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On the Numbers of Palindromes

  • Bang, Sejeong;Feng, Yan-Quan;Lee, Jaeun
    • Kyungpook Mathematical Journal
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    • v.56 no.2
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    • pp.349-355
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    • 2016
  • For any integer $n{\geq}2$, each palindrome of n induces a circulant graph of order n. It is known that for each integer $n{\geq}2$, there is a one-to-one correspondence between the set of (resp. aperiodic) palindromes of n and the set of (resp. connected) circulant graphs of order n (cf. [2]). This bijection gives a one-to-one correspondence of the palindromes ${\sigma}$ with $gcd({\sigma})=1$ to the connected circulant graphs. It was also shown that the number of palindromes ${\sigma}$ of n with $gcd({\sigma})=1$ is the same number of aperiodic palindromes of n. Let $a_n$ (resp. $b_n$) be the number of aperiodic palindromes ${\sigma}$ of n with $gcd({\sigma})=1$ (resp. $gcd({\sigma}){\neq}1$). Let $c_n$ (resp. $d_n$) be the number of periodic palindromes ${\sigma}$ of n with $gcd({\sigma})=1$ (resp. $gcd({\sigma}){\neq}1$). In this paper, we calculate the numbers $a_n$, $b_n$, $c_n$, $d_n$ in two ways. In Theorem 2.3, we $n_d$ recurrence relations for $a_n$, $b_n$, $c_n$, $d_n$ in terms of $a_d$ for $d{\mid}n$ and $d{\neq}n$. Afterwards, we nd formulae for $a_n$, $b_n$, $c_n$, $d_n$ explicitly in Theorem 2.5.

On-the-go Nitrogen Sensing and Fertilizer Control for Site-specific Crop Management

  • Kim, Y.;Reid, J.F.;Han, S.
    • Agricultural and Biosystems Engineering
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    • v.7 no.1
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    • pp.18-26
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    • 2006
  • In-field site-specific nitrogen (N) management increases crop yield, reduces N application to minimize the risk of nitrate contamination of ground water, and thus reduces farming cost. Real-time N sensing and fertilization is required for efficient N management. An 'on-the-go' site-specific N management system was developed and evaluated for the supplemental N application to com (Zea mays L.). This real-time N sensing and fertilization system monitored and assessed N fertilization needs using a vision-based spectral sensor and controlled the appropriate variable N rate according to N deficiency level estimated from spectral signature of crop canopies. Sensor inputs included ambient illumination, camera parameters, and image histogram of three spectral regions (red, green, and near-infrared). The real-time sensor-based supplemental N treatment improved crop N status and increased yield over most plots. The largest yield increase was achieved in plots with low initial N treatment combined with supplemental variable-rate application. Yield data for plots where N was applied the latest in the season resulted in a reduced impact on supplemental N. For plots with no supplemental N application, yield increased gradually with initial N treatment, but any N application more than 101 kg/ha had minimal impact on yield.

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Wear Characteristics of Coated $Si_3N_4$-TiC Ceramic Tool (Coated $Si_3N_4$-TiC Ceramic 공구의 마모 특성)

  • 김동원;권오관;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.44-51
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    • 1988
  • Titanium carbide(TiC), Titanium nitride(TiN), and Titanium carbonnitride(Ti(C,N)) films were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$, $TiCl_4-N_2-H_2$, and $TiCl_4-CH_4-N_2-H_2$ gas mixtures, respectively. The experimental results indicate that TiC coatings compared with TiN coatings on $Si_3N_4$ -TiC ceramic have an improved microstructural property, good thermal shock resistance, and good interfacial bonding. However TiN coatings compared with TiC coatings have a low friction coefficient with steel and good chemical stability. It is found by cutting test that coated insert compared with $Si_3N_4$-TiC ceramic have a superior flank and crater wear resistance. And multilayer coating compared with monolayer coating shows a improved wear resistance.

A Facile Synthesis of N,N'-Disubstituted Ureas from Amide and Amine by Using N-Bromophthalimide (NBP) and Silvercetate in One Pot

  • Park, Min-Soo;Choi, Chang-Uk
    • Archives of Pharmacal Research
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    • v.17 no.1
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    • pp.39-41
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    • 1994
  • Various N,N'-disubstituted ureas 5 were easily prepared from the corresponding primary amide 1 by tratment with N-Bromophthalimide $(NBP)-AgOAc-RNH$_{2}$ 4 in dry N,N-dimrthylformamide (DMF). This reaction envolved the intemediate formation of isocyanate 3 from amide 1 via Hofmann rearrangement by treatment with AgOAc and NBP and nucleophilic addition of amine 4 to this isocyante 3. This method is simple enough to be applied to the synthesis of various N,N'-disubstututed ureas scale conviently.

