• Title/Summary/Keyword: NOx Concentrations

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Chemical Characteristics of Fine Aerosols During ABC-EAREX2005 (ABC-EAREX2005 미세 에어러솔의 화학적 특성)

  • Song, M.;Lee, M.;Moon, K.J.;Han, J.S.;Kim, K.R.;Lee, G.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.604-613
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    • 2006
  • The chemical composition of $PM_{2.5}$ such as ${SO_4}^{2-},\;{NO_3}^-,\;Cl^-,\;{NH_4}^+,\;Ca^{2+},\;K^+,\;Na^+,\;Mg^{2+}$, OC, and EC and the concentrations of reactive trace gases including $O_3,\;CO,\;NOx,\;SO_2,\;and\;H_2O_2$ were measured at Gosan in Jeju Island during March $13{\sim}30$, as a part of the Atmospheric Brown Clouds-East Asian Regional Experiment 2005(ABC-EAREX2005). The average mass concentrations of $PM_{2.5}$ was 27.3 ${\mu}g/m^3$, of which OC showed the highest concentration as 4.22 ${\mu}g/m^3$ and nss ${SO_4}^{2-}$ was the second highest as 3.34 ${\mu}g/m^3$. During that period, average concentrations of CO and $O_3$ was about 300 ppbv and 56 ppbv, respectively. For the whole experiment, the correlations of CO with ${SO_4}^{2-}$ and EC were very good, which suggests that CO can be used as tracer for the formation of fine aerosols. Several pollution and dust episodes were identified by the enhancement of CO, OC, EC, nss ${SO_4}^{2-},\;or\;Ca^{2+}$ concentrations or their ratios. In conjunction with factor analysis, air trajectory analysis, and comparison with emission inventories, these results indicate the spring aerosols collected at Gosan was strongly influenced by Asian outflows.

On Relationship of Low Visibility to Air Pollution in Cities (도시의 대기오염과 시정감소에 관하여)

  • 정용승;김태군;정재섭
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.1
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    • pp.1-6
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    • 1992
  • Using data measured in 1989, a study on variations of visibility and air pollution observed in Seoul, Chongju and Choopoongryong is carried out. Analysis includes on low visibility (< 10km) and smog occurring in the Metropolitan Seoul. It was observed that number of days of visibility less than 10km during 1989 was 56.7% (207 days) for Seoul, 45.7%(167 days) for Chongju and 5.8% (21 days) for Choopoongryong. Chongju is a medium size city (population : a half million) and Choopoongryong is a rural site. In the urban are as, however, the number of low visibility days was relatively large during the winter but with little seasonal variations. In each month these cities recorded more than 10 days of low visibility. The visibility reduction due to mist, fog and haze been occurred with air pollution. In particular, the reduction in a cold season related with an increase in high concentrations of $SO_x$ and aerosols. This type of low visibility occurring in Seoul is a similar type that is occurring in London, U.K. On the other hand, the visibility reduction during in a warm season is related with high concentrations of NOx and other photochemical precursors. The visibility reduction in Seoul during summer is the same type occurring in Los Angeles, U.S.A.

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A Survey on the Long-range Transport of Sulfur Compounds by Aircraft Measurement over the Yellow Sea in 1998 (황해상공에서의 항공기관측에 의한 황화합물 장거리이동 특징에 대한 조사)

