• Title/Summary/Keyword: NO$_x$ Emission

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Analysis of Reduction Strategies for Air Pollutants Discharged from Emission Sources and their Impact on the Seoul Metropolitan Area

  • Lee, Woo-Keun;SunWoo, Young
    • Asian Journal of Atmospheric Environment
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    • v.1 no.1
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    • pp.14-18
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    • 2007
  • The Korean government enacted the "Special Law for Improving Air Quality of Metropolitan Area" in 2003. According to this plan, Korean government plan to lower the concentrations of $PM_{10}$ and $NO_x$ to $40{\mu}g/m^3$ and 22 ppb, respectively, by 2014. In this study, we analyze emission reduction strategies to lower their concentration. Emission reduction for the supply of mass energy and regenerative energy are compared with several scenarios. According to the results, 713 t/y of $NO_x$ and 165 t/y of $PM_{10}$ will be reduced by enhancing the number of households supplied by local heating and air conditioning. And also 5 t/y of $PM_{10}$ and 312 t/y of $NO_x$ will be reduced by replacing conventional energy with solar energy by 2014.

Verification of Mobile Emission for CMAQ using an Observation-based Approach in Seoul Metropolitan Area (수도권 지역에서 대기질 측정망 자료를 이용한 광화학모델의 이동오염원 배출량 검증)

  • Lee, Yong-Mi;Lee, Hyun-Ju;Yoo, Chul;Song, Jeong-Hui;Kim, Ji-Young;Hong, Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.5
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    • pp.369-381
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    • 2009
  • The objective of this study was to simulate surface air pollutants and to examine reliability of mobile emission for CMAQ system using an observation-based approach in the Seoul Metropolitan Area. Accurate assessment of emissions from mobile source is one of the most debatable parts in the entire emissions inventory process. For this study, we evaluated the official emission inventories of Volatile Organic Compounds (VOCs) and nitrogen oxides ($NO_x$) using an observation-based approach. In this paper, we achieved VOCs/CO and $NO_x$/CO ratios derived from ambient measurements taken from June to August of 2005 in early morning (07:00~08:00). And we compared them with those derived from the emission inventory. Based on these ratios and on the assumption that official inventory of CO emissions is reasonably accurate, mobile emissions of $NO_x$ seem to be slightly overestimated and VOCs emissions significantly underestimated. The results of simulations using modified emission of mobile source were in closer agreement with the observation results except NO. Predicted NO values based on revised $NO_x$ emissions were considerably lower than the observed values. Using modified emission inventories brings the modeled values into closer agreement with observed ozone levels in Seoul. Especially in case of CO, $NO_x$ and VOCs emission, the modified values were suitable for simulating ozone levels in Seoul and Gyeonggi. However, ozone values predicted using the modified emissions were higher than the observed and predicted values based on original emissions. According to the 95 percentile ozone concentrations, emission revised by CO, $NO_x$ and VOCs from mobile source was the best for predicting high concentration.

HCCI Combustion Engines with Ultra Low CO2 and NOx Emissions and New Catalytic Emission Control Technology (CO2/NOx 초저배출형 HCCI 엔진 연소기술과 신촉매제어기술)

  • Kim, Moon-Hyeon
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1413-1419
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    • 2008
  • The Kyoto Protocol, that had been in force from February 16, 2005, requires significant reduction in $CO_2$ emissions for all anthropogenic sources containing transportation, industrial, commercial, and residential fields, etc, and automotive emission standards for air pollutants such as particulate matter (PM) and nitrogen oxides $(NO_x)$ become more and more tight for improving ambient air quality. This paper has briefly reviewed homogeneous charge compression ignition (HCCI) combustion technology offering dramatic reduction in $CO_2,\;NO_x$ and PM emissions, compared to conventional gasoline and diesel engine vehicles, in an effort of automotive industries and their related academic activities to comply with future fuel economy legislation, e.g., $CO_2$ emission standards and corporate average fuel economy (CAFE) in the respective European Union (EU) and United States of America (USA), and to meet very stringent future automotive emission standards, e.g., Tier 2 program in USA and EURO V in EU. In addition, major challenges to the widespread use of HCCI engines in road applications are discussed in aspects of new catalytic emissions controls to remove high CO and unburned hydrocarbons from such engine-equipped vehicles.

