• 한국산학기술학회논문지
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• 제21권11호
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• pp.233-238
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• 2020

최근 우주 항공 분야 발전으로 인해 NBR에 대한 관심이 높아지고 있으나, HNBR의 항공용 윤활유 관련 연구는 많지 않고, 특히 가혹인자들에 대한 가속수명 평가는 그렇게 많이 보고되지 않고 있다. 본 연구에서는 항공분야에 사용되는 HNBR(Hydrogenated Acrylonitrile Butadiene Rubber) 제품의 가속수명을 평가하기 위해 성능평가 인자로 인장강도를 채택하고, 성능 노화특성에 영향을 미치는 가속 스트레스 인자를 온도로 정의했다. 가속 스트레스 인자는 온도(60 ℃, 80 ℃, 100 ℃)로 정하여 시간(0 ~ 720시간)에 따른 인장강도 변화를 측정한 결과값으로 결정했다. 가속 조건은 일정 기간 동안 노화된 시편을 오븐에서 꺼내어 24시간 상온에서 방치한 후, 시험편을 KS M 6518에 명시된 기준에 따라 아령형 3호 시편을 제작하여 가속수명 평가의 한 요소인 인장강도를 측정하였다. 아레니우스 모델을 이용하여 얻어진 활성화 에너지 값은 0.895임을 알 수 있고, 형상모수는 1.152이었으며, 20℃에서 항공용 오일에 침지한 HNBR 시편의 인장강도로부터 얻어진 특성수명은 272,256시간, 평균수명(MTTF)는 258,965시간, B10 수명은 38,624시간이었다.

• 한국산림과학회지
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• 제101권3호
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• pp.365-373
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• 2012

본 연구는 원주시를 대상으로 중해상도 위성영상을 이용하여 산림전용지의 추출 및 정확도 분석을 목적으로 수행하였다. 2000년부터 2008년까지 산림에서 비산림으로 전용된 면적은 467 ha로 연평균 약 52 ha가 전용되었으며, 전용형태는 주거지로의 전용이 약 72% 차지하였으며, 전체발생면적의 약 97%가 2 ha 미만이였다. 또한, 산림전용지는 도로로부터 500 m이내와 산림 비산림 경계로부터 100 m이내 지역에서 약 79%가 발생하였다. 한편, 행정정보상의 산림전용지(GIS전용지)와 위성영상에 의하여 구축된 지수별(NDVI,NBR,NDWI) 산림전용지(RS전용지)와 비교한 결과, 추출정확도는 $3{\times}3$ 필터링을 적용한 NDVI의 평균$({\mu})$-표준편차$({\sigma}){\times}1.5$ 구간에서 일치율 35.47%, K-지수 0.20로 가장 안정적인 정확도를 나타냈다. 정확도 오차의 원인으로는 산림전용지의 토지이용변화와 토지피복변화의 불일치로서, 행정정보상의 산림전용지의 실제 토지피복변화율은 약 32%에 지나지 않았다. 또한, RS전용지에 의하여 산림경영활동지역의 약 7.52%가 산림전용지로 오류 추출되었다. 토지이용 및 토지피복상 변화된 산림전용지(GIS전용지2)를 대상으로 지수별 RS전용지와 정확도를 비교한 결과, $3{\times}3$ 필터링을 적용한 NDVI의 ${\mu}-{\sigma}{\times}2$ 구간에서 일치율 61.23%, K-지수 0.23으로 향상되었다.

• Elastomers and Composites
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• 제19권1호
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• pp.13-31
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• 1984

