• Title/Summary/Keyword: NI method

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Removal of Copper from the Solution Containing Copper, Nickel, Cobalt and Iron (구리, 니켈, 코발트, 철 혼합용액(混合溶液)으로부터 구리의 제거(除去))

  • Park, Kyung Ho;Nam, Chul Woo;Kim, Hyun Ho;Barik, Smruti Prakash
    • Resources Recycling
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    • v.22 no.6
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    • pp.48-54
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    • 2013
  • The methods to separate and remove copper in the mixed solution ((399 ppm Cu, 208 ppm Fe, 15.3 g/L Ni, 2.1 g/L Co) with nickel, cobalt and iron were investigated. With hydroxide precipitation method, copper and iron ions were completely precipitated and removed from the solution at pH 7 while some nickel and cobalt also were precipitated. 99.75% copper could be precipitated and removed as copper sulfide from the solution with adding $Na_2S$ (1.25 w/v concentration) of 2 times equivalent of Cu at pH 1. Copper was selectively absorbed on TP 207 ion exchange resin at equilibrium pH 2.0 and could be eluted from copper-loaded resin using 5% $H_2SO_4$.

Fabrication of Coated Conductor by Continuous PVD Methods (연속 공정 PVD 방법에 의한 Coated Conductor 제조)

  • Ko, Rock-Kil;Chung, Jun-Ki;Kim, Ho-Sup;Ha, Hong-Soo;Shi, Dongqi;Song, Kyu-Jeong;Park, Chan;Yoo, Sang-Im;Moon, Seung-Hyun;Kim, Young-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1241-1245
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    • 2004
  • Continuous physical vapor deposition (PVD) method is one of many processes to fabricate long length coated conductor which is required for successful large-scale application of superconducting power devices. Three film deposition systems (pulsed laser deposition, sputtering, and evaporation) equipped with reel-to-reel(R2R) metal tape moving apparatus were installed and used to deposit multi-layer oxide thin films. Both RABiTS and IBAD texture templates are used. IBAD template consists of CeO$_2$(PLD)/YSZ(IBAD) on stainless steel(SS) metal tape, and RABiTS template has the structure of CeO$_2$/YSZ/Y$_2$O$_3$ which was continuously deposited on Ni-alloy tape using R$_2$R evaporation and DC reactive sputtering in a deposition system designed to do both processes. 0.4 m-long coated conductor with Ic(77 K) of 34 A/cm was fabricated using RABiTS template. 0.5 m and 1.1 m-long coated conductor with Ic(77 K) of 41 A/cm and 26 A/cm were fabricated using IBAD template.

Long length HTS coated conductor by RABiTS-PLD method (RABiTS-PLD 법을 이용한 장선 박막형 고온초전도선재)

  • Ko, Rock-Kil;Kim, Ho-Sup;Ha, Hong-Soo;Yang, Joo-Sang;Park, Yu-Mi;Song, Kyu-Jeong;Oh, Sang-Soo;Park, Chan;Kim, Young-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.50-51
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    • 2005
  • 냉간 압연과 열처리 공정을 통해 2축 배향성을 가지는 금속 기판 위에 산화물 박막을 증착 시켜 같은 정도의 2축 배향성을 갖도록 제조된 RABiTS template 위에 YBCO 초전도체를 PLD 방법으로 증착하여 YBCO coated conductor 선재를 제조하였다. RABiTS template은 NiW/$Y_2O_3$/NSZ/$CeO_2$ 구조로 DC reactive sputtering와 PLD 방법에 의해 증착되었다. 모든 공정은 reel-to-reel 방식의 연속 공정으로 이루어졌다. 1m와 10m급의 장선 고온초전도선재를 제조하고, 이에 대한 전기적 특성과 초전도 및 다층 산화물 완충층에 대한 결정성, 표면 특성에 대한 분석을 수행하였다. 그 결과 1m 길이에서 end-to-end 107 A와 10.6m 길이에서 end-to-end 51A의 임계 전류를 획득하였다. 제조된 박막형 선재의 초전도 층과 다층의 산화물 완충층 모두 금속 기판의 결정성을 그대로 유지하면서, epitaxial하게 성장하였으며, 최종 YBCO의 in-plane FWHM 값은 > $9^{\circ}$를 유지 하였다.

