• Title/Summary/Keyword: NO Emission

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NOx Formation and Emission Characteristics of Premixed Swirl Flame of Natural Gas (천연가스 선회 예혼합 화염의 NOx 생성 및 배출 특성)

  • You, Hyun-Seok;Lee, Joong-Seong;Han, Jeong-Ok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.6
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    • pp.788-794
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    • 1999
  • The swirl flame is mostly used to stabilize the flame on the burner nozzle in the industrial combustor. In the case of the weak swirl flame(S<0.4), the recirculation zone could not be formed, but in the strong swirl(S>0.6) flame, it could be formed in the center of the swirl flame. In this study, the measurement and analysis of emission species, temperature, radicals of premixed swirl flame in the combustor were performed to understand the NO formation and emission characteristics of the swirl flame of natural gas. The result of NO emission in the swirl flame is that the amount of NO emission in the strong swirl flame decreased about 60% compared with that of the weak swirl flame. The main region of NO formation of the weak swirl flame is positioned in the down stream(z=100~200mm) of the flame, but that of the strong swirl flame is positioned in the up stream(z=40mm) where the recirculation zone seems to be formed. It is supposed that the increase of flame surface and the formation of inversed flame cause the reduction of the high temperature region on the production of NO in the strong swirl flame. The result of NO-temperature relation revealed that the factor of NO formation is not only temperature but also another parameters in the weak swirl flame, but in the strong swirl flame, NO is proportional to the temperature of higher than 1200K.

Combustion and Exhaust Emission Characteristics of DME in a Common-rail Diesel Engine (커먼레일 디젤엔진에서 DME의 연소 및 배기 특성)

  • An, Sang-Gyu;Kim, Myung-Yoon;Yoon, Seung-Hyun;Lee, Je-Hyung;Lee, Chang-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.2
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    • pp.74-80
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    • 2007
  • An experiment was conducted with a common-rail direct injection diesel engine operated with neat dimethyl ether (DME). In order to investigate the effect of combustion characteristics and emission reduction of DME fuel, the experiment was performed at various injection pressure from 35 MPa to 50MPa. Also, the exhaust emissions from the engine were compared with that of diesel fuel. In this work, Cooled EGR was implemented to reduce $NO_x$ exhaust emissions. The results showed that DME has shorter ignition delay than that of diesel fuel. Despite of the increased $NO_x$ emissions with DME at an equal engine power compared to the case of fueling diesel, the engine emitted zero soot emissions all over the operating conditions in this work. $NO_x$ emission can be decreased greatly by adopting 45% of EGR while maintaining zero soot emission. Judging from the result of engine test, DME is a suitable fuel for common-rail diesel engine due to it's clean emission characteristics.

A study on the air pollutant emission trends in Gwangju (광주시 대기오염물질 배출량 변화추이에 관한 연구)

