• Bulletin of the Korean Chemical Society
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• v.27 no.6
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• pp.893-898
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• 2006

Novel bis- and tris-crown ethers were synthesized from 1-aza and diaza-crown ethers with 2-acryloyloxy-methyl crown ethers through Michael addition. The synthesized bis- and tris-crown ethers were characterized by their elemental analyses, $^1H$-NMR, $^{13}C$-NMR, mass spectra, IR spectra, respectively. The complexation behavior of the bis- and tris-crown ethers with $Li^+$, $Na^+$, $Na^+$, $Rb^+$, $Cs^+$ was examined by $^1H$-NMR, FAB mass, and UV spectrometry.

• Microbiology and Biotechnology Letters
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• v.10 no.1
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• pp.39-43
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• 1982

t-Cinnamamide has been isolated from the culture filtrate of the isolates, Streptomyces. sp. No.297 The identity of the compound was established by UV and IR spectra, NMR, mass spectra and by chemical reactions. Through antimicrobial activity test using a two-fold serial agar dilution mothjod, t-cinnamamide showed strong growth inhibitory activity against Pellicularia sasakii, Pyriculario oryzae and some pathogenic fungi, but not inhibitory over procaryotes tested.

• Journal of the Korean Chemical Society
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• v.24 no.6
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• pp.457-462
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• 1980

Phosphates and phosphoric amides were synthesized by the reaction of phosphoryl chloride with allyl alcohol, 2,3-dibromopropanol, 2-pyrrolidone and ethylenimine. All of these compounds were thermally very unstable. Allyl phosphorodichoridate and diallyl phosphorochloridate gave significant amount of polymeric products when they were distilled. IR spectra showed characteristic P=O stretching bands between 1300 and $1200 cm^{-1}$ and NMR spectra were very complicated due to the long range coupling effect of phosphorus atom. And mass spectrum of 2,3-dibromopropyl phosphorodichloridate gave no indication of molecular ion peak.

• Journal of the Korean Magnetic Resonance Society
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• v.15 no.1
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• pp.14-24
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• 2011

We have performed Liquid Chromatography-Solid Phase Extraction-NMR (LC-SPE-NMR) analysis for liquid crystalline mixture and elucidated the structures of selected components by NMR spectra. Combining the results of one-dimensional 1H experiments as well as homonuclear and heteronuclear two-dimensional experiments, we could analyze the molecular structure of the liquid crystal singles whose structure had not been interpretable by mass spectrometry alone.

• Korean Journal of Medicinal Crop Science
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• v.12 no.3
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• pp.179-182
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• 2004

Bioassay-directed fractionation of the dried roots of Salvia miltiorrhiza led to the isolation of abietane tanshinones, cryptotanshinone and dibydrotanshinone I. Their structures were elucidated using $^1H-\;and\;^{13}C-NMR$, UV, IR and mass spectral analyses. These compounds exhibited a moderate antimicrobial activities against Staphylococcus epidemidis, Staphylococcus aureus, and Staphylococcus pyogene.

• YAKHAK HOEJI
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• v.22 no.2
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• pp.83-86
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• 1978

A colorless sublime needles (A), $C_{10}H_{10}O_{4}$, mp$142~143\circ$ was isolated from the fresh flowers of Chrysanthemun sinense Sabine in 0.16% yield. Its ir, nmr and mass spectral data suggested that it may have an aromatic methylester structure. Hydrolysis of this substane with 10% sodium hydroxide solution yielded terephthalic acid and methanol. This substance was confirmed as dimethyl terephthalate by comparison of ir and nmr spectra, and TLC and GC behaviors of an authentic sample which was prepared from terephthalic acid by methylation. This is the first report that dimethly terephthalate was isolated in the Composite plants.

• Archives of Pharmacal Research
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• v.12 no.1
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• pp.48-51
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• 1989

A new polyacetylene compound with cytotoxic activity against L1210 cells having diyne-ene and epoxy moiety, named panaxyne epoxide, was isolated from Panax ginseng C.A. Meyer. The chemical structure of the polyacetylene was determined to be tetradeca-13-ene-1,3-diyne-6,7-epoxide by UV, IR, $^1H-NMR,\;^{l3}$C-NMR and mass spectra.

• Bulletin of the Korean Chemical Society
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• v.18 no.1
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• pp.80-86
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• 1997

Nine new solubility-increased container hosts having eight undecyl substituents were synthesized and characterized. 1H NMR spectral data showed integral inclusion state of carceplexes and their stability. 1H NMR chemical shifts of guest DMA were correlated to the host's cavity dimensions shrinked by constrictive binding. Carceplex and hemicarcerand showed their distinctive FD mass spectra.

• Investigative Magnetic Resonance Imaging
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• v.12 no.2
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• pp.107-114
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• 2008

Purpose : The aim of this study is to determine possibility of application of in vivo proton ($^1H$) magnetic resonance spectroscopy (MRS) in distinguishing cystic mass arising around pancreas by comparison of in vivo MRS, in vitro MRS using 3T MR machine, based on nuclear magnetic resonance (NMR). Materials and Methods : We obtained spectra of in vivo MRS, in vitro MRS and NMR from abdominal mass arising around pancreas (mucinous cystic neoplasm=5, intraductal papillary mucin producing tumor=5, pseudocyst=1, and lymphangioma=1). We estimated existence of peak of in vivo MRS, and in vitro MRS concordant to that of NMR. We also evaluated differential peak for predicting specific disease. Results : Correlation of presence of peak with NMR showed showed sensitivity of 29.6%, specificity of 82.6% and accuracy of 67.7% on in vivo MRS (p = 0.096, McNemar test), sensitivity of 57.1% and specificity of 92.6% and accuracy of 82.3% on in vitro MRS (p = 0.362, McNemar test). The spectra of NMR for IPMT showed more frequent peaks at 3.5-4.0 ppm (p=0.026). Conclusion : Although chemical analysis, using NMR could be regarded as possible tool to differentiate cystic masses, in vivo and in vitro MRS need further technical evolution for clinical application.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.428-429
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• 2005

Novel fluoroionophore of dibenzothiazolyl-dibenzo-crown ethers were synthesized from diformal-dibenzo 18-crown-6 (24-crown-8) with 2-aminothiophenol, and they were characterizated by $^1H$-NMR, $^{13}C$-NMR, IR spectrum, Mass spectrum, elemental analyses, respectively. The fluorescent properties of the newly synthesized crown ether were examined with $Li^+$, $Na^+$, $K^+$, $Rb^+$, $Cs^+$, $NH_4^+$ and $CF_3COOH$, respectively. With protonation using $CF_3COOH$, the absorption bands of the new crown ethers are further blue shifted, the maximum emission wavelengths further red shifted.