• 제목/요약/키워드: NOx,

검색결과 2,540건 처리시간 0.026초

Metal-Urea-Montmorillonite Hybrid Incorporated with Citric Acid

  • Kim, Kwang Seop;Kim, Min-Tae;Ryu, Jin-Hee;Choi, Jong-Seo;Park, Ki Do;Kang, Hang-Won;Park, Man
    • 한국토양비료학회지
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    • 제46권6호
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    • pp.610-614
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    • 2013
  • Massive intercalation of urea into montmorillonite (MUCH) was recently proposed to enhance urea use efficiency through smart suppression of emission of $NH_3$ and NOx. This study was to synthesize citrate-incorporated MUCH (Cit-MUCH) which can enhance suppression of $NH_3$ volatilization. The XRD pattern of Cit-MUCH was very similar to that of MUCH to indicate successful incorporation of citric acid into MUCH. Incorporation of citric acid was confirmed by the existence of $COO^-$ symmetric stretching vibration. During the initial 4 days after application, $NH_3$ volatilization from both bare and perilla-planted soils was much more suppressed by application of Cit-MUCH than MUCH. A peak volatilization rate decreased from 28.3 N mg $m^{-2}\;h^{-1}$ of MUCH-broadcasted soil to 22.2 N mg $m^{-2}\;h^{-1}$ of Cit-MUCH-broadcast soil. $NH_3$ volatilization was less in planted soil than bare soil for 72 hrs after application. These results showed that incorporation of citric acid led to increase in suppression of ammonia volatilization from urea-applied soils.

Low Calorific Gasturbine 매립지 적용 및 유리온실 운용기술 설계 (Design for Landfill Gas Application by Low Calorific Gas Turbine and Green House Optimization Technology)

  • 허광범;박정극;이정빈;임상규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.244.1-244.1
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    • 2010
  • Bio energy development by using Low Calorific Gas Turbine(LCGT) has been developed for New & Renewable energy source for next generation power system, low fuel and operating cost method by using the renewable energy source in landfill gas (LFG), Food Waste, water waste and Livestock biogas. Low calorific fuel purification by pretreatment system and carbon dioxide fixation by green house system are very important design target for evaluate optimum applications for bio energy. Main problems and accidents of Low Calorific Gas Turbine system was derived from bio fuel condition such as hydro sulfide concentration, siloxane level, moisture concentration and so on. Even if the quality of the bio fuel is not better than natural gas, LCGT system has the various fuel range and environmental friendly power system. The mechanical characterisitics of LCGT system is a high total efficiency (>70%), wide range of output power (30kW - 30MW class) and very clean emmission from power system (low NOx). Also, we can use co-generation system. A green house designed for four different carbon dioxide concentration from ambient air to 2000 ppm by utilizing the exhaust gas and hot water from LCGT system. We look forward to contribute the policy for Renewable Portfolio Standards(RPS) by using LCGT power system.

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과급 디젤엔진에서 선회비 변경에 따른 흡기 포트유동 및 엔진성능 특성에 관한 연구 (A Study on the Characteristics of Intake Port Flow and Performance with Swirl Ratio Variance in a Turbocharged D.I. Diesel Engine)

  • 윤준규;차경옥
    • 대한기계학회논문집B
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    • 제24권9호
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    • pp.1185-1194
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    • 2000
  • The characteristics of intake port flow and engine performance with swirl ratio variance in a turbocharged D.I. diesel engine were studied in this paper. The intake port flow is important factor which have influence on the engine performance and exhaust emission because the properties in the injected fuel depend on the combustion characteristics. Through these experiments it can be expected to satisfy performance and emission by optimizing the main parameters; the swirl ratio of intake port, injection timing and compression ratio. The swirl ratio for ports was modified by hand-working and measured by impulse swirl meter. For the effects on performance and emission, the brake torque and brake specific fuel consumption were measured by engine dynamometer, NOx and smoke were measured by gas analyzer and smoke meter. The results of steady flow test are as follows; as the valve eccentricity ratio are closed to cylinder wall, the flow coefficient and swirl intensity are increased. Also we realized that there is a trade-off that the increase of swirl ratio decreases mean flow coefficient and increases the Gulf factor. And the optimum parameters to meet performance and emission through engine test are as follows; the swirl ratio 2.43, injection timing BTDC 13oCA and compression ratio 15.5.

이산화티탄 광촉매의 효율적 적용을 위한 LEFC 블록 제작에 관한 연구 (A Study on the Development of Light Emotion Friendly Concrete Block for Efficient Application of Titan-oxide Photocatalyst)

  • 김병일;오상근;서승훈
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권6호
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    • pp.120-131
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    • 2019
  • 본 연구에서는 빛 감성친화형 콘크리트에 광촉매를 적용하여 대기질 및 실내공기질을 개선하기 위한 LEFC 블록을 개발하고자 하였다. LEFC에 광촉매를 적용하게 되면 자외선 입사면 반대편에서도 투과로 인한 자외선이 존재하여 광촉매가 반응함으로써 일반 건축 자재를 적용한 경우보다 광촉매 반응효율이 크게 상승한다. 따라서 광촉매를 LEFC에 적용하기 위해 슬럼프, J-ring, L-box 테스트를 통한 자기충전성능을 평가하여 최적 배합을 결정하였고, 압축 및 휨 강도 시험을 통해 역학성능을 평가하였다. 그리고 TiO2 분포도를 확인하기 위해 SEM과 EDS 분석을 실시하였다. ALC골재와 단열재 적용으로 광촉매 사용량을 줄이고 단위중량을 감소시키는 방안을 활용하여 광촉매 효율을 증가시키는 빛투과 콘크리트 블록을 제작하였고, 향후 건조수축 등의 문제점 개선 및 NOx 제거 실험을 통한 LEFC 블록 성능 평가를 진행하고자 한다.

Inhibitors of DNA methylation support TGF-β1-induced IL11 expression in gingival fibroblasts

  • Sufaru, Irina-Georgeta;Beikircher, Gabriel;Weinhaeusel, Andreas;Gruber, Reinhard
    • Journal of Periodontal and Implant Science
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    • 제47권2호
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    • pp.66-76
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    • 2017
  • Purpose: Oral wound healing requires gingival fibroblasts to respond to local growth factors. Epigenetic silencing through DNA methylation can potentially decrease the responsiveness of gingival fibroblasts to local growth factors. In this study, our aim was to determine whether the inhibition of DNA methylation sensitized gingival fibroblasts to transforming growth factor-${\beta}1$ (TGF-${\beta}1$). Methods: Gingival fibroblasts were exposed to 5-aza-2'-deoxycytidine (5-aza), a clinically approved demethylating agent, before stimulation with TGF-${\beta}1$. Gene expression changes were evaluated using quantitative polymerase chain reaction (PCR) analysis. DNA methylation was detected by methylation-sensitive restriction enzymes and PCR amplification. Results: We found that 5-aza enhanced TGF-${\beta}1$-induced interleukin-11 (IL11) expression in gingival fibroblasts 2.37-fold (P=0.008). 5-aza had no significant effects on the expression of proteoglycan 4 (PRG4) and NADPH oxidase 4 (NOX4). Consistent with this, 5-aza caused demethylation of the IL11 gene commonly next to a guanosine (CpG) island in gingival fibroblasts. The TGF-${\beta}$ type I receptor kinase inhibitor SB431542 impeded the changes in IL11 expression, indicating that the effects of 5-aza require TGF-${\beta}$ signaling. 5-aza moderately increased the expression of TGF-${\beta}$ type II receptor (1.40-fold; P=0.009), possibly enhancing the responsiveness of fibroblasts to TGF-${\beta}1$. As part of the feedback response, 5-aza increased the expression of the DNA methyltransferases 1 (DNMT1) (P=0.005) and DNMT3B (P=0.002), which are enzymes responsible for gene methylation. Conclusions: These in vitro data suggest that the inhibition of DNA methylation by 5-aza supports TGF-${\beta}$-induced IL11 expression in gingival fibroblasts.

MILD 연소 폐기물 소각로에서 배기가스 재순환 흡입구 위치에 따른 유동 특성 연구 (A study on the flow characteristics in a MILD combustion waste incinerator with the change of flue gas recirculation inlet location)

  • 하지수;심성훈;정응호
    • 에너지공학
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    • 제23권3호
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    • pp.51-57
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    • 2014
  • MILD 연소는 고온의 배기가스가 연소로 내에 유입되는 연료와 공기의 혼합물과 고온의 배기가스 가 만나는 위치에 따라 질소산화물 저감 특성이 많은 영향을 받는다. 본 연구에서는 폐기물소각로에 적용한 MILD 연소로에서 배기가스 재순환 여부에 따른 유동 특성과 배기가스 재순환 위치에 따른 유동 특성을 살펴보아 최적의 배기가스 재순환 위치를 선정하는 것을 목적으로 하였다. 본 연구의 전산 해석의 결과는 배기가스 재순환이 없는 경우에는 수직 격벽 상부의 단면에서 속도 분포는 수직 격벽 바로 상부에 큰 속도가 있고 더 상부는 역류가 일어나는 것을 확인할 수 있었다. 배기가스 재순환이 있는 경우는 상부 자유공간에서의 유동 균일도를 수직 격벽 상부 단면에서의 x 방향 속도의 %RMS 값으로 비교하였으며 재순환 흡입구 위치가 자유공간 우측 상단에 위치한 경우가 %RMS 값이 57.4%로 가장 작은 값을 가지며 따라서 가장 효과적임을 알 수 있었다.

배출허용기준 강화에 따른 차속별 경유 중형트럭의 유해대기오염물질 배출특성 (Speed-dependent Emission Characteristics of the Hazardous Air Pollutants from Diesel Medium-duty Trucks according to Emission Standards)

  • 홍희경;정성운;손지환;문태영;이상은;문선희;윤현진;김정수;김정화
    • 한국분무공학회지
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    • 제20권2호
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    • pp.121-129
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    • 2015
  • This study was designed to investigate the emission characteristics of unregulated pollutants (Aldehyde, VOCs, PAHs) as well as regulated pollutants (CO, HC, NOx and PM) from diesel medium-duty trucks. The emission characteristics of unregulated and regulated pollutants were assessed based on regulation standards (EURO 4 and EURO 5) and intake weight (2.5 ton and 5 ton). The results show that unregulated and regulated pollutants remained almost unchanged at higher speeds but decreased at below 23.5 km/h. Reduction in unregulated and regulated pollutants was noticeable in vehicles of recent regulation standards and light intake weight. The analysis of aldehyde using UPLC showed that formaldehyde and acetaldehyde of aldehyde were most dominant. The GC/MS analysis showed that benzene, toluene, ethylbenzene and xylene of VOCs was over 80% followed by toluene, xylene, ethylbenzene and benzene. In addition, the analysis of PAHs using GC/TOF-MS indicated that bi- and tricyclic aromatic ring of aromatic compounds was 73% and 53% at 2.5 ton and 5 ton vehicles, respectively. The results of this study will be contributed to establish HAPs inventory.

고농도 알코올 혼합 석유제품이 자동차 성능 및 배출가스에 미치는 영향 연구 (The Study on Effect of Emissions and Performance of a Conventional Vehicle using the High Concentration Alcohol Blended Petroleum Product)

  • 김성우;도진우;김기호;하종한
    • 한국수소및신에너지학회논문집
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    • 제26권6호
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    • pp.629-637
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    • 2015
  • As concern about energy security and global warming many countries have been making effort to reduce fossil fuel. In the case of US, as one of the efforts, the standards of the alcohol vehicle fuels(including blended with gasoline) have been established. Alcohol is known that make some trouble concerning startability, durability and corrosion when using as fuel of a conventional vehicle. For these reason, alcohol usage needs not only the fuel standard, but also a modified car. In the case of Korea, although there are no the standard and the modified vehicle yet, high concentration alcohol blended fuel has being sold at illegal market. In this study, exhaust gas and performance of the conventional vehicle that alcohol(methanol and isopropyl alcohol) blends were fueled were measured to notify danger of using them without preparation of institutional arrangements. Also, to analyze correlation characteristics of the fuels and them, property test of the fuels was conducted. The test result show that bad-startability caused by low RVP and high T10 affected increase in NMOG and CO. NOx was increased under the highest short term fuel trim caused by high Oxygen content and low NHV of alcohol. According to increasing as alcohol content, fuel economy and acceleration ability were decreased but $CO_2$ was not significantly decreased.

Chemical Characteristics of Precipitation in Quercus Forests in Korea and Japan

  • Kim, Min Sik;Takenaka, Chisato;Park, Ho Taek;Chun, Kun Woo
    • 한국산림과학회지
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    • 제96권5호
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    • pp.503-509
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    • 2007
  • The major objective of this study was to analyze the difference of the chemical characteristics of acid deposition in Quercus forests in Korea and Japan. The pH values of rainfall at the experimental forest of Kangwon National University (KS site) were higher than those at the Foresta Hills in Japan (JP site), and all chemical contents of throughfall and stemflow were much higher than those of rainfall in Quercus forest stands at the KS and JP site. The pH values, $Ca^{2+}$, $NO_3{^-}$ and $SO{_4}^{2-}$ concentration of throughfall and stemflow at the KS site showed seasonal variation. While at the JP site, the same pattern was shown in the pH values of throughfall and stemflow, however, did not show any difference among seasons. Also, the annual input of all nutrients in these two contrasting forests varied seasonally. These results can be used to predict the amounts of air pollutant that are washed off and leached by the rainfall and Yellow Sand (Asian dust), including NOx and SOx acid pollutants transported easterly from China in the spring. Therefore, it is necessary to quantify the inputs of dry and wet deposition throughout a full year to gain a more complete understanding of the effects of acid deposition on the nutrient cycles in these forest ecosystems.

가스터빈 연소기내 CARS 온도측정을 통한 연소해석 (Combustion Analysis with CARS Temperature Measurement in a Gas Turbine Combustor)

  • 이종호;박철웅;한영민;고영성;이수용;양수석;이대성;전충환;장영준;신현동;한재원
    • 대한기계학회논문집B
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    • 제27권8호
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    • pp.1134-1141
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    • 2003
  • Performance of a gas turbine combustor installed in a test facility has been studied by measuring spatially- and temporally-resolved temperature distributions using multiplex CARS technique. 500 CARS temperatures were determined at each measuring point to obtain a histogram of temperature distribution. Experiments were carried out in the aero-engine combustor sector rig burning standard kerosene fuel. The histograms were obtained around a triple-sector double annular rig running in ground idle conditions, showing features of flow mixing within the rig. The temperature histograms that prove the existence of high temperatures above 1900 K provide us valuable information to improve the design of the combustor structure suppressing NOx generation in turbulent combustion processes. The effects of swirl direction and pre-filmer on gas turbine combustion were investigated. When we installed radial swirls, a large recirculation zone was formed by the fuel module regardless of swirl directions and the pre-filmer installation. It is found that the swirl direction affects the shape of the reverse flow zone, however. Also, an attempt to estimate the flow field and flame structure is made using the histogram of temperature determined with the CARS technique.