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Preparation and Properties of the Fast-Curing γ-Ray-Shielding Materials Based on Polyurethane

  • Ni, Minxuan;Tang, Xiaobin;Chai, Hao;Zhang, Yun;Chen, Tuo;Chen, Da
    • Nuclear Engineering and Technology
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    • v.48 no.6
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    • pp.1396-1403
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    • 2016
  • In this study, fast-curing shielding materials were prepared with a two-component polyurethane matrix and a filler material of PbO through a one-step, laboratory-scale method. With an increase in the filler content, viscosity increased. However, the two components showed a small difference. Curing time decreased as the filler content increased. The minimum tack-free time of 27 s was obtained at a filler content of 70 wt%. Tensile strength and compressive strength initially increased and then decreased as the filler content increased. Even when the filler content reached 60 wt%, mechanical properties were still greater than those of the matrix. Cohesional strength decreased as the filler content increased. However, cohesional strength was still greater than 100 kPa at a filler content of 60 wt%. The ${\gamma}$-ray-shielding properties increased with the increase in the filler content, and composite thickness could be increased to improve the shielding performance when the energy of ${\gamma}$-rays was high. When the filler content was 60 wt%, the composite showed excellent comprehensive properties.

ELISA detection of vivax malaria with recombinant multiple stage-specific antigens and its application to survey of residents in endemic areas

  • Kim, Sera;Ahn, Hye-Jin;Kim, Tong-Soo;Nam, Ho-Woo
    • Parasites, Hosts and Diseases
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    • v.41 no.4
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    • pp.203-207
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    • 2003
  • An ELISA was developed for the diagnosis of vivax malaria using multiple stage-specific recombinant antigens of Plasmodium vivax. The DNA from the whole blood of a malaria patient was used as template to amplify the coding regions for the antigenic domains of circumsporozoite protein (CSP-1), merozoite surface protein (MSP-1), apical merozoite antigen (AMA-1), serine repeat antigen (SERA), and exported antigen (EXP-1). Each amplified DNA fragment was inserted into pQE30 plasmid to induce the expression of His-tagged protein in Escherichia coli (M15 strain) by IPTG. His-tagged proteins were purified by Ni-NTA metal-affinity chromatography and used as antigens for ELISA with patient sera that were confirmed previously by blood smear examinations. When applied to patient sera, 122 (80.3%) out of 152 vivax malaria cases reacted to at least one antigen, while no reactions were observed with 128 uninfected serum samples. We applied this ELISA to the screening of 3,262 civilian residents in endemic regions near the DMZ, which resulted in 236 positively detected (7.2%) cases. This method can be applied to serological diagnosis and mass screening in endemic regions, or can be used as a safety test for transfusion blood in endemic areas.

Precise Flow Stress Analysis for the Occurrence of Dynamic Ferritic Transformation and Dynamic Recrystallization of Austenite in Low Carbon Steel (고온 변형 곡선을 이용한 동적 재결정 해석과 동적 상변태의 조기 예측)

  • Park, Nokeun
    • Korean Journal of Metals and Materials
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    • v.56 no.11
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    • pp.779-786
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    • 2018
  • There have been previous attempts to observe the occurrence of dynamic ferritic transformation at temperatures even above $Ae_3$ in a low-carbon steel, and not only in steels, but recently also in titanium alloys. In this study, a new approach is proposed that involves treating true stress-true strain curves in uniaxial compression tests at various temperatures, and different strain rates in 0.1C-6Ni steel, which is a model alloy used to decelerate the kinetics of ferrite transformation from austenite. The initial flow stress up to peak stress was used to analyze the change in dynamic softening phenomena, such as dynamic recovery, dynamic recrystallization, and dynamic transformation. It is worth mentioning that for predicting the occurrence of dynamic transformation, flow stress before reaching peak stress is much more sensitive to the change in the dynamic softening rate due to dynamic transformation, compared to peak stress. It was found that the occurrence of dynamic ferritic transformation could be successfully obtained even at temperatures above $Ae_3$ once the deformation condition was satisfied. This deformation condition is a function of both the strain rate and the deformation temperature, which can be described as the Zener - Hollomon parameter. In addition, the driving force of dynamic ferritic transformation might be much less than that of the dynamic recrystallization of austenite at a given deformation condition. By applying this technique, it is possible to predict the occurrence of dynamic transformation more sensitively compared with the previous analysis method using peak stress during deformation.

Exchange Coupling in CoZr/Ag/CoCr Trilayered Films (CoZr/Ag/CoCr 삼층박막의 교환결합)

  • 백종성;박용성;임우영;이수형;김종오
    • Journal of the Korean Magnetics Society
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    • v.8 no.6
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    • pp.357-361
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    • 1998
  • For CoZr/Ag/CoCr trilayered films deposited by DC and FR magnetron sputtering method, ferromagentic resonance experiments have been used to investigate the dependence of the exchange coupling between CoZr and CoCr layers separated by Ag layer on the thickness of the Ag layer. The coupling strength K increases with increasing Ag thickness up to 10 $\AA$ with a maximum value of 748 Oe, but oscillates with increasing Ag thickness in the range from 20 to 100 $\AA$. The coupling strength is positive for all samples. Hence, it seems that the exchange coupling between CoZr and CoCr layers separated by Ag layer is ferromagnetic.

