• 제목/요약/키워드: NOx Formation

검색결과 220건 처리시간 0.038초

무화염 형성에 영향을 미치는 유동조건에 대한연구 (Affect of Flow Condition on Formation of Flameless Combustion)

  • 홍성원;이필형;차천륜;송기종;임현진;황상순
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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    • pp.189-192
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    • 2012
  • The flameless combustion has been considered as one of the promising combustion technology for high energy efficiency and reducing NOx and CO emissions. To investigate the effects of fluid conditions on the formation of flameless combustion, a numerical approach was performed. The flameless combustion possesses lower temperature region and more uniform temperature distribution than conventional flame. The results show that the flow rate of the system which mainly influence on recirculation ratio is the most important parameter for flameless combustion.

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코로나 샤워 시스템을 이용한 NOx제거에서 $SO_2$의 영향 (The $SO_2$ effect on NOx removal by Corona Shower System)

  • 박재윤;김익균;이재동;김종달;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 E
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    • pp.1794-1796
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    • 1998
  • In this study, the $SO_2$ addition effect on NOx removal has been conducted from a combustion flue gases by the do corona discharge-activated radical shower systems. The simulated flue gases were consisted of NO-O_2-$N_2$, NO-$CO_2-N_2-O_2$ and $NO-SO_2-CO_2-Na-O_2$([NO]o:200ppm and $[SO_2]o$:800ppm). The injection gases used as radical source gases were $NH_3$-Ar-air. $SO_2$ and NOx removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as $SO_2$. NOx and $NO_2$ gas detectors. By-product aerosol particles were also observed by Condensation Nucleation Particle Counter(CNPC) and SEM images after sampling. The results showed that asignificant aerosol Particle formation was observed during a removal operation in corona radical shower systems. The NOx removal efficiency significantly increased with increasing applied voltage and $NH_3$ molecule ratio. The $SO_2$ removal efficiency was not significantly effected by applied voltage and slightly increased with increasing $NH_3$ molecule ratio. The NOx removal efficiency for NO-$SO_2-CO_2-N_2-O_2$ was better than that for NO-$CO_2-N_2-O_2$.

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비예혼합 대향류화염에서 산소부화에 따른 NOx 생성특성 (NOx Formation Characteristics with Oxygen Enrichment in Nonpremixed Counterflow Flames)

  • 이창언;황철홍;유병훈;한지웅
    • 한국가스학회지
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    • 제11권4호
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    • pp.17-22
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    • 2007
  • 비예혼합 대향류화염에서 산소부화에 따른 NOx 생성특성에 관한 수치해석이 수행되었다. 순산소의 연소과정에서 공기침투에 의한 부득이한 질소 유입의 상황을 체계적으로 고려하기 위하여, 산화제의 $O_2$는 체적비 21%에서 100%까지 변화되었다. 결과적으로 NO 배출지수$(EI_{NO})$는 산소부화율 75%까지 증가하다가 급격히 감소하는 경향을 보여준다. 이러한 경향은 화염온도, 화염두께 및 체류시간 보다는 NOx 생성과 관련된 $N_2$ 소모율 변화에 의해 설명될 수 있음을 확인하였으며, 특히 N+NO=$N_2+O$ 반응이 가장 크게 기여함을 알 수 있었다.

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CB4를 이용하여 부산 지역의 오존 전구 물질의 배출량에 대한 오존 농도의 민감도 (Sensitivity of Ozone Concentrations to Ozone Precursor Emissions In Busan Metropolitan Area Using the Carbon Bond Mechanism IV)

  • Lee, Hwa-Woon;Roh, Soon-A;Kim, Heon-Sook
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.362-363
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    • 2003
  • Photochemical ozone is formed from nitrogen oxides (NOx) and volatile organic compounds(VOCs) through non-linear interactions between chemical reactions and meteorology, and the relationship between precursors and photochemical ozone will be changed to match the emission distribution and meteorological fields. It is generally known that for some conditions the process of ozone formation is controlled almost entirely by NOx and is largely independent of VOC, while for other conditions ozone production increases with increasing VOC and does not increase(or sometimes even decreases) with increasing NOx (omitted)

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2중스월류에 의한 난류분무화염의 연소특성 연구 (A Study on Combustion Characteristics of Turbulent Spray Flame by the Dual Swirler)

  • 이강엽;황상순
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2000년도 제20회 KOSCO SYMPOSIUM 논문집
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    • pp.105-116
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    • 2000
  • An Experimental study was conducted on spray combustion using dual swirlers at different outlet angle; co-swirl and counter-swirl. To understand the characteristics of turbulent spray combustion of dual swril flow(DSF), the axial helical annular vaned swirlers with various swirl ratios and combination of angle and direction were designed. and temperature measurements of a rapidly thermocouple insertion and measurements of soot volume fraction and microrstructure using thermophoretic sampling particle diagnostic(TSPD) as TEM were carried out. The NOx, $CO_2$,$O_2$, etc. was analyzed using emission gas analyzer. The results show that flame stability were maintained under very lean condition. for both co-swirl and counter-swirl case. And though Counter-swirl case kept the higher temperature region compared to co-swirl case, Counter-swirl combustion represented less NOx emission and soot formation than co-swirl case.