  • Seo, Gwang-Yeob;Shin, Dae-Yewn
    • Journal of environmental and Sanitary engineering
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    • v.24 no.4
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    • pp.1-26
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    • 2009
  • We conclude the following with air pollution data measured from city measurement net administered and managed in Gwangju for the last 7 years from January in 2001 to December in 2007. In addition, some major statistics governed by Gwangju city and data administered by Gwangju as national official statistics obtained by estimating the amount of national air pollutant emission from National Institute of Environmental Research were used. The results are as follows ; 1. The distribution by main managements of air emission factory is the following ; Gwangju City Hall(67.8%) > Gwangsan District Office(13.6%) > Buk District Office(9.8%) > Seo District Office(5.5%) > Nam District Office(3.0%) > Dong District Office(0.3%) and the distribution by districts of air emission factory ; Buk District(32.8%) > Gwangsan District(22.4%) > Seo District(21.8%) > Nam District(14.9%) > Dong District(8.1%). That by types(Year 2004~2007 average) is also following ; Type 5(45.2%) > Type 4(40.7%) > Type 3(8.6%) > Type 2(3.2%) > Type 1(2.2%) and the most of them are small size of factory, Type 4 and 5. 2. The distribution by districts of the number of car registrations is the following ; Buk District(32.8%) > Gwangsan District(22.4%) > Seo District(21.8%) > Nam District(14.9%) > Dong District(8.1%) and the distribution by use of car fuel in 2001 ; Gasoline(56.3%) > Diesel(30.3%) > LPG(13.4%) > etc.(0.2%). In 2007, there was no ranking change ; Gasoline(47.8%) > Diesel(35.6%) > LPG(16.2%) >etc.(0.4%). The number of gasoline cars increased slightly, but that of diesel and LPG cars increased remarkably. 3. The distribution by items of the amount of air pollutant emission in Gwangju is the following; CO(36.7%) > NOx(32.7%) > VOC(26.7%) > SOx(2.3%) > PM-10(1.5%). The amount of CO and NOx, which are generally generated from cars, is very large percentage among them. 4. The distribution by mean of air pollutant emission(SOx, NOx, CO, VOC, PM-10) of each county for 5 years(2001~2005) is the following ; Buk District(31.0%) > Gwangsan District(28.2%) > Seo District(20.4%) > Nam District(12.5%) > Dong District(7.9%). The amount of air pollutant emission in Buk District, which has the most population, car registrations, and air pollutant emission businesses, was the highest. On the other hand, that of air pollutant emission in Dong District, which has the least population, car registrations, and air pollutant emission businesses, was the least. 5. The average rates of SOx for 5 years(2001~2005) in Gwangju is the following ; Non industrial combustion(59.5%) > Combustion in manufacturing industry(20.4%) > Road transportation(11.4%) > Non-road transportation(3.8%) > Waste disposal(3.7%) > Production process(1.1%). And the distribution of average amount of SOx emission of each county is shown as Gwangsan District(33.3%) > Buk District(28.0%) > Seo District(19.3%) > Nam District(10.2%) > Dong District(9.1%). 6. The distribution of the amount of NOx emission in Gwangju is shown as Road transportation(59.1%) > Non-road transportation(18.9%) > Non industrial combustion(13.3%) > Combustion in manufacturing industry(6.9%) > Waste disposal(1.6%) > Production process(0.1%). And the distribution of the amount of NOx emission from each county is the following ; Buk District(30.7%) > Gwangsan District(28.8%) > Seo District(20.5%) > Nam District(12.2%) > Dong District(7.8%). 7. The distribution of the amount of carbon monoxide emission in Gwangju is shown as Road transportation(82.0%) > Non industrial combustion(10.6%) > Non-road transportation(5.4%) > Combustion in manufacturing industry(1.7%) > Waste disposal(0.3%). And the distribution of the amount of carbon monoxide emission from each county is the following ; Buk District(33.0%) > Seo District(22.3%) > Gwangsan District(21.3%) > Nam District(14.3%) > Dong District(9.1%). 8. The distribution of the amount of Volatile Organic Compound emission in Gwangju is shown as Solvent utilization(69.5%) > Road transportation(19.8%) > Energy storage & transport(4.4%) > Non-road transportation(2.8%) > Waste disposal(2.4%) > Non industrial combustion(0.5%) > Production process(0.4%) > Combustion in manufacturing industry(0.3%). And the distribution of the amount of Volatile Organic Compound emission from each county is the following ; Gwangsan District(36.8%) > Buk District(28.7%) > Seo District(17.8%) > Nam District(10.4%) > Dong District(6.3%). 9. The distribution of the amount of minute dust emission in Gwangju is shown as Road transportation(76.7%) > Non-road transportation(16.3%) > Non industrial combustion(6.1%) > Combustion in manufacturing industry(0.7%) > Waste disposal(0.2%) > Production process(0.1%). And the distribution of the amount of minute dust emission from each county is the following ; Buk District(32.8%) > Gwangsan District(26.0%) > Seo District(19.5%) > Nam District(13.2%) > Dong District(8.5%). 10. According to the major source of emission of each items, that of oxides of sulfur is Non industrial combustion, heating of residence, business and agriculture and stockbreeding. And that of NOx, carbon monoxide, minute dust is Road transportation, emission of cars and two-wheeled vehicles. Also, that of VOC is Solvent utilization emission facilities due to Solvent utilization. 11. The concentration of sulfurous acid gas has been 0.004ppm since 2001 and there has not been no concentration change year by year. It is considered that the use of sulfurous acid gas is now reaching to the stabilization stage. This is found by the facts that the use of fuel is steadily changing from solid or liquid fuel to low sulfur liquid fuel containing very little amount of sulfur element or gas, so that nearly no change in concentration has been shown regularly. 12. Concerning changes of the concentration of throughout time, the concentration of NO has been shown relatively higher than that of $NO_2$ between 6AM~1PM and the concentration of $NO_2$ higher during the other time. The concentration of NOx(NO, $NO_2$) has been relatively high during weekday evenings. This result shows that there is correlation between the concentration of NOx and car traffics as we can see the Road transportation which accounts for 59.1% among the amount of NOx emission. 13. 49.1~61.2% of PM-10 shows PM-2.5 concerning the relationship between PM-10 and PM-2.5 and PM-2.5 among dust accounts for 45.4%~44.5% of PM-10 during March and April which is the lowest rates. This proves that particles of yellow sand that are bigger than the size $2.5\;{\mu}m$ are sent more than those that are smaller from China. This result shows that particles smaller than $2.5\;{\mu}m$ among dust exist much during July~August and December~January and 76.7% of minute dust is proved to be road transportation in Gwangju.