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Evaluation of Heavy Metal Sources and Its Transfer and Accumulation to Crop in Agricultural Soils (농경지 토양의 중금속 오염원 및 농작물로의 중금속 전이·축적 평가)

  • Lim, Ga-Hee;Jo, Hun-Je;Park, Gyoung-Hun;Yun, Sung-Mi;Kim, Ji-In;Noh, Hoe-Jung;Kim, Hyun-Koo;Yoon, Jeong-Ki
    • Journal of Soil and Groundwater Environment
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    • v.23 no.3
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    • pp.27-42
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    • 2018
  • It is important to identify the contaminant sources and to evaluate the fate and transport of heavy metals to crops in agricultural lands. This study was conducted to evaluate metal sources and its transfer and accumulation to crop in agricultural soils. Pollution indices were calculated and multivariate analysis was performed to identify metal sources. To evaluate transfer and accumulation of metals to crops, the contents of phytoavailable metals were evaluated by using single extraction method and the correlation between metal content and soil properties was analyzed. Also the BCF was quantitatively evaluated for investigating the metal transition to each crop grown in the research area. As a result, Cr, Ni, and Co were expected to be mainly derived from geologic factors due to weathering of certain parent rocks. The content of nickel in soils of the research area was slightly higher than that of the concern level criteria based on total concentration, but the amount transferred and accumulated in the crops was actually low. Understanding the contamination characteristics by investigating the pollution sources of heavy metals and its transfer and accumulation to crops through various evaluation techniques could provide important information for proper management of the agricultural land.

Stochastic vibration suppression analysis of an optimal bounded controlled sandwich beam with MR visco-elastomer core

  • Ying, Z.G.;Ni, Y.Q.;Duan, Y.F.
    • Smart Structures and Systems
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    • v.19 no.1
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    • pp.21-31
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    • 2017
  • To control the stochastic vibration of a vibration-sensitive instrument supported on a beam, the beam is designed as a sandwich structure with magneto-rheological visco-elastomer (MRVE) core. The MRVE has dynamic properties such as stiffness and damping adjustable by applied magnetic fields. To achieve better vibration control effectiveness, the optimal bounded parametric control for the MRVE sandwich beam with supported mass under stochastic and deterministic support motion excitations is proposed, and the stochastic and shock vibration suppression capability of the optimally controlled beam with multi-mode coupling is studied. The dynamic behavior of MRVE core is described by the visco-elastic Kelvin-Voigt model with a controllable parameter dependent on applied magnetic fields, and the parameter is considered as an active bounded control. The partial differential equations for horizontal and vertical coupling motions of the sandwich beam are obtained and converted into the multi-mode coupling vibration equations with the bounded nonlinear parametric control according to the Galerkin method. The vibration equations and corresponding performance index construct the optimal bounded parametric control problem. Then the dynamical programming equation for the control problem is derived based on the dynamical programming principle. The optimal bounded parametric control law is obtained by solving the programming equation with the bounded control constraint. The controlled vibration responses of the MRVE sandwich beam under stochastic and shock excitations are obtained by substituting the optimal bounded control into the vibration equations and solving them. The further remarkable vibration suppression capability of the optimal bounded control compared with the passive control and the influence of the control parameters on the stochastic vibration suppression effectiveness are illustrated with numerical results. The proposed optimal bounded parametric control strategy is applicable to smart visco-elastic composite structures under deterministic and stochastic excitations for improving vibration control effectiveness.

Design formulas for vibration control of sagged cables using passive MR dampers

  • Duan, Yuanfeng;Ni, Yi-Qing;Zhang, Hongmei;Spencer, Billie F. Jr.;Ko, Jan-Ming;Dong, Shenghao
    • Smart Structures and Systems
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    • v.23 no.6
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    • pp.537-551
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    • 2019
  • In this paper, a method for analyzing the damping performance of stay cables incorporating magnetorheological (MR) dampers in the passive control mode is developed taking into account the cable sag and inclination, the damper coefficient, stiffness and mass, and the stiffness of damper support. Both numerical and asymptotic solutions are obtained from complex modal analysis. With the asymptotic solution, analytical formulas that evaluate the equivalent damping ratio of the sagged cable-damper system in consideration of all the above parameters are derived. The main thrust of the present study is to develop an general design formula and a universal curve for the optimal design of MR dampers for adjustable passive control of sagged cables. Two sag-affecting coefficients are derived to reflect the effects of cable sag on the maximum attainable damping ratio and the optimal damper coefficient. For the cable configurations commonly used in cable-stayed bridges, the sag-affecting coefficients are directly expressed in terms of the sag-extensibility parameter to facilitate the control design. A case study on adjustable passive vibration control of the longest cable (536 m) on Stonecutters Bridge is carried out to demonstrate the influence of the sag for the damper design, and to figure out the necessity of adjustability of damper coefficients for achieving maximum damping ratio for different vibration modes.