• Title/Summary/Keyword: NOx Formation

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Multidimensional Engine Modeling: NO and Soot Emissions in a Diesel Engine with Exhaust Gas Recirculation

  • Kim, Hongsuk;Nakwon Sung
    • Journal of Mechanical Science and Technology
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    • v.15 no.8
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    • pp.1196-1204
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    • 2001
  • The effects of EGR(Exhaust Gas Recirculation) on heavy-duty diesel engine performance, NO and soot emissions were numerically investigated using the modified KIVA-3V code. For the fuel spray, the atomization model based on the linear stability analysis and spray wall impingement model were developed for the KIVA-3V code. The Zeldovich mechanism for the formation of nitric oxide and the soot model suggested by Hiroyasu et al. were used to predict the diesel emissions. In this paper, the computational results of fuel spray, cylinder pressure, and emissions were compared with experimental data, and the optimum EGR rates were sought from the NO and soot emissions trade-off. The results showed that the EGR is effective in suppressing NO but the soot emission was increased considerably by EGR. Using cooled EGR, soot emission could be enhanced without worsening of NO.

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The Function of Halogen Additive in $CH_4/O_2/N_2$ Flames ($CH_4/O_2/N_2$ 화염에서 할로겐 첨가제의 역할)

  • Lee, Ki-Yong;Shin, Sung-Su
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.209-214
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    • 2003
  • Numerical simulations are performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, the radical concentration, the NOx formation in freely propagating $CH_4/O_2/N_2$ flames. The additives used are carbon dioxide and hydrogen chloride which have a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, $CO_2$ addition significantly contributes toward the reduction of flame speed and flame temperature by the physical effect, whereas addition of HCl mainly does by the chemical effect. The impact of HCl addition on the decrease of the radical concentration is about 1.6-1.8 times as large as $CO_2$ addition. Hydrogen chloride addition is higher on the reduction of EINO than $CO_2$ addition because of the chemical effect of HCl.

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Exhaust gas purification characteristics of M-90 fueled SI engine for passenger car (자동차용 M-90 스파크 점화기관의 배기가스 정화특성)

  • 김재휘;홍영표
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.4
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    • pp.43-49
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    • 1996
  • With the recent interest in methanol as a SI engine fuel, aldehyde emissions have become a greater concern. A M-90 fueled passenger car was operated in a chassis dynamometer using FTP 75 driving cycle to examine formaldehyde emissions. Formation process of aldehyde and methods to reduce them are discussed in this paper for a SI-engine passenger car operating by M-90. Aldehyde emissions have been found to be 3 to 7 times higher from M-90 than from gasoline, while CO, NOx, THC are as low or lower than gasoline. Noble metal compositions appeared to play a role in formaldehyde and unburned methanol emission performance. For example, catalyst Pd showed better reduction of both formaldehyde and methanol than catalyst Pt. however, emission rates of formaldehyde and methanol for catalyst Pt were relatively similar to catalyst Pt/Rh.

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Combustion Characteristics of Flameless Combustion by Reactants Injection Conditions (반응물 분사조건에 따른 무화염 연소특성 연구)

  • Hong, Seong Weon;Lee, Pil Hyong;Hwang, Sang Soon
    • Journal of the Korean Society of Combustion
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    • v.18 no.2
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    • pp.8-16
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    • 2013
  • The flameless combustion has been considered as one of the promising combustion technology for high thermal efficiency, reducing NOx and CO emissions. In this paper, the effect of air and fuel injection condition on formation of flameless combustion was analyzed using three dimensional numerical simulation. The results show that the high temperature region and the average temperature was decreased due to increase of recirculation ratio when air velocity is increased. The average temperature was also affected by entrainment length. Generally mixing effect was enhanced at low entrainment length and dilution was dominated at high entrainment length. This entrainment length was greatly affected by air and fuel injection velocity and distance between air and fuel. It is also found that the recirculation ratio and dilution effect were generally increased by entrainment length and the recirculation ratio, mixing and dilution effect are the significant factor for design of flameless combustion system.