A Study of NO Fmission Characteristics in a Non-premixed Counterflow Flame with $H_2/CO_2/Ar$ Blended-fuel (수소/이산화탄소/알곤 혼합 연료의 비예혼합 대향류 화염에서 NO 배출 특성 연구)

  • Lee, Kee-Man
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.4
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    • pp.146-153
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    • 2007
  • The detailed chemistry with reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions, have been numerically conducted to investigate the flame structure and NO emission characteristics in a non-premixed counterflow flame of blended fuel of $H_2/CO_2/Ar$. The combination of $H_2,\;CO_2$, and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of $CO_2$. Radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. All mechanisms including thermal, $NO_2,\;N_2O$, and Fenimore are also taken into account to separately evaluate the effects of $CO_2$ addition on NO emission characteristics. The increase of added $CO_2$ quantity causes flame temperature to fall since at high strain rates diluent effect is prevailing and at low strain rates the breakdown of $CO_2$ produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the ratio of the contribution by Fenimore mechanism to that by thermal mechanism in the total mole production rate becomes much larger with increase in the $CO_2$ quantity and strain rate, even though the absolute quantity of NO production is deceased. Consequently, as strain rate and $CO_2$ quantity increase, NO production by Fenimore mechanism is remarkably augmented.

The Methods Calculating the Reduction Efficiency of Nitrogen Oxide for the Facilities Including the Low NOx Burners (저녹스 버너 설치 시설의 질소산화물 저감 효율 산정 방법)

  • Lee, Ki Yong;Talukder, Niladri
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.295-296
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    • 2015
  • We presented the methods calculating the reduction efficiency of nitrogen oxide for the low $NO_x$ burner as the pollution prevention facilities. The standard $NO_x$ concentration was used on the emission factor of LNG, $3.7g/m^3$. The $NO_x$ reduction efficiency based on the $NO_x$ concentration was presented and the relationships between the $NO_x$ concentration and the emission factor or the specific heat emission factor were derived. These results could be accurately reflected on calculating the amount of the nitrogen oxide emissions. In addition, according to the arrangement of the low $NO_x$ burners the methods of applying their $NO_x$ reduction efficiency were proposed. The $NO_x$ reduction efficiency for the facilities consisting of the low $NO_x$ burners and the non-low $NO_x$ burners could be estimated with information about the reduction efficiency of each low $NO_x$ burners, the fuel consumption rate, and the heating value of fuel.

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A Study on the Characteristics of Solid-Fuel Combustion (고형연료의 배출특성 연구)

  • Jang, Kee-Won;Heo, Sun-Hwa;Lim, Seung-Young;Kim, Dae-Gon;Jung, Yong-Won;Kang, Dae-Il
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.4
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    • pp.351-360
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    • 2017
  • In this study, we developed emission factors from solid-fuel fired combustors. In order to increase the reliability of emission factors, we conducted a joint research with the Institute of Health and Environment. As a result, PM average concentration was $8.19mg/m^3$. $SO_2$ and $NO_x$ were respectively 8.46 ppm, 50.64 ppm. Hazardous air pollutants such as Cr, Pb and Hg were detected in trace amounts continuously for 2 years in some solid-fuel fired combustors. The emission factors for the three kinds of PM, $SO_x$, $NO_x$ were developed based on the measurement data. For the PM emission factors, that of SRF was 15.93 g/kg and that of Bio-SRF was 14.18 g/kg. Compared with those of US. EPA, emission factors of this study showed the results of low values. $SO_x$ emission factors were 4.42 g/kg for SRF and 1.39 g/kg for Bio-SRF. $NO_x$ emission factors were 13.21 g/kg and 4.43 g/kg, respectively. Through the results of this study, we would support atmospheric administration policies such as the emission factor notification revision.

Relationship of Electricity Consumption and Emission Rate of Acidic Gases (전력소비와 산성가스 배출량과의 관계)

  • 정일록;김대곤
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.131-138
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    • 1995
  • As the energy consumption increases continuously, the emission amount of air pollutants is growing, and after all it can influence the global environment as welt as the regional atmosphere. So, the clean energy which emits less air pollutants should be developed and widely used to reduce emission of pollutants. Electricity, known for clean energy in the side of consumption, is not actually clean in the process of generation. Electric power is generated using fossil fuels which produce acidic gases like $SO_{2}$, $NO_{x}$, etc. The emission rates of $SO_{2}$, $NO_{x}$, $CO_{2}$ are 2g,0.78g and 1 l0g per electric power generating Ikwh. If one light(60 watt bulb) be turned off at each house for a month electricity will be saved about 1.Skillion kwh a year. This is almost the same as 4,170 tons of $SO_{2}$ and $NO_{x}$. As a result the economization of electricity will be one of the effective strategy to reduce the air pollution and to keep our life clean and comfortable.