The purposes of this dissertation are to demonstrate that DSC theromoanaytical methods of vulcanization can provide useful informations on the vulcanization characteristics of industrial formulations and also provides the potential basis for a rapid and complete method of sulfur and vulcanizing accelerator analysis for quality control. The influences of those factors such as heating rate, scan temperature, vucanizing accelerator's type and concentration upon vulcanization exotherm in NR and NBR compounds in the presence of vulcanizing accelerators such as TMTD,MBTS,DPG,TMTM,CBS, and MBT were evaluated by means of DSC. In order to examine the credibility in the DSC method, the same samples which were used for DSC method were studied to compare the DSC results with the ODR (Oscillating Disk Rheometer) data. The results obtained were as follows 1. In the DSC dynamic experiments, the observed enthalpy results from vulcanization depends upon the heating rate; In the range of 2 to $20^{\circ}C/min$ of heating rate, as the heating rate was increased the enthalpy change was also increased. However, over the heating rate of $30^{\circ}C/min$ it was observed that the enthalpy change was decreased as the heating rate was further increased. Without regard to the change of enthalpy, tremendous instantaneous heat evolving was observed in the range of high heating rates. 2. For the samples which are added with various vulcanizing accelerators, the activation energies of vulcanization were as follows; 3. Regarding to the influences of vulcanizining accelerator's types upon the characteristics of vulcanization exotherm, NR and NBR compounds in the presence of thiuramsulphide compounds type accelerators such as TMTD, TMTM, were exhibited sharper and higher vulclanization exotherm than others. From the resuts of DSC thermograms which was distributed in even shape in the broad temperature range, it was clearly shown that the guanidine compounds type accelerator such as DPG acts as a delayed acting accelerator. 4. In the comparison of DSC and ODR results, the dependency of temperature in the cure rate and the observed conversions show good agreements between two results. 5. In the same curatives, by the comparison of glass transition temperatures, it was possible to predict relative values of maximum torques. Consequently, from the present studies, it is shown that the DSC thermoanalytical method can provide an alternate new method for rapid and complete quality control analysis of rubber industry.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.216.2-216.2
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• 2010

본 연구에서는 $H_2+CO_2$(40%) 혼합기체로부터 이산화탄소를 효과적으로 분리/회수 하기 위하여 가스 하이드레이트 형성법을 제안하였다. 하이드레이트의 형성 조건을 보다 완화시켜 주기 위하여 열역학적 촉진제로서 TBAB (Tetra-n-butyl Ammonium Bromide, $(C_4H_9)_4NBr$))와 THF(Tetrahydrofuran)를 각각 첨가하여 열역학적 촉진 현상을 살펴보았다. 다양한 농도의 TBAB(10, 40, 60 wt%)와 THF(1, 5.56, 10 mol%)에 대하여 3상(H - Lw - V) 평형을 측정하였다. 그 결과 40 wt%의 TBAB와 5.56 mol%의 THF의 농도에서 가장 큰 촉진효과를 보였으며 그 이상의 농도에서는 오히려 촉진효과가 줄어드는 것을 확인할 수 있었다. 이러한 결과는 혼합가스 하이드레이트 형성시 양론비 이상의 TBAB와 THF가 첨가될 경우 반응에 참여하지 못한 TBAB와 THF가 가스 하이드레이트 형성을 방해하기 때문이다. 열역학적 촉진제로서 실제공정에 적용할 경우 40 wt%의 TBAB와 5.56 mol%의 THF를 사용하는 것이 가장 효과적일 것으로 사료된다. 본 실험에서 얻어진 결과는 가스 하이드레이트 형성법을 이용한 합성가스 분리 공정 개발에 중요한 기초 자료가 될 것이다.

• Elastomers and Composites
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• 제31권1호
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• pp.33-42
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• 1996

NR, NBR, and CR rubber were prepared by mixing filler in various ratios. Their vulcanization characteristics and thermal properties were studied. Vulcanization characteristics were investigated using cure curve that had been obtained from oscillating disk rheometer study. The Arrhenius law is known to describe the relationship between cure time and temperature of most elastomers. Curing could be done by the addition of sulfur, peroxides, and proper acceleratores. The optimum cure time that affects desirable values of modulus and tensile strength of the vulcanizate is taken as t90 as measured by a rheometer. Rubbers were cured in the rheometer at temperatures ranging from $130^{\circ}C\;to\;180^{\circ}C$ in order to check the validity of the curing system used. A linear relationship between ln(ts2) and ln(t90) was found for all elastomers. The term sensitivity has been used to describe the relationship between a change of ts2 to the corresponding change of t90 due to an increment of temperature. This is related to the formula of the compound.

• 한국임상수의학회지
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• 제22권2호
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• pp.100-107
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• 2005

This study was carried out to investigate the physical and chemical properties of teat cup liners. The hardness of the liners was $50\~67$, and their fatigue to failure 38-1,185 cycles. The elongation and tensile strength of these liners were about $134 kgf/cm^2\;and\;473\%$, respectively. The infrared spectrum and the gas chromatogram revealed that the liner A was consisted of NR, SBR, and BR, with a composition ratio of 60:20:20 (part per hundred rubber). The raw rubber materials used for liners B to G, on the other hand, were NBR only. However, the liner H was made of silicon rubber. The thermogravimetric analysis showed that the liners tested in this study contained raw rubber material, carbon black, organic compounds and metallic compounds.