  • 김병곤;안준영;김종호;박철진;한진석;나진균;최양일
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.6
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    • pp.713-725
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    • 1999
  • Air pollutants($SO_2$, NOx, $O_3$ and aerosol number) were measured using an aircraft to investigate the characteristical features of long-range transport of sulfur compounds over the Yellow Sea for the periods of 26~27 April and 7~10 November in 1998. The mean $SO_2$ concentrations of April 26th~27th and November 7th~10th flight were 0.6~1.8 ppb and 0.5~8.3 ppb, respectively, and the sulfur transport was largely limited to the atmospheric boundary layer. Especially, $SO_2$ increased up to 8.3 ppb altogether with the increase of particle number concentraton especially on November 8, 1998. In addition, $O_3$ was remarkably decreased against the increase of $SO_2$and particle number concentrations. This enhanced $SO_2$ concentration occurred in the low level westerlies in association with the anticyclonic flow over Southern China and the cyclonic circulation over Manchuria. Aerosol analyses at Taean site also showed that sulfate concentration increased 2~3 times higher than those of another sampling days, which could suggest possible interactions between aerosol particels and tropospheric ozone. A rigorous evaluation will be possible after the more intensive measurements and quantitative analyses with detailed chemistry model including the postulated heterogeneous mechanism.

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Microalgal Removal of $CO_2$from Flue Gases: Changes in Medium pH and Flue Gas Composition Do Not Appear to Affect the Photochemical Yield of Microalgal Cultures

  • Olaizola, Miguel
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.6
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    • pp.360-367
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    • 2003
  • Our research objectives are to determine under what conditions microalgal-based $CO_2$capture from flue gases is economically attractive. Specifically, our objective here was to select microalgae that are temperature, pH and flue gas tolerant. Microalgae were grown under five different temperatures, three different pH and five different flue gas mixtures besides 100% $CO_2$(gas concentrations that the cells were exposed to ranged 5.7-100% $CO_2$, 0-3504ppm SO$_2$, 0-328ppm NO, and 0-126ppm NO$_2$). Our results indicate that the microalgal strains tested exhibit a substantial ability to withstand a wide range of temperature (54 strains tested), pH (20 strains tested) and flue gas composition (24 strains tested) likely to be encountered in cultures used for carbon sequestration from smoke stack gases. Our results indicate that microalgal photosynthesis is a limited but viable strategy for $CO_2$capture from flue gases produced by stationary combustion sources.

NUMERICAL MODEL ON THE FUEL INJECTION CHARACTERISTICS FOR PREDICTING EXHAUST EMISSIONS FROM A MARINE DIESEL ENGINE

  • LEE S.-Y.;KIM G.-B.;JEON C.-H.;CHANG Y.-J.
    • International Journal of Automotive Technology
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    • v.6 no.3
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    • pp.205-213
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    • 2005
  • This study deals with the result of exhaust emissions and performance calculated by simulation of the fuel injection characteristics of the inline injection system in a marine diesel engine. The emissions are calculated through non-equilibrium by using the extended Zel'dovich kinetic mechanism for NOx and equilibrium method for OH, CO, $H_2$, Hand soot concentrations. Comparisons of the model predictions with the experimental values show reasonable agreement. Detailed prediction results showing the sensitivity of the model by injection rates are presented and discussed.

Measurement of Efficiency and Flue Gas Concentration of 90 kW Woodchip Boiler (90kW급 우드칩 온수 보일러 특성 및 성능 시험)

  • Kang, Sae-Byul;Kim, Jong-Jin;Choi, Kyu-Sung;Lee, Woong-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.194-197
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    • 2008
  • We measured the efficiency and flue gas concentration of a 90kW woodchip boiler which is for heating water of lodging. At nominal operating condition, the fuel, woodchip is fed into the boiler at a rate of 22.6 kg/h. In order to determine the efficiency of the boiler, we measured the water flow rate, woodchip flow rate, heating value and water content of woodchip, temperature of inlet and outlet of heating water. The results of test show that the power output of the woodchip boiler is 90.0 kW(77,400 kcal/h) and the thermal efficiency of the boiler is 88.5%. By using a gas analyser, flue gas concentrations are measured. The results show that O2 in the flue gas is 10.2%, CO concentration is 393 ppm and NOx concentration is 74 ppm.