Effect of Vortex Generator in Intake Pipe on the Moisture Concentration Distributions and Combustion Performance in a CI Engine (흡기관내 와류생성기가 압축착화엔진의 수분 농도 분포 및 연소성능 향상에 미치는 영향)

  • Jeong, Seok Hoon;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.169-174
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    • 2018
  • In this work, optimization of blade shape for the improvement of mixture formation and vortex of intake port was performed by numerically, and the combustion performance of CI engine with optimized blade shape was investigated. To achieve this, 3 types of blade shape were studied under the different air flow mass conditions and the numerical results were investigated in terms of humidification water, moisture concentration, and velocity distributions. Evaporated liquid mass was also compared under various test conditions to reveal the turbulent intensity in an intake port. It was observed that the optimized blade shape can improve the humidification water, moisture concentration, and velocity distributions of intake port inside. The evaporated liquid mass was also increased under the conditions with blade. Especially, low NOx emissions was observed with optimized blade condition.

The Pollutant Emission Characteristics of Lean-Rich Combustion System with Exhaust Gas Recirculation (배기가스 재순환을 적용한 희박-과농 연소시스템의 공해물질 배출특성 연구)

  • Oh, Wheesung;Lee, Chang-Eon;Yu, Byeonghun
    • Journal of the Korean Society of Combustion
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    • v.20 no.2
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    • pp.28-35
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    • 2015
  • In this study, the CH4/air lean-rich combustion system with exhaust gas recirculation (EGR) was investigated to explore the potential for lowering pollutant emissions. To achieve this purpose, experiments of lean-rich combustion system with EGR were conducted to measure the changes in the characteristics of the pollutant emission and flame shape with various equivalence ratios and EGR rates. Here, this study was applied to the fuel distribution ratio of 3:1 for the formation of the lean and rich flames. Additionally, the results were compared with $CH_4$/air lean premixed combustion system. The results show that flame shape of lean-rich combustion system was determined by lean and rich equivalence ratios (${\Phi}_L$ and ${\Phi}_R$) and stratified flame was formed with increasing ${\Phi}_R$. According to the pollutant emission characteristics based on experimental results, the NOx and CO emission index (EINOx and EICO) decreased with increasing EGR rate. Especially, in the range needed to form a stable flame, the reduction rates of EINOx and EICO were approximately 47% and 48% for an EGR rate of 25%, global equivalence ratio of 0.85 and ${\Phi}_L$ of 0.80 compared with lean premixed combustion system (${\Phi}$ = 0.78).

Analytical Study on Re-solidification Materials(Ammonium Carbonate Intermediates) for NOx Reduction of Exhaust Emissions in Diesel Engine with Solid SCR (디젤엔진 배출가스 질소산화물 저감을 위한 Solid SCR용 Ammonium Carbonate 중간생성물인 재응고 물질의 분석 연구)

  • Shin, Jong Kook;Lee, Hoyeol;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.4
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    • pp.152-159
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    • 2014
  • Urea solution as a reductant of SCR has been widely used to reduce NOx emissions from diesel engine. But it has lots of problems which are freezing at low temperature due to liquid state, deposition of solid formation in the exhaust, dosing device, and complex package such as mixers for uniform concentration of ammonia. In order to overcome these obstacle, ammonium carbonate which is one of solid ammonium materials to produce ammonia gas directly by sublimation process is considered. Simple reactor with visible widow was designed to predict equilibrium temperature and pressure of ammonium carbonate. To simulate real operation conditions under automobile environment, several cycles of heating and cooling condition were settled, two different re-solidification materials were extracted from the reactor and visible window. Analytical study is performed to characterize these unknown materials by XRD(X-Ray Diffraction), FT-IR(Fourier Transform Infrared Spectroscopy), and EA(Elemental Analyzer). From analytical results, re-solidification materials from heating and cooling cycles are very similar to original material of ammonium carbonate.