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고속분사를 이용한 소형 축열식 복사관 버너시스템의 성능평가 (Performance Estimation of Small Regenerative Radiant Tube Burner System using High Velocity Discharge)

  • 조한창;조길원;이용국
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.242-247
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    • 2004
  • An Experimental study was conducted on spray combustion using dual swirlers at different outlet angle; co-swirl and counter-swirl. To understand the characteristics of turbulent spray combustion of dual swirl flow (DSF), the axial helical annular vaned swirlers with various swirl ratios and combination of angle and direction were designed. and temperature measurements of a rapidly thermocouple insertion and measurements of soot volume fraction and microrstructure using thermophoretic sampling particle diagnostic (TSPD) as TEM were carried out. The NOx, $CO_2$, $O_2$, etc. was analyzed using emission gas analyzer. The results show that flame stability were maintained under very lean condition. for both co-swirl and counter-swirl case. And though Counter-swirl case kept the higher temperature region compared to co-swirl case, Counter-swirl combustion represented less NOx emission and soot formation than co-swirl case.

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오존의 직접 분사가 NO 전환 및 부산물 생성에 미치는 영향 (The Effect of $O_3$ Direct Injection on NO Conversion and Byproduct Formation)

  • 이용환;고경보;최유리;길영미;정재우;조무현;남궁원
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 추계학술대회 논문집
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    • pp.143-144
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    • 2003
  • 최근 들어 플라즈마 촉매 복합공정을 이용하여 NOx를 제거시키기 위한 연구가 활발히 이루어지고 있다. 저온 플라즈마 공정중 하나인 DBD (Dielectric barrier discharge) 공정 내에서 NO는 NO$_2$로 매우 효과적으로 전환된다. 촉매공정의 경우 NO보다 NO$_2$가 주입되는 경우 NOx 제거 효율이 높고 촉매의 피독 현상도 줄어들게 된다. 따라서 DBD를 이용하여 NO의 전환율을 높일 수 있다면 플라즈마 촉매 복합공정의 NOx 제거 효율은 매우 높아진다. DBD 반응기 내에서 NO를 NO2로 전환시키는데 가장 중요한 역할을 하는 것 중 하나는 오존 (O$_3$)이다. (중략)

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2중스월류에 의한 난류분무화염의 연소특성 연구 (A Study on Combustion Characteristics of Turbulent Spray Flame by the Dual Swirler)

  • 이강엽;황상순
    • 한국연소학회지
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    • 제5권1호
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    • pp.67-79
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    • 2000
  • An Experimental study was conducted on spray combustion using dual swirlers at different outlet angle; co-swirl and counter-swirl. To understand the characteristics of turbulent spray combustion of dual swril flow(DSF), the axial helical annular vaned swirlers with various swirl ratios and combination of angle and direction were designed. and temperature measurements of a rapidly thermocouple insertion and measurements of soot volume fraction and microstructure using thermophoretic sampling particle diagnostic(TSPD) as TEM were carried out. The NOx, $CO_2,\;O_2$, etc. was analyzed using emission gas analyzer. The results show that flame stability were maintained under very lean condition. for both co-swirl and counter-swirl case. And though Counter-swirl case kept the higher temperature region compared to co-swirl case, Counter-swirl combustion represented less NOx emission and soot formation than co-swirl case.

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CuO/γ-Al2O3 흡수제/촉매를 이용한 SOx/NOx 제거 반응특성 (Reaction Characteristics of SOx/NOx Removal Using CuO/γ-Al2O3 Sorbent/Catalyst)

  • 유경선;김상돈
    • 대한환경공학회지
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    • 제22권4호
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    • pp.671-678
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    • 2000
  • 열중량분석기와 관형 고정층 반응기에서 $CuO/{\gamma}-Al_2O_3$ 흡수제/촉매의 SOx와 NOx 동시제거 반응특성에 대하여 고찰하였다. $CuO/{\gamma}-Al_2O_3$ 흡수제/촉매의 아황산가스 제거능은 반응온도 $450^{\circ}C$와 담지량 6wt% 이상에서 담체인 알루미나의 반응참여에 의하여 급격히 증가하였다. $CuO/{\gamma}-Al_2O_3$ 흡수제/촉매의 탈질 효율은 반응온도, $370^{\circ}C$에서 최대값을 보였으며 그 이상의 온도에서는 $NH_3$가스의 산화반응에 의하여 반응온도가 증가할수록 제거효율은 감소하였다. 흡수제/촉매 표면에 sulfate가 존재하는 경우 최대 탈질 효율을 보이는 반응온도는 증가하였다. SOx와 NOx 동시 제거반응에서 $CuO/{\gamma}-Al_2O_3$ 흡수제/촉매의 NO제거 활성은 $NH_4HSO_4$와 같은 암모늄염의 생성으로 인하여 크게 감소하였다. SOx와 NOx 동시제거 반응에 있어서 최대의 탈질 효율을 보이는 반응온도는 $SO_2$ 가스의 존재로 인하여 $400^{\circ}C$로 증가하였다.

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예혼합 압축착화 디젤엔진의 분사시기 변화에 따른 혼합기 형성 과정 및 연소 특성에 관한 연구 (A Study on the Mixture Formation Process and Combustion Characteristics According to Injection Timing in Premixed Charge Compression Ignition)

  • 조병호;한용택;이기형;이창식
    • 대한기계학회논문집B
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    • 제26권12호
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    • pp.1692-1698
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    • 2002
  • A diesel engine has various merits such as high thermal-efficiency, superior fuel consumption and durability. Therefore the number of diesel engine in the world is increasing. As the seriousness of environmental pollution increases in the world, the method to reduce the noxious materials of $CO_2$, NOx and P.M. is very important subject to correspond to exhaust gas regulations. A new concept, so called premixed charge diesel combustion(PCCI), is focused among the various corresponding manners. In this study, we investigated the mixture formation within the cylinder with injection timing using GTT simulation code and also compared combustion characteristics of PCCI engine with that of commercial diesel engine. From this experiments, it could be found that homogeneous mixture formation was observed according to advance of injection timing and simultaneous reduction of NOx and Soot in injection timing of BTDC 60$^{\circ}$.