A Numerical Study on the $NO_{x}$ Reduction in 500MW Pulverized Coal Tangential Firing Boiler (500MW급 접선분사형 미분탄보일러의 $NO_{x}$ 저감에 관한 수치해석적 연구)

  • Choi, Choeng-Ryul;Kang, Dae-Woong;Kim, Chang-Nyung;Park,, Man-Heung;Kim, Kwang-Chu;Kim, Jong-Kill
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.967-972
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    • 2001
  • The emission of $NO_{x}$ during coal combustion is a major reason of environment impact. $NO_{x}$ is an acid rain precursor and participates in the generation of smog through ozone production. $NO_{x}$ can be divided into thermal $NO_{x}$, fuel $NO_{x}$ and prompt $NO_{x}$. Thermal $NO_{x}$ is formed in a highly temperature condition dependent. Fuel $NO_{x}$ is dependent on the local combustion characteristics and initial concentration of nitrogen bound compound, while prompt $NO_{x}$ is formed in a significant quantity in some combustion environments, such as low temperature and short residence times. This paper presents numerical simulation of the flow and combustion characteristics in the furnace of a tangential firing boiler of 500MW with burners installed at the every comer of the furnace. The purpose of this paper is to investigate the reduction of $NO_{x}$ emission in a 500MW pulverized coal tangential firing boiler with different OFA's and burner angles. Calculations with different air flow rates of over fired air(OFA) and burner angles are performed.

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Characteristics of Flame Structure and $NO_X$ Emission in a Dump Gas Turbine as Fuel-Air Mixing Degrees (희박 예혼합 정도에 따른 모형 덤프 가스터빈 연소기의 화염 구조와 $NO_X$배출 특성)

  • Ryu, Hye-Yeon;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3452-3457
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    • 2007
  • Experiments were carried out in an atmopheric pressure, lab-scale gas turbine combustor to see the effect of partial premixing on unstable flame structure and $NO_X$ emission characteristics. The swirl angle is 45 deg., fuel-air mixing degrees were varied 0, 50, and 100% respectively at equivalence ration ranging from 0.53 to 0.79. The evaluation of phased-locked OH chemiluminescence images were acquired with an ICCD. $NO_X$ emission characteristics were also investigated at each experimental condition. The effect of the fuel-air mixing degree on the flame structure was obtained from phase-locked $OH^*$ images. And it was obtained from local heat release characteristics that the information about the region which the combustion instability was amplified or damped. It also could be confirmed that ${\sigma}$ has greatly influence on $NO_X $emission characteristics at lean regimes. It would be expected that it could provide invaluable data for understanding the mechanism of combustion instability

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Characteristics of Real-Driving CO2 and NOx Emissions Compared to Test Modes on Euro-6 LDVs Equipped with SCR and LNT (SCR 및 LNT가 적용된 Euro-6 소형 경유차의 실제도로 주행과 인증모드에서의 CO2 및 NOx 배출특성의 비교)

  • Lee, Jongtae;Kim, Jeongsoo;Chon, Mun Soo;Cha, Junepyo
    • Journal of ILASS-Korea
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    • v.21 no.4
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    • pp.200-206
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    • 2016
  • Recently, the certification procedure for exhaust emission regulation of LDV has tested with the NEDC mode in the laboratory. But the on-road exhaust emissions exceed the standard emission limits. Therefore, it is important to analyze the real-driving emissions (RDE) with a portable emissions measurement system (PEMS). In present study, the on-road emissions were measured with a PEMS and evaluated by moving averaging window (MAW) method. Also, it was compared with the $CO_2$ and $NO_x$ emissions for real-driving and test modes from euro-6 light-duty vehicles equipped with SCR and LNT systems. In results, on-road $NO_x$ emission has been 2.3-10.0 times higher than the standard $NO_x$ emission limit on NEDC mode. The reason was that the test modes did not reflect traffic and various real-driving patterns sufficiently.