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The Demonstration Test Result of 100% Bio Heavy Oil Combustion at the 75 MWe Oil Fired Power Plant (75 MWe급 중유 발전소 보일러에 대한 바이오중유 100% 전소 실증 연소실험 결과)

  • Baek, Sehyun;Park, Hoyoung;Kim, Young Joo;Kim, Tae Hyung;Kim, Hyunhee;Ko, Sung Ho
    • Journal of the Korean Society of Combustion
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    • v.19 no.2
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    • pp.28-36
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    • 2014
  • Bio fuel oil combustion experiments were successfully demonstrated at the 75 MWe oil-fired power plant without major equipment retrofit and 100% bio-fuel oil combustion was possible without big problems. The experimental data error correction was conducted and numerical model-based analysis technique was applied for the evaluation of the results. Incase of bio fuel oil combustion, heat absorption of radiative heat transfer section was reduced while convection section has opposite trend. The furnace exit gas temperature tends to rise slightly. Environment emissions such as NOx and SOx concentrations showed a tendency to decrease during the bio fuel oil combustion period. On the other hand, boiler efficiency was slightly underestimated.

Unsteady Flamelet Modeling of Turbulent Nonpremixed Flames (비정상 층류화염편 모델을 이용한 비예혼합 난류화염 해석)

  • Kim, Seong-Ku;Kang, Sung-Mo;Kim, Yong-Mo
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.133-141
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    • 2000
  • The present study is focused on modeling the transient behavior of the local flame structure which is especially important for slow reaction processes, such as NOx formation in the radiating flame field. The recently developed unsteady flamelet model has been applied to analyze a steady, turbulent jet flame. Numerical results are compared with experimental data and numerical results of the conventional steady flamelet model. The numerical result reveals that the unsteady flamelet model correctly predicts the nonequilibrium effect upsteam and the subsequent decay of the superequilibrium radical concentrations the further downstream.

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Combustion of RDF and RPF in a Lab-Scale Circulating Fluidized Bed (실험실규모 순환유동층에서 RDF와 RPF의 연소 특성에 관한 연구)

  • Lee, J.S.;Lee, E.L.;An, M.H.;Park, S.U.;Shin, D.H.;Hwang, J.H.
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.173-179
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    • 2004
  • Combustion of refuse derived fuel(RDF) and refuse plastic fuel (RPF) was carried out in a lab-scale circulating fluidized bed. Experiment was investigated cold flow visualization. RDF was made by C & tech and RPF was made by KRS. The results include distribution of temperature in the combustion chamber, and concentrations of flue gas such as $O_2$, $CO_2$, CO, $NO_x$ and HCs Micro G.C(gas chromatograph) was employed to find out concentration of He Temperature distribution was different when RDF and RPF were burnt respectably. As air ratio became increased, $CO_2$, CO, and total of HCs emissions were decreased. According to the number of carbon atom of HCs, HC were classified as five kinds of HC.

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Pollutant Formation Characteristics in a Flamelet Interacting with a Vortex (와동과 상호작용하는 화염편에서의 오염물질 생성특성)

  • Oh, Chang-Bo;Lee, Eui-Ju
    • Journal of the Korean Society of Safety
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    • v.25 no.1
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    • pp.9-16
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    • 2010
  • Flame structure of diffusion flame interacting with a single vortex was investigated with direct numerical simulation (DNS). A well-known counterflow diffusion flame was used as an initial flat flame and single vortices were made by issuing a high-velocity jet abruptly in fuel- and air-side. The variations in the maximum concentration of major species (CO and $CO_2$) and NOx (NO and $NO_2$) with the stoichiometric scalar dissipation rate were investigated. Unsteady effects in the species concentration variation of the flame interacting with a vortex were identified by comparing with that of steady flame. $NO_2$ formation characteristics of the flame interacting with a vortex were well understood by investigating the $HO_2$ formation. To enhance the prediction performance in the fire simulation, current turbulent combustion modelings are needed to be modified by adopting the unsteady effects in the species concentrations of diffusion flame interacting with a vortex.