• 한국신뢰성학회지:신뢰성응용연구
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• 제6권2호
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• pp.135-150
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• 2006

Rubber material properties and lifetime evaluation are very important in design procedure to assure the safety and reliability of the rubber components. This paper discusses the failure mechanism and material tests were carried out to predict the useful lifetime of NBR and EPDM for compression motor, which is used in refrigerator component. The heat-aging process leads not only to mechanical properties change but also to chemical structure change so called degradation. In order to investigate the aging effects on the material properties, the accelerated test were carried out. The stress-strain curves were plotted from the results of the tensile test for virgin and heat-aged rubber specimens. The rubber specimens were heat-aged in an oven at the temperature ranging from $70^{\circ}C\;to\;100^{\circ}C$ for a period ranging from 1 to 180 days. Compression set results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the compression set test, several useful lifetime prediction equations for rubber material were proposed.

• Journal of Information Display
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• 제4권1호
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• pp.17-23
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• 2003

A thermoset type anisotropic conductive adhesive film (ACAF) comprising epoxy resin and natural butyl rubber (NBR) as the binder, micro-encapsulated imidazole as the curing agent, and Ni/Au coated polymer bead as a conductive particle has been studied. These films have been prepared to respond to requirements such as improved contact resistance, current status less of than 60 ${\mu}m$ and reliability. These films can also be used for connection between the ITO glass for LCD panel and the flexible circuit board. The curing conditions for the connection were 40, 20 and 15 seconds at 150, 170 and 190 $^{\circ}C$, respectively. The initial contact resistance and adhesion strength were 0.5 ${\Omega}/square$ and 0.4 kg/cm under the condition of 30 kgf/$^{cm}^2}$, respectively. After completing one thousand thermal shock cycling tests between -15 $^{\circ}C$ and 100 $^{\circ}C$, the contact resistance was maintained below 0.7 ${\Omega}/square$. Durability against high temperature (80$^{\circ}C$) and high humidity (85 % RH) was also tested to confirm long-term stability (1000 hrs) of the conduction.

• Elastomers and Composites
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• 제15권3호
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• pp.147-154
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• 1980

The cellular rubber products for industrial purpose have been applied in many fields such as auto-motive parts, ship-building, machinery, sports goods, diving suit or interior housings etc. The purpose of this dissertation is to study the physical properties of celluar rubber products particulary for those elastomers such as EPDM, CR and NBR with heat resistance property, weather proofness, and oil resistance characteristics respectively, aiming at improving their quality, and renovating the manufacturing know-how which is beyond our technical power at the present time in Korea. In order to meet this requirement an ideal recipe is being shown for the three elastomers, and also a practical recipe which is easily available in terms of compounding ingredients in domestic market has set up as shown in Table 1. for the investigation of vulcanization characteristics by means of Rheometer. The optimum Mooney viscosity of compounded rubber was found to be approximately $ML_{1+4}(100^{\circ}C)$ $30\sim45$. Excess mustication makes a dispersion of ingredients worse, consequently it causes deformation of shapes and heterogenous cell distribution. In other words the articles are rejected because of its insufficient workmanship. The results of physical properties of the products are indicated in Table 3. It has shown that the quality meet requirement when tested in accordance with ASTM D572, 573 and D 395. The test results o CR/IR blends in terms of hardness, volume change by blowing, tensile strength and elongation have been shown.

• Nuclear Engineering and Technology
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• 제51권5호
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• pp.1428-1435
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• 2019

The total ionizing dose (TID) and non ionizing energy loss (NIEL) effects of 100 MeV phosphorous ($P^{7+}$) and 80 MeV nitrogen ($N^{6+}$) ions on 200 GHz silicon-germanium heterojunction bipolar transistors (SiGe HBTs) were examined in the total dose range from 1 to 100 Mrad(Si). The in-situ I-V characteristics like Gummel characteristics, excess base current (${\Delta}I_B$), net oxide trapped charge ($N_{OX}$), current gain ($h_{FE}$), avalanche multiplication (M-1), neutral base recombination (NBR) and output characteristics ($I_C-V_{CE}$) were analysed before and after irradiation. The significant degradation in device parameters was observed after $100MeV\;P^{7+}$ and $80MeV\;N^{6+}$ ion irradiation. The $100MeV\;P^{7+}$ ions create more damage in the SiGe HBT structure and in turn degrade the electrical characteristics of SiGe HBTs more when compared to $80MeV\;N^{6+}$. The SiGe HBTs irradiated up to 100 Mrad of total dose were annealed from $50^{\circ}C$ to $400^{\circ}C$ in different steps for 30 min duration in order to study the recovery of electrical characteristics. The recovery factors (RFs) are employed to analyse the contribution of room temperature and isochronal annealing in total recovery.