Diesel SCR Development to Meet US Tier2 Bin5 Emission Regulation (북미 Tier2 Bin5 규제 대응을 위한 디젤 SCR 개발)

  • Lee, Kang-Won;Kang, Jung-Whun;Jo, Chung-Hoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.2
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    • pp.98-104
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    • 2011
  • The introduction of a diesel engine into the passenger car and light duty applications in the United States involves significant technical challenges for the automotive makers. This paper describes the SCR System optimization procedure for such a diesel engine application to meet Tier2 Bin5 emission regulation. A urea SCR system, a representative $NO_x$ reduction after-treatment technique, is applied to a 3.0 liter diesel engine. To achieve the maximum $NO_x$ reduction performance, the exhaust system layout was optimized using series of the computational fluid dynamics and the urea distribution uniformity test. Furthermore a comprehensive simulation model for the key factors influencing $NO_x$ reduction performance was developed and embedded in the Simulink/Matlab environment. This model was then applied to the urea SCR system and played a key role to shorten the time needed for SCR control parameter calibration. The potential of a urea SCR system for reducing diesel $NO_x$ emission is shown for FTP75 and US06 emission standard test cycle.

The Study on NOx Emission for Hydrogen Fueled Engine(1) (수소기관에서 NOx 특성에 관한 연구(1))

  • Lee, S.J.;Choi, G.H.
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.2
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    • pp.91-97
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    • 1997
  • The goals of this research are to understand the $NO_x$ emission in direct injected diesel engine with premixed hydrogen fuel. Hydrogen fuel was supplied into the test engine through the intake pipe. Amount of hydrogen-supplemented fuel was 70 percent basis heating value of the total fuel. The effects of intake air temperature on $NO_x$ emission were studied. The intake air temperature was controlled by flow rate of liquid nitrogen. The major conclusions of this work include : (i) the tested engine was run without backfire under 70 percent hydrogen fuel supplemented. (ii) radicals of nitrogen gas in the intake pipe were increased by 30 percent and cylinder gas temperature was decreased by 24 percent as the intake air temperature were changed from $23^{\circ}C$ to $0^{\circ}C$ ; and (iii) $NO_x$ emission per unit heating value of supplied fuel was decreased by 45 percent with same decrease of intake air temperature.

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Prediction of Biodiesel Combustion, CO and NOX Emission Characteristics in Accordance with Equivalence Ratio (당량비 변화에 따른 바이오디젤 연소 및 CO, NOX 생성 특성 예측)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of the Korean Society of Combustion
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    • v.21 no.1
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    • pp.1-7
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    • 2016
  • This study was performed to provide the basic information of the combustion, CO and $NO_X$ characteristics of biodiesel in accordance with equivalence ratio. The closed homogeneous reactor model used for the analysis. The analysis conditions were set to 900 K of the initial temperature, 20 atm of initial pressure and equivalence ratio was changes from 0.6 to 1.4. The results of analysis were predicted and compared in terms of combustion temperature, combustion pressure, CO and $NO_X$ emissions. The results of combustion characteristics showed that ignition delay was decreased and the combustion temperature and combustion pressure was increased in accordance with equivalence ratio. CO emission was decreased in lean condition(${\Phi}$ < 1.0), however, CO emission was increased in rich condition(${\Phi}$ > 1.0) because oxygen supply insufficient. $NO_X$ emission showed the largest amount in condition 0.8 of equivalence ratio because the oxygen concentration was sufficient.

THE EFFECTS OF EGR AND SPLIT FUEL INJECTION ON DIESEL ENGINE EMISSION

  • Gao, Z.;Schreiber, W.
    • International Journal of Automotive Technology
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    • v.2 no.4
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    • pp.123-133
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    • 2001
  • An important goal in diesel engine research is the development of a means to reduce the emission of oxides of nitrogen ($NO_x$) and soot particulate. A phenomenological model based on the multizone concept is used in the current paper to analyze and compare the effects of exhaust gas recirculation (EGR) and split fuel injection on emission from a compression-ignited, direct-injection engine. The present results show that $NO_x$ can be reduced with a minimum penalty of soot particle emission with cooled EGR. Compared with EGR, split fuel injection has a higher soot penalty at a given level of $NO_x$ reduction.

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