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Empirical Analysis on Determinants of Air Pollution in China (중국의 대기오염 배출 결정요인에 대한 경험적 분석)

  • Li, Dmitriy D.;Wang, Wen;Bae, Jeong Hwan
    • Environmental and Resource Economics Review
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    • v.29 no.1
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    • pp.23-45
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    • 2020
  • The rapid economic growth has brought tremendous pressure on the environment and caused severe air pollution in China. This study empirically examines causes of air pollution in China. Panel-corrected standard errors procedure (PCSE) was used to analyze major determinants of increasing or reducing emissions of sulfur dioxide (SO2) and nitrogen oxides (NOX) in 30 Chinese provinces. The estimation results show that SO2 emission is mitigated as per capita regional GDP increases, but the relation between emission of NOX and per capita regional GDP is found to have an inverse N-shaped curve, which implies that emission of NOX is ultimately expected to decline with economic growth. As for increasing factors of air pollutants, electricity consumption is a significant common source of SO2 and NOX emissions. Moreover, the results show that increment of coal consumption significantly affects emission of SO2 while increase of natural gas consumption reduce emission of SO2. On the other side, investment in energy industry, and investment on treatment of waste gases are determinants of mitigating emissions of SO2, but have no impact on NOX. Consumption of diesel, truck ratio and number of vehicles increase emission of NOX. Meanwhile, higher precipitation rate is a common determinant of mitigating emissions of SO2 and NOX. Policy implications are suggested in the conclusion.

A Study on the Comparison of Emission Factor Method and CEMS (Continuous Emission Monitoring System) (배출계수법과 연속자동측정법에 의한 배출량 비교 연구)

  • Jang, Kee-Won;Lee, Ju-Hyoung;Jung, Sung-Woon;Kang, Kyoung-Hee;Hong, Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.5
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    • pp.410-419
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    • 2009
  • Generally, air pollutant emission at workplace is estimated by two methods: indirect methods using emission factors and direct methods based on CEMS (Continuous Emission Monitoring System). CAPSS (Clean Air Policy Support System) is a representative indirect method and the national air pollutant database of Korea. However, characteristics of some workplaces may create a gap between CAPSS and CEMS data. For improving of emission data accuracy, emission data of CEMS (named CleanSYS) equipped at 138 target workplaces were compared with those of CAPSS. As a result, $SO_x$ and $PM_{10}$ emission levels obtained by CAPSS were lower than those of CleanSYS. $SO_x$ and $PM_{10}$emission ratios were 61.5% and 71.2% lower respectively, showing the biggest gaps. On the other hand, $NO_x$ emission of CAPSS was higher by 10.4%. $SO_x$ showed the biggest difference in 'Energy industry combustion' and $NO_x$ did in 'Production Process' within the SCC category. $PM_{10}$ presented a large gap in 'Manufacturing industry combustion.' The differences in $SO_x$ between the two systems occurred because some large-size facilities lack pollution controllers or efficient pollution controllers. Based on this study, CAPSS emission database of Korea will improve accuracy through adopting CEMS emission system, which enables more efficient national atmospheric policies and workplace management.

Carbon Emission Disclosure, Good Corporate Governance, Financial Performance, and Firm Value

  • KURNIA, Pipin;DARLIS, Edfan;PUTR, Adhitya Agri
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.12
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    • pp.223-231
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    • 2020
  • This research aims to examine (1) the effect of carbon emission disclosure on firm value, (2) the effect of good corporate governance on firm value, (3) the mediating role of financial performance between carbon emission disclosure and firm value, and (4) the mediating role of financial performance between good corporate governance and firm value. The research sample includes 43 mining, agro, and manufacturing firms listed in the Indonesian Stock Exchange over the 2015-2017 period. Carbon emission disclosure is measured by an indicator of the Global Reporting Initiative Series of Environmental Aspect. Good corporate governance is measured by the corporate governance score of shareholder rights, boards of directors, outside directors, audit committee and internal auditor, and disclosure to investors. Financial performance is measured by return on assets, while firm value is measured by Tobin's Q. Data analysis uses the structural equation modeling. The result shows carbon emission disclosure and good corporate governance have no direct effect on firm value. On the other hand, financial performance mediates the effect of carbon emission disclosure and good corporate governance on firm value. It shows that higher carbon emission disclosure and good corporate governance are meaningless for the investor if they do not give any financial performance improvement.