• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.6
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• pp.183-194
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• 2013

Liquid urea based SCR has been used in the market to reduce NOx in the exhaust emission of the diesel engine vehicle. This system has several problems at low temperature, which are freezing below $-12^{\circ}C$, solid deposit formation in the exhaust, and difficulties in dosing system at exhaust temperature below $200^{\circ}C$. Also, it is required complicated exhaust packaging equipment and mixer due to supply uniform ammonia concentration. In order to solve these issues, solid urea, ammonium carbonate, and ammonium carbamate are selected as ammonia sources for the application of solid SCR. In this paper, basic research on reaction rate of three ammonia-transporting materials was performed. TGA (Thermogravimetric Analysis) and DTA (Differential Thermal Analysis) tests for these materials are carried out for various heating conditions. From the results, chemical kinetic parameters such as activation energy and frequency factor are obtained from the Arrhenius plot. Additionally, from test results of DSC (Differential Scanning Calorimeter) for these materials, chemical kinetic parameters using the Kissinger method are calculated. Activation energies of solid SCR from this experiment are compared with proper data of literature study, then obtained data of this experiment are used for the design of reactor and dosing system for candidate vehicle.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.8
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• pp.2721-2730
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• 1996

The present study conducted experimental study of spray combustion to investigate the effect of the inlet conditions of fuel and air on the flame structure, the flame stability and the characteristics of emission in the can-type model of a gas turbine combustor. In the experiment, the diameter of fuel droplet was measured using Malvern particle size analyser and temperatures in the combustion chamber were measured with R-type shielded thermocouple. In addition, flame structure was taken picture with camera and analysed. Gas analyser was also used to analyse the concentration of each components of exhausting gas. The experimental results showed that the flame condition was optimal with swirl number, 0.63 and equivalence ratio, 0.5 for controlling the flame stability, the combustion temperature and the NOx concentration. The present study concluded that both the flame structure and the emission formation were strongly affected by the swirl intensity, which selection was found as an important parameter for either stabilizing flame or lowering the quantity of NOx.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.3
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• pp.93-100
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• 2002

For natural gas and LPG fuel, measurements on the concentrations of individual exhaust hydrocarbon species have been made as a function of air-fuel ratio in a 2-liter four-cylinder engine using a gas chromatography. NMHC in addition to the species of HC, other emissions such as CO$_2$, CO and NOx were examined for natural gas and LPG at 1800rpm far two compression ratios (8.6 and 10.6). Fuel conversion efficiencies were also investigated together with emissions to study the effect of engine parameters on the combustion performances in gas engines especially under the lean bum conditions. It was found that CO$_2$ emission decreased with smaller C value of fuel, leaner mixture strength and the higher compression ratio. HC emissions from LPG engine consisted primarily of propane (larger 60%), ethylene and propylene, while main emissions from natural gas were mothane (larger than 60%), ethane, ethylene and propane on the average. The natural gas was proved to give the less ozone formation than LPG fuel. This was accomplished by reducing the emissions of propylene, which has relatively high MIR factor, and propane that originally has large portion of LPG. In addition, natural gas shows a benefit in other emissions (i.e. NMHC,NOx, CO$_2$and CO), SR and BSR values except fuel conversion efficiency.

• International Journal of Automotive Technology
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• v.8 no.6
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• pp.697-704
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• 2007

Recently, a variable valve timing system has been widely adopted in internal combustion engine in order to improve the fuel economy and torque at low engine speed. In addition, it is known that varying valve timing according to the various engine operations could reduce exhaust gas, especially NOx, because of residual gas by valve overlap. In this study, to improve the low exhaust gas and fuel economy at part load condition, the residual gas and back flow of exhaust gas due to valve overlap were calculated computationally. Moreover, the characteristics of engine performances and NOx formations were investigated with the experiment of combination of intake and exhaust valve timing condition. Under these various valve operating conditions, the effects of both the positive valve overlap and negative valve overlap(valve underlap) were examined simultaneously. Finally, the characteristics of cyclic THC emission were analyzed by using Fast Response FID(FR-FID) in the cylinder, intake port and exhaust port positions. Besides, the effect of the different gradients of the valve timing change on engine performance was investigated and an optimum control strategy was suggested.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.7
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• pp.275-282
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• 2016

MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.12
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• pp.1756-1762
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• 2002

To effectively meet current regulations on the exhaust emissions of diesel engine required to control the deterioration of air pollution in the whole world, this study is to investigate the effects of water induction through the air intake system on the characteristics of combustion and exhaust emissions in IDI diesel engine. A method fur supplying water through the air intake system to reduce the exhaust emissions has been considered with other methods such as water introduction in the form of water-in-fuel emulsion or water injection directly into the combustion chamber, but it has not been studied about the effects of water on the combustion concepts and the characteristics of exhaust emissions in detail until now. In this study, the formation of NOx was significantly suppressed by decreasing the gas peak temperature during the initial combustion process because the water play a role as a heat sink during evaporating in the combustion chamber, but the smoke was slightly increased by increasing water amount.

