• 제목/요약/키워드: NMA

검색결과 38건 처리시간 0.021초

Interplay of the Intramolecular Water Vibrations and Hydrogen Bond in N-Methylacetamide-Water Complexes: Ab Initio Calculation Studies

  • Kim, Joo-Hee;Cho, Min-Haeng
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권8호
    • /
    • pp.1061-1068
    • /
    • 2003
  • The correlation between the water and N-methylacetamide (NMA) intramolecular vibrational frequencies and the hydrogen-bond length in a variety of NMA-H₂O and NMA-D₂O complexes was investigated by carrying out ab initio calculations. As the hydrogen-bond length decreases, the frequencies of bending and stretching modes of the hydrogen-bonding water increases and decreases, respectively, and the amide I and II (III) mode frequencies of the NMA decreases and increases, respectively. In this paper, correlation maps among the amide (I, II, and III) modes of NMA and three intramolecular water modes are thus established, which in turn can be used as guidelines for interpreting two-dimensional vibrational spectra of aqueous NMA solutions.

Growth Associated Hormones Response and Fat Metabolism Change in Finishing Pigs Fed with n-Methyl-d, L-Aspartate

  • Xi, Gang;Xu, Zirong;Xiao, Ping
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제15권7호
    • /
    • pp.1026-1030
    • /
    • 2002
  • A trial was conducted to investigate the effect of dietary NMA on several growth associated hormones and fat metabolism in finishing pigs. A total of 84 crossbred finishing pigs (average initial BW of $56{\pm}$0.37kg) were divided into 6 pens, 14 pigs per pen (7 gilts and 7 barrows per pen). 3 pens of pigs were fed with control diet (corn-soybean meal) and the others were fed control diet addition with 50 mg/kg NMA. During the trial, all pigs were given free access to feed and water. After 44 days trial, 8 pigs from each treatment (4 gilts and 4 barrows, weight similar to average group weight, $86.94{\pm}0.71kg$ for control group, and $90.55{\pm}1.51kg$ for NMA treated group) were sacrificed to collect the sample of the liver, longissimus muscle, subcutaneous fat (10th rib). The addition of NMA in diet increased the IGF-I, Insulin, T3, T4 levels in serum by 50.68% (p<0.05), 38.36% (p<0.05), 123.33% (p<0.01), 60.58% (p<0.03), respectively. Meanwhile, IGF-I level in the liver and the muscle were increased with 17.83% (p<0.03) and 26.00% (p<0.03) with addition of NMA. The data from subcutaneous fat (10th rib) analysis showed that supplement of 50 mg/kg NMA decreased the total activities of malic dehydrogenase (MDH) by 20.54% (p<0.05), glucose-6- phosphate dehydrogenase (G-6-DPH) by 16.97% (p<0.05), and decreased the specific activities of MDH and G-6-DPH by 37.46% (p<0.01) and 35.06% (p<0.01), respectively. The hormone sensitive lipase (HSL) total activity was increased by 25.00% (p<0.05) in NMA treated pigs. These results indicated that addition of 50 mg/kg NMA to diet can induce the endocrine great change in finishing pigs, furthermore, inhibit the fat synthesis through suppressing lipogenic enzymes and promote the fat degradation by elevating HSL activity in finishing pigs.

DGEBA/NMA/2,4,6-tris(dimethylaminomehyl)phenol 시스템의 경화거동 및 Morphology (Curing Behavior and Morphology of DGEBA/NMA/2,4,6-tris(dimethylaminomethyl) phenol System)

  • 김민영;김성호;최영선;김원호;황병선
    • 한국복합재료학회:학술대회논문집
    • /
    • 한국복합재료학회 2001년도 춘계학술발표대회 논문집
    • /
    • pp.118-121
    • /
    • 2001
  • The investigation of cure kinetics and morphology studies on DGEBA/PEI/Anhydride system were performed by differential scanning calorimetry and scanning electron microscopy. Autocatalystic kinetics model was applied by isothermal scan test. Ozawa method and Kissinger method was applied by temperature scan. Activation energy was 95kJ/mol for neat DGEBA/NMA, 120kJ/mol for DGEBA/PEI(10p.h.r.)/NMA. The generation of secondary phase of PEI was observed and its size was grown up by increasing contents of PEI.