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A Study on the Friction and Wear Characteristics of C-N Coated Spur Gear (C-N코팅 스퍼기어의 마찰 . 마모 특성에 관한 연구)

  • 노룡;류성기
    • Tribology and Lubricants
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    • v.20 no.5
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    • pp.272-277
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    • 2004
  • This study deals with the friction and wear characteristics of C-N coated spur gear. The PSII apparatus was built and a SCM415 test piece and test gear with steel substrate was treated with carbon nitrogen by this apparatus. The composition and structure of the surface layer were analyzed and compared with that of PVD coated TiN layer. It was found that both of friction coefficient of C-N coating and TiN coating decreased with increasing load, however, C-N coating showed relatively lower friction coefficient than that of TiN coating. We was investigated the effect of C-N coating on hardness, friction and wear. The TiN coated gear showed a more serious friction phenomena than that of C-N coated gear. It was considered that coating of TiN, which was conducted at a vacuum chamber at about 500$^{\circ}C$, results in a tempering of base material that causes microstructural change, which in turn resulted in decreasing of hardness. The C-N coated gear and pinion had higher wear resistance that of TiN coated gear and pinion. C-N coating significantly improved the friction and wear resistance of the gear.

A Study on the Friction and Wear Characteristics of C-N Coated Spur Gear (C-N 코팅 스퍼기어의 마찰${\cdot}$마모 특성에 관한 연구)

  • Lu Long;Lyu Sung-ki
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.41-46
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    • 2004
  • This study deals with the friction and wear characteristics of C-N coated spur gear. The PSII apparatus was built and a SCM415 test piece and test gear with steel substrate was treated with carbon nitrogen by this apparatus. The composition and structure of the surface layer were analyzed and compared with that of PVD coated TiN layer. It was found that both of friction coefficients of C-N coating and TiN coaling decreased with increasing load, however, C-N coating showed relatively lower friction coefficient than that of TiN coating. We was investigated the effect of C-N coating on hardness, friction and wear. The TiN coated gear showed more serious friction phenomena than that of C-N coated gear. It was considered that coating of TiN, which was conducted at a vacuum chamber at about $500^{\circ}C$ results in a tempering of base material that causes microstructure change, which in turn resulted in decreasing of hardness. The C-N coated gear and pinion had higher wear resistance that of TiN coated gear and pinion. C-N coating significantly improved the friction and wear resistance of the gear.

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The Study of Cyclophosphamide Metabolite $^{15}N$ and $^{17}O$ Phosphoramide Mustards (항암제인 Cyclophosphamide의 중간체인 $^{15}N$$^{17}O$-phosphoramide Mustards의 합성)

  • Koo, Kyo-Im;Ryem, Kon
    • YAKHAK HOEJI
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    • v.38 no.4
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    • pp.455-461
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    • 1994
  • Each nitrogen and oxygen site isotope enriched the cyclophosphamide metabolite phosphoramide mustard was synthesized. Reaction of N,N-bis(2-chloroethyl)phosphoramidic dichloride$[Cl_2P(O)N(CH_2CH_2Cl)_2]$ with benzyl alcohol and ammonia gave N,N-bis(2-chloroethyl)phosphorodiamidic acid phenylmethyl ester $[BzO(H_2N)P(O)N(CH_2CH_2Cl)_2]$. Catalytic hydrogenation of this benzyl ester followed by the addition of cyclohexylamine provided PM. Incorporation of $^{15}NH_3$ into this general scheme gave PM with a $^{15}NH_2$ moiety. Glycine-$^{15}N$ was converted to bis(2-chloroethyl)amine-$^{15}N$ hydrochloride which, in turn, provided for N,N-bis(2-chloroethyl)phosphorodiamidic-$^{15}N$ dichloride. Use of this compound in the general synthetic pathway yielded PM CHA with $^{15}N$ in the mustard moiety. $^{17}O$-Enriched PM was generated through the use of benzyl alcohol-$^{17}O$. To obtain the alcohol, labelled benzaldehyde was made by exchange with $^{17}OH_2$ and was then reduced with sodium borohydride.

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MO Studies of Configuration and Conformation (Ⅰ). Configuration and Conformation of Methyl Benzamidoxime (配置와 形態에 關한 分子軌道論的 硏究 (第1報). Methyl Benzamidoxime의 配置와 形態)

  • Shi Choon Kim;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.20 no.2
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    • pp.111-117
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    • 1976
  • The configuration and conformation of methyl benzamidoxime have been studied from extended Huckel molecular orbital calculations.The results show that the E-configuration of the C=N double bond is favored compared with that of Z-configuration with the sp-conformation of the C-N bond rotamers, but Z-configuration is more stable with the ap-conformation of the C-N bond rotamers. The conformation of C-N bond with equal configuration of C=N bