ data is used in the fine particulate matters warning and alert. The data of NOx, SOx, $NH_3$, which have the particulate matter formation potential are not well considered. Also, the researches related with particulate matter formation potential and respiratory effects by industrial sectors and cities/regions are not conducted well. Therefore, the purpose of this study is to evaluate and calculate particulate matter formation potential and respiratory effects in 11 industrial sectors and cities using NOx, SOx, $PM_{10}$, $NH_3$ data (developed by Ministry of Environment and National Institute of Environmental Research) in 2001 and 2013. The results of this study will be provided the particulate matter formation potential and respiratory effects and will be used for future the fine particulate matter researches.

The Role of Oxygen Atom in the NOx Formation of DME/Air Nonpremixed Flames (DME/Air 비예혼합화염의 NOx 생성에서 산소원자의 역할)

  • Kim, Tae-Hyun;Hwang, Cheol-Hong;Lee, Seung-Ro;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.14 no.1
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    • pp.9-18
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    • 2009
  • The NOx emission characteristics of DME in counterflow nonpremixed flames were investigated numerically, and brief experiments were carried out to compare the flame shapes and NOx emissions with those of $C_{3}H_{8}$ and $C_{2}H_{6}$. The DME flames were calculated using Kaiser's mechanism, while the $C_{2}H_{6}$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show that DME flame has the characteristics of partial premixed flame and the flame length becomes very shorter compared with general hydrocarbon fuels and then, the NOx emission of DME is low as much as 60 % of $C_{3}H_{8}$. In the calculated results of counterflow nonpremixed flames, the $EI_{NO}$ of DME nonpremixed flame is low as much as 50 % of the $C_{2}H_{6}$ nonpremixed flame. The cause of $EI_{NO}$ reduction is attributed mainly to the characteristics of partial premixed flame due to the existence of O atom in DME and partly to the O-C bond in DME, instead of C-C bond in hydrocarbon fuels.

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A Study on the Optimization of Fuel Injection Nozzle Geometry for Reducing NOx Emission in a Large Diesel Engine (대형 디젤 엔진의 연료 분사 노즐 형상이 NOx 발생량 및 연료소비율에 미치는 영향 연구)

  • Kim Ki-Doo;Ha Ji-Soo;Yoon Wook-Hyeon
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.7
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    • pp.1123-1130
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    • 2004
  • Numerical simulations have been carried out to investigate the effect of nozzle hole geometry on the combustion characteristics of the large diesel engine. 6S90MC-C. Spray and combustion phenomena were examined numerically using FIRE code. Wane breakup and Zeldovich models were adopted to describe the atomization characteristics and NOx formation processes. Predictions on the cylinder peak pressure and NOx emission were first verified with the experimental data to confirm the reliability of numerical calculations. The comparison results showed good agreements within the range of 0.64% and 4.6% respectively. Finally, the effects of fuel spray angle and diameter on the engine performance were investigated numerically to find the optimum nozzle hole geometry considering fuel consumption, NOx emission and heat flux of the combustion chamber wall. It was concluded that the combustion gas recirculation in cylinder by changing fuel injection direction is an effective method to reduce NOx emission by about 10% with increasing fuel oil consumption, 1.4% in a large diesel engine.

Experimental Study on the NOx Emission Characteristics of Low Calorific Value(LCV) Gas Fuel at Premixed Combustion Condition (저 발열량 가스 연료의 예혼합 연소시 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan;Yun, Yong-seung
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.11a
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    • pp.23-29
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value (LCV) coal derived gas fuel. Synthetic LCV fuel gas is produced by mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas. The syngas mixture is fed to and burnt with air on flat flame burner. With the variation of the equivalence ratio for specific syngas fuel, flame behaviors are observed to identify the flame instability due to blow-off or flashback and to define stable combustion range. Measurements of NOx content in combustion gas are made for comparing thermal and fuel NOx from the LCV syngas combustion with those of the natural gas one. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique, and its effects on thermal and fuel NOx production are discussed.

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Formation of MILD Combustion using Co-flow MILD Combustor (동축류 마일드 연소기를 적용한 마일드 연소 형성 연구)

  • Lee, Pil Hyong;Hwang, Sang Soon
    • Journal of the Korean Society of Combustion
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    • v.22 no.3
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    • pp.8-16
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    • 2017
  • MILD combustion was first developed to suppress thermal NOx formation in combustor for heating industrial furnaces. In this paper, the effect of co-flow MILD combustor geometry and operating conditions on the formation of MILD combustion was analyzed using 3 dimensional numerical simulation. The numerical simulations were carried out using ANSYS Fluent. The combustion and turbulence flow was modeled using the Eddy Dissipation Concept(EDC) model and realizable $k-{\varepsilon}$ model respectively. The results show that the high temperature region and average temperature decreased due to an increase in the air velocity and decrease the wall thickness of fuel nozzle. In particular, the MILD combustion flame was found to be stable with a combustion flame region at fuel velocity 10 m/s, air velocity 20 m/s, fuel nozzle thickness 1.0 mm, equivalence ratio 0.9, and outlet area ratio 40%.