• Journal of Power System Engineering
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• v.19 no.6
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• pp.68-74
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• 2015

NOx emission has been controlled because it is a major cause of the acid rain and effects considerably on formation and destruction of ozone. A SCR system on diesel engine is necessary to clear TierIII, because IMO(International Maritime Organization) plans on tightening regulations to TierIII at $1^{st}$ January 2016. In this study, flow analysis was accomplished with ANSYS Fluent program so that the SCR system would be retrofitted in training ship KAYA and the temperature distributions of exhaust gas in SCR sytem were investigated after it was installed. As a result, it was confirmed that pressure and velocity distributions in SCR system were depended on pipe line shapes, then it was designed as the pressure was lower. The temperature differential between 1 and 3 point was $15^{\circ}C$ because of evaporative latent heat of urea and the temperature of 4 point after catalyst was increased by $5^{\circ}C$ than 3 point because of exothermic reaction.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.5
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• pp.67-77
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• 2000

Investigated was the effect of propene(C3H6) on the NO-NO2 conversion in dry exhaust gases from lean burn engine using a pulsed corona discharge. A kinetic model was developed to characterize the plasma chemistry in simulated exhausts containing propene. The model uses ELENDIF program to solve Boltzmann equation for electron energy distribution function, and CHEMKIN-II program to solve stiff ODE(ordinary differential equation) problems for species concentrations. The corona discharge energy per pulse and the time-space averaged E/N were obtained by fitting the model to experimental data. The model calculation shows good agreement for NO and NO2 concentrations with the experimental data, and predicts the formation of byproducts such as CH2O, CH3HCO, CO AND CH3NO2 Propene enhances the NOx conversion enormously at lower energy density and the NOx conversion increases with the increase of initial propene and oxygen concentration, and temperature.

• Journal of ILASS-Korea
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• v.22 no.2
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• pp.96-102
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• 2017

In order to reduce the NOx, SCR technology is most suitable. In this study, we focused on studying the injector part of urea-SCR system. When stoichiometric 1 mole of urea is injected, 2 moles of $NH_3$ are created. $NH_3$ causes a SCR reaction by reacting with NOx. However, urea is decomposed by the side reaction of coming out HNCO, deposit formation is formed. In this study, it was to design a nozzle that can spray the optimal spray flow rate. Test nozzle used in this experiment is efferverscent type. The result of the experiment, liquid flow rate was confirmed to be that they are dominated by the exit orifice diameter. The area ratio is defined by ratio of the area of exit orifice hole and that of aerorator. The droplet size was measured by varying the area ratios. In addition, it was also confirmed that there is no change of the liquid flow rate and air flow rate to change the aerorator at the same exit orifice. Further, It was confirmed that the droplet size was relatively uniform even though the area ratio was different. Finally, there is little change in the SMD that air flow rate increases in 0.3 or more ALR.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2365-2378
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• 2018

We investigated the correlation between vanadium surface density and VOx structure species in the selective catalytic reduction of NOx by $NH_3$. The properties of the $VOx/TiO_2$ catalysts were investigated using physicochemical measurements, including BET, XRD, Raman spectroscopy, FE-TEM, UV-visible DRS, $NH_3-TPD$, $H_2-TPR$, $O_2-On/Off$. Catalysts were prepared using the wet impregnation method by supporting 1.0-3.0 wt% vanadium on $TiO_2$ thermally treated at various calcination temperatures. Through the above analysis, we found that VOx surface density was $3.4VOx/nm^2$, and the optimal V loading amounts were 2.0-2.5 wt% and the specific surface area was $65-80m^2/g$. In addition, it was confirmed that the optimal VOx surface density and formation of vanadium structure species correlated with the reaction activity depending on the V loading amounts and the specific surface area size.