• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.179-183
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• 2002

Resonance-enhanced multiphoton ionization with time-of-flight product imaging of the $N(^2D)$ atoms has been used to study the $N_2O$ photodissociation at 118.2 nm and the two-photon dissociation at 268.9 nm. These imaging experiments allowed the determination of the total kinetic energy distribution of the $NO(X^2{\prod})$ and $N(^2D_{5/2})$ products. The $NO(X^2{\prod})$ fragments resulting from the photodissociation processes are produced in highly vibrationally excited states. The two-photon photodissociation process yields a broad $NO(X^2{\prod})$ vibrational energy distribution, while the 118.2 nm dissociation appears to produce a vibrational distribution sharply peaked at $NO(X^2{\prod},\;{\nu}=14)$.

• 에너지공학
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• 제10권4호
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• pp.379-386
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• 2001

본 연구는 산업용 고부하 버너연소에서의 NO$_{x}$ 저감에 관한 실험적 연구이다. 본 연구에서는 NO$_{x}$의 정량적 농도 분포 측정을 위하여 레이저 유동 형광법을 사용하였다. XeCL 엑시머 레이저를 사용하여 NO A-X (0, 0) 진동밴드를 226 nm로 여기하였다. 또한 P$_{21}$+Q$_1$(14.5)/R$_{12}$+Q$_2$(20.5)/P$_1$(23.5) 전이를 여기라인으로 하였으며 다른 간섭의 영향을 최소화 하였다. 본 실험에서 이중선회 확산화염에서의 NO 농도 분포를 측정하였으며, 이 스월버너에서의 화염의 후류에 있어서 NO 농도는 1차/2차 공기비가 증가할 때 감소함을 알수 있었다.

• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.429-434
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• 2009

The OH($X^2{\Pi},\;{\nu}$"=0, 1) internal state distributions from the reaction of electronically ground state oxygen atoms with HSi$Cl_3$ were measured using laser-induced fluorescence. The ground-state O$(^3P_J)$ atoms with kinetic energies above the reaction barrier were produced by photolysis of N$O_2$ at 355 nm. The OH product revealed strong vibrational population inversion, P(${\nu}$"=1)/P(${\nu}$"=0) = 4.0 ${\pm}$ 0.6, and rotational distributions in both vibrational states exhibit substantial rotational excitations to the limit of total available energy. However, no preferential populations in either of the two $\Lambda$ doublet states were observed from the micropopulations, which supports a mechanism involving a direct abstraction of hydrogen by the atomic oxygen. It was also found that the collision energy between O and HSi$Cl_3$ is effectively coupled into the excitation of the internal degrees of freedom of the OH product ($$ = 0.62, and $<\;f_{rot}>$ = 0.20). The dynamics appear consistent with expectations for the kinematically constrained reaction which supports the reaction type, heavy + light-heavy $\rightarrow$ heavy-light + heavy (H + LH′ $\rightarrow$ HL + H′). The dynamics of oxygen atom collision with HSi$Cl_3$ are discussed in comparison to those with Si$H_4$.