Effect of Intake Flow Control Method on Part Load Performance in SI Engine(2) - EGR Characteristics and Comparison of Dilution Method (스파크점화기관에서 흡기제어 방식이 부분부하 성능에 미치는 영향(2) - EGR 특성과 희석 방법의 비교)

  • Kang, Min Gyun;Ohm, Inyong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.4
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    • pp.121-130
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    • 2014
  • This paper is the second investigation on the effects of intake flow control methods on the part load performance in a spark ignition engine. In the previous work, two control methods, port throttling and masking, were compared with respect to lean misfire limit, fuel consumption and emissions. In this work, the effects of these two methods on EGR characteristics were studied and simultaneously the differences between EGR and lean combustion as a dilution method were investigated. The results show that EGR limit is expanded up to 23% and 3 ~ 5% improvement in the fuel consumption are achieved around 8 ~ 13% rates by the flow controls comparing with 10% limit and 1.5% reduction around 3% rate of non-control case. The masking method is more effective on the limit expansion than throttling as like as lean misfire limit; however there is no substantial difference in fuel consumptions improvement regardless the control methods except high load condition. Also it is observed that there exist critical EGR rates around which the combustion performance and NOx formation change remarkably and these rates generally coincide with optimum rates for the fuel consumption. In addition, dilution with fresh air is much more advantageous than that of the exhaust gas from the view point of dilution limit and fuel consumption, while utilization of the exhaust gas is more effective on NOx reduction in spite of considerably small dilution compared with the use of fresh air. Finally, the improvement of fuel consumption by massive EGR is highly dependent on the EGR limit at which the engine runs stably, therefore the stratified combustion technique might be a best solution for this purpose.

A Study on Combustion and Emission Characteristics in Compression Ignition CRDI Diesel Engine (직접분사식 압축점화 디젤엔진의 연소 및 배기특성에 관한 연구)

  • Kim, Gi-Bok;Choi, Il-Dong;Ha, Ji-Hoon;Kim, Chi-Won;Yoon, Chang-Sik
    • Journal of the Korean Society of Industry Convergence
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    • v.17 no.4
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    • pp.234-244
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    • 2014
  • Recently it has been focused that the automobile engine has developed in a strong upward tendency for the use of the high viscosity and poorer quality fuels in achieving the high performance, fuel economy, and emission reduction. Therefore it is not easy to solve the problems between low specific fuel consumption and exhaust emission control at motor cars. In this study, it is designed and used the engine test bed which is installed with turbocharger and intercooler. In addition to equipped using CRDI by controlling injection timing with mapping modulator, it has been tested and analyzed the engine performance, combustion characteristics, and exhaust emission as operating parameters, and they were engine speeds(rpm), injection timing(bTDC), and engine load(%). From the result of an experimental analysis, peak cylinder pressure and the rate of pressure rise were increased, and the location of it was closer toward top dead center according to the increasing of engine speed and load, and with advancing injection timing. The combustion characteristics are effected by fuel injection timing due to be enhanced the mass burned fraction. Using the engine dynamometer for analyzing the engine performance, the engine torque and power have been enhanced according to advancing the fuel injection timing. In analyzing of exhaust emission, there has been a trade-off between PM and NOx with increasing of engine speed and load, and with advanced injection timing. The experimental data are shown that the formation of NOx has increased and PM, vice versa.

Characteristic Evaluation of SCR catalyst using Aluminum dross (알루미늄 폐드로스를 활용한 SCR 탈질촉매 제조 및 특성평가)

  • Bae, Min A;Kim, Hong Dae;Lee, Man Sig
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.10
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    • pp.4672-4678
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    • 2013
  • Aluminum dross is formation at the surface of the molten metal as the latter reacts with the furnace atmosphere and it was an unavoidable by-product of the aluminum production process. However aluminum dross was usually landfilled or disposed without treatment, causing much environmental damage. The purpose of this study is to investigate the possibility of ceramic catalyst support using recycled Al dross. The recycled Al dross was made into SCR catalyst by mixing with $WO_3$, $V_2O_5$ and $TiO_2$. The $V_2O_5-WO_3/TiO_2-Al_2O_3$ SCR catalyst was observed with XRF, XRD and BET. $V_2O_5-WO_3/TiO_2-Al_2O_3$ SCR strength was measured by Universal Testing Machine(UTM). As the added $Al_2O_3$, streagth is increased. And the NOx removal activity was observed by MR(Micro-Reactor). The temperatures ranging from $350^{\circ}C$ and $400^{\circ}C$, $V_2O_5-WO_3/TiO_2-Al_2O_3$ SCR catalyst De-NOx performance result of showed excellent activity over 90% at application condition.