• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.7
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• pp.1465-1472
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• 2009

The effect of heat loss rate on NOx formation of $CH_4/air$premixed flame were examined numerically in a perfectly stirred reactor. The following conclusions were drawn. Under the adiabatic wall condition, an increase in the residence time causes a remarkable increases in NOx emission. Under the heat loss conditions, however, NOx decreases significantly as the heat transfer coefficient and residence time increase. As the heat loss rate increases, Thermal NO mechanism and Re-burning NO mechanism play an important role in the NOx reduction, but Prompt NO mechanism and $N_2O$-intermediate NO mechanism lead to the increase in NOx production. Although the NOx formation is actually related to complex NOx mechanism with the changes in the heat transfer coefficient and residence time, it was found that NOx concentration can be represented by independent Thermal NO mechanism. From these results, new NOx correlation combined with the heat loss rate and residence time was suggested for predicting the NOx concentration in a practical $CH_4/air$premixed combustor.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1994.05a
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• pp.15-21
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• 1994

단계적 연료방식을 가지는 가스터빈 연소기의 해석을 위한 방법을 제안하였으며, 이를 바탕으로 연료배분방식에 따른 연소기의 연소 및 NOx 발생특성을 규명하였다. 연소기 해석모델은 연소기 내부를 선회기구역, 1차연소구역, 재순환구역, 2차연소구역 및 희석구역으로 나누어 각각의 반응구역을 혼합반응기, 플러그 유동반응기의 모델로서 근사하였다. 반응기내의 연소 및 NOx 생성반응은 천연가스 반응모델과 Zel'dovich 의 NOx 모델을 이용하여 예측하였다. 본 해석방법을 이용하여, 각 반응구역에 유입되는 연료량이 연소기내 연소특성, NOx 발생 특성 및 온도분포에 미치는 영향을 검토하였다. 또한, NOx 저감을 위해 증기분사를 사용하는 경우에 분사위치가 NOx 발생에 미치는 영향을 분석하여, 가스터빈 연소기설계에 필요한 기초자료를 제공하였다.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.4
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• pp.485-490
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• 2010

MILD (Moderate and Intense Low Oxygen Dilution) combustion is a technique which is able to reduce NOx formation and to uniform temperature distribution in the furnace by recirculating the exhaust gas to the fresh air and fuel. This study focuses on finding optimal condition of MILD combustor by changing equivalence ratio with fuel and air flow. The present experiment employs six thermocouple sensors in the furnace, and two concentration probes of NOx and CO at the exhaust exit pipe respectively. The MILD combustion phenomena have been observed at the condition of equivalent ratios of 0.71~0.73, and the temperature uniformity, NOx and CO concentration are also examined at the MILD combustion condition.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.368-370
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• 1999

고농도의 오존 농도를 예측ㆍ평가하기 위해서는 대상지역의 기상조건과 풍상쪽(up wind)으로부터의 오존ㆍ오존전구물질(precursor)의 중ㆍ장거리이동, VOCs 및 NOx의 배경농도 및 배출량과 관련된 VOC/NOx의 농도 특성을 파악하는 것이 필수적이다. 따라서 대상지역의 VOCs/NOx의 농도 특성에 따라 차후 고농도의 오존 생성을 예방하기 위한 오존전구물질의 저감대책이 결정되어지므로 대상지역의 광화학특성을 파악하는 것이 선행되어져야 한다.(중략)

• Journal of the korean Society of Automotive Engineers
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• v.6 no.3
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• pp.19-23
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• 1984

이글에서는 다음의 내용에 대하여 알아보았다. 1. 디이젤 기관의 배기대책 1) NOx 및 매연의 생성 메커니즘 2) NOx 및 매연의 배출특성 3) HC

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.696-701
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• 2018

The nitrogen oxides generated during combustion reactions have a great influence on the generation of acid rain and fine dust. As an NOx reduction method, exhaust gas recirculation combustion using Coanda nozzles capable of recirculating a large amount of exhaust gas with a small amount of air has recently been utilized. In this study, for the burner outlet with dual end opening, the use of a recirculation burner was investigated for the distribution of the pressure, streamline, temperature, combustion reaction rate and nitrogen oxides using computational fluid analysis. The gas mixed with the combustion air and the recirculated exhaust gas flow in the tangential direction of the circular cylinder burner, so that there is a region with low pressure in the vicinity of the fuel nozzle exit. As a result, a reverse flow is formed in the central portion of the burner near the center of the circular cylinder burner and the exhaust gas is discharged to the outside region of the circular cylinder burner. The combustion reaction occurs on the right side of the burner and the temperature and NOx distribution are relatively higher than those on the left side of the burner. It was found that the average NOx production decreased from an air flow ratio of 1.0 to 1.5. When the air flow ratio is 1.8, the NOx production increases abruptly. It is considered that the NOx production reaction increases exponentially with temperature when the air ratio is more than 1.5 and the NOx production reaction rate increases rapidly on the right-hand side of the burner.

• Journal of the Korean Institute of Gas
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• v.11 no.4
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• pp.17-22
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• 2007

The NOx emission characteristics with oxygen enrichment in non-premixed counterflow flames were investigated numerically. To consider systematically the situation of inevitable $N_2$ contamination by air infiltration in the process of pure-oxygen combustion, the volume ratio of $O_2$ in an oxidizer was changed from 21% to 100%. As a result the NO emission index $(EI_{NO})$ has the highest value under condition of 75% oxygen enrichment. This result can be explained by the change of $N_2$ destruction rate with oxygen enrichment rather than flame temperature, flame thickness and residence time. In particular, it was found that the reaction of N+NO=$N_2+O$ has the largest contribution on NOx production in oxygen-enrichment flames.

• Journal of the Korean Society of Safety
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• v.17 no.3
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• pp.112-117
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• 2002

A comparative investigation of an experimental and a simulation of chemical kinetics for NOx removal from silent(dielectric-barrier) discharges is presented. Several types of dielectric-barrier discharges were implemented depending upon the configuration of electrodes. The simulation was based on an approximate mathematical model for plasma cleaning of waste gas. The influence of non-uniform distributions of species due to the production of primary active particles in the streamer channel was taken into account. A comparison of observed experimental to the calculated removal efficiency of NOx showed acceptable agreement.

• 한국연소학회:학술대회논문집
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• 1998.10a
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• pp.155-164
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• 1998

Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymetric 2-D CH4 jet diffusion, partial premixed, premixed flame. Calculations were carried out twice with C2-Full Mechanism including prompt NO reaction in addition to the above C2-Thermal NO Mechanism. The role of thermal NO mechanism and prompt NO mechanism on each flame's NO production is investigated by using the numerical result. The NOx production of each flame were evaluated Quantitatively in terms of the NOx emission index

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.4
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• pp.400-412
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• 2022

Hydrogen with high chemical reactivity and combustion efficiency, is expected to reduce greenhouse gas and CO emission. However, there is a problem of increase in NOx emission due to hydrogen combustion. MILD combustion technology has been proposed to resolve NOx emission. In this study, the characteristics of MILD combustion and NOx formation by flue gas recirculation (KV) in CH₄-H₂ mixture were analyzed and predicted using 0D premixed combustion model. The ignition delay time became shorter as the hydrogen co-firing rate increased, and longer as the recirculation rate increased. For NOx emission, EINO decreased as the KV increased, but EINO increased as the hydrogen co- firing rate increased. In particular, EINO was predicted to increase significiently above 80% hydrogen. Through the pathway analysis of NO formation, it was found that the influence of N₂O intermediate route and NNH route was enhanced for hydrogen co-firing.