  • PDF

천마를 이용한 뇌혈관성 질환의 예방을 위한 양생약선(養生藥膳)의 개발을 위한 연구 (2). 천마를 주재료로 한 다식의 제조 및 관능적 특성 (Study on the Gastrodiae rhizoma as Applications in YackSun(Medicated Diets) for Preventing of Cerebral Cardiovascular Disease (2). Development and Sensory Characteristics of Dasik Made from Gastrodiae rhizoma)

  • 정인창;나혜영;이윤희;박성혜
    • 동아시아식생활학회지
    • /
    • 제17권2호
    • /
    • pp.250-257
    • /
    • 2007
  • This study was performed to provide basic for predicting the usefulness of Gastrodiae rhizoma(Cho'nma) as a food material for oriental applied diet therapy(YackSun). Thus, Gastrodiae rhizoma was used to develop a traditional Korean snack, Dasik. As a useful food resource, Gastrodiae rhizoma along with Cortex fraxini powder, was used to prepare Dasik. Cho'nma powder was added to the Dasik 63.2%(Dasik-1), 42.2%(Dasik-2) and 21.0%(Dasik-5) of Cho'nma powder to Dasik in one piece(5 g). The moisture and crude ash contents of the Dasik-1, 2 and 3 were analyzed. Physio-chemical analysis and a sensory test were also performed on the Dasik. Moisture and crude ash contents of Dasik-1 were 20.16% and 0.65%, respectively. Moisture and crude ash contents of Dasik-2 and Dasik-3 were 22.92 and 27.17% and 0.49 and 0.23% respectively. from the color test, the t value of Dasik-1 was found to be significantly low but the b value of Dasik-1 significantly high compared with the other preparations. The addition of Cho'nma had a tendency to impart high hardness, fracturability, gumminess and chewiness. Therefore, the addition of Cho'nma made the texture of Dasik denser. From the sensory test, the color, chewiness and overall acceptability of Dasik-1 were found to be significantly high. In conclusion, the addition of 63.2% Cho'nma per piece would be a useful recipe to enhance the quality of Dasik, and the flour Cho'nma showed better result than the Dasik-2 and Dasik-3.

  • PDF

TSMA 방법을 이용한 순환 굵은골재 콘크리트의 기계적 성능 (Mechanical Properties of Recycled Coarse Aggregate concrete using Two-Stage Mixing Approach)

  • 권성준;임희섭;이한승;임명관
    • 한국구조물진단유지관리공학회 논문집
    • /
    • 제22권4호
    • /
    • pp.60-67
    • /
    • 2018
  • 본 논문은 콘크리트 배합 방식(NMA, TSMA1, TSMA2)에 따른 순환 굵은골재 치환량에 따른 콘크리트의 기계적 성능을 비교 평가하였다. 실험은 순환 굵은골재를 0%, 50%, 100%로 3수준으로 콘크리트의 배합 방식에 따라 실험을 진행하였다. 굳지 않은 콘크리트에서는 공기량, 슬럼프, 단위용적질량 실험을 진행하였으며, 경화 콘크리트에서는 압축강도 및 휨강도 시험을 진행하였다. 본 연구의 실험결과 NMA 방식과 비교하여 TSMA 방식에서 강도 저하가 나타나고 있음을 확인할 수 있었다. 하지만, 이는 순환 굵은골재가 다량 치환됨에 따른 것으로 사료된다. 순환 굵은골재가 다량 치환됨에 따라 슬럼프 증진, 공기량 증진, 강도 저하가 나타남을 확인하였다.

DP 가공조건이 면직물의 역학적 성질과 태에 미치는 영향 (Effect of DP Finishing Conditions on the Mechanical Properties and Hand of Cotton Fabrics)

  • 신윤숙
    • 한국의류학회지
    • /
    • 제24권3호
    • /
    • pp.440-447
    • /
    • 2000
  • The effects of DP finishing conditions including process technique and finishing agent on the mechanical properties and hand of cotton fabrics were investigated. 100% cotton fabrics were treated with NMA/DMDHEU and NMA/YF using wet-fixation and steam-fixation process. For comparison, conventional pad-dry-cure process was used with DMDHEU. After DP finishing, tensile and compressional resilience increased and bending hysteresis decreased, resulting in the improvement of dimensional stability of cotton fabric. WF and SF process rendered fabrics better shear properties, tensile energy, and compressional linearity and energy than PDC process. However, SF process produced fabrics with higher geometrical roughness than WF process. After DP finishing, primary hand values except Koshi increased, resulting in the increase of total hand value of cotton fabric.

  • PDF

THE GALACTIC-SCALE MOLECULAR OUTFLOWS IN STARBURST GALAXIES NGC 2146 AND NGC 3628

  • TSAI, AN-LI;MATSUSHITA, SATOKI
    • 천문학논총
    • /
    • 제30권2호
    • /
    • pp.499-502
    • /
    • 2015
  • Starburst galaxies have strong star formation activity and generate large scale outflows which eject a huge amount of gas mass. This process affects galaxy activity, and therefore, the detailed study of nearby starburst galaxies could provide valuable information for the study of distant ones. So far there have been only a few studies of galactic-scale molecular outflows due to the sensitivity limitation of telescopes. Our study provides two nearby examples, NGC 2146 and NGC 3628. We used Nobeyama Millimeter Array (NMA) CO(1-0) data, Chandra soft X-ray data, and NMA 3 mm data to study the kinematics of molecular outflows, their interaction with ionized outflows, and the star forming activity in the starburst region. We found that the gas ejected through molecular outflows is much more significant than that used to form stars.

Efficacy and Safety of Laser Surgery and Transurethral Resection of the Prostate for Treating Benign Prostate Hyperplasia: a Network Meta-analysis

  • Wang, Li;Yu, Qiu-Yan;Liu, Yan;Zhu, Zhen-Li;Huang, Yuan-Wei;Li, Ke
    • Asian Pacific Journal of Cancer Prevention
    • /
    • 제17권9호
    • /
    • pp.4281-4288
    • /
    • 2016
  • Background: Traditional meta-analyses or systematic reviews of randomized controlled trials (RCTs) have been used to compare laser surgeries and transurethral resection of the prostate (TURP) for benign prostate hyperplasia (BHP), but they cannot provide a hierarchy regarding efficacy and safety of treatment. Objective: We therefore performed a network meta-analysis (NMA) to compare and create hierarchies for efficacy and safety of TUPR and laser surgeries for BPH. Materials and Methods: We searched for reports of RCTs published up to April 25, 2015. After methodological quality assessment and data extraction, we performed an NMA to compare TURP and laser surgeries for BPH. Results: We ranked the treatments of TURP and laser surgeries for BPH. For IPSS at 6 months, holmium laser resection of the prostate (HoLRP) ranked the first-best and at 12 months, holmium laser enucleation of the prostate (HoLEP). For Qmax at 6 and 12 months, HoLEP ranked the first-best; for operative time it was TURP; for cathedral removal time, diode laser enucleation of the prostate (DiLEP) ranked the first-best. Conclusions: Although TURP is considered the gold standard for treating BPH, it is not better in terms of efficacy and safety compared with the laser surgery. Our NMA created hierarchies for the 9 types of surgery in terms of efficacy and safety, which should help clinicians choose the best approach for the individual patient.

Pharmacological and non-pharmacological strategies for preventing postherpetic neuralgia: a systematic review and network meta-analysis

  • Kim, Junhyeok;Kim, Min Kyoung;Choi, Geun Joo;Shin, Hwa Yong;Kim, Beom Gyu;Kang, Hyun
    • The Korean Journal of Pain
    • /
    • 제34권4호
    • /
    • pp.509-533
    • /
    • 2021
  • Background: Postherpetic neuralgia (PHN) is a refractory complication of herpes zoster (HZ). To prevent PHN, various strategies have been aggressively adopted. However, the efficacy of these strategies remains controversial. Therefore, we aimed to estimate the relative efficacy of various strategies used in clinical practice for preventing PHN using a network meta-analysis (NMA). Methods: We performed a systematic and comprehensive search to identify all randomized controlled trials. The primary outcome was the incidence of PHN at 3 months after acute HZ. We performed both frequentist and Bayesian NMA and used the surface under the cumulative ranking curve (SUCRA) values to rank the interventions evaluated. Results: In total, 39 studies were included in the systematic review and NMA. According to the SUCRA value, the incidence of PHN was lower in the order of continuous epidural block with local anesthetics and steroids (EPI-LSE), antiviral agents with subcutaneous injection of local anesthetics and steroids (AV + sLS), antiviral agents with intracutaenous injection of local anesthetics and steroids (AV + iLS) at 3 months after acute HZ. EPI-LSE, AV + sLS and AV + iLS were also effective in preventing PHN at 1 month after acute HZ. And paravertebral block combined with antiviral and antiepileptic agents was effective in preventing PHN at 1, 3, and 6 months. Conclusions: The continuous epidural block with local anesthetics and steroid, antiviral agents with intracutaneous or subcutaneous injection of local anesthetics and a steroid, and paravertebral block combined with antiviral and antiepileptic agents are effective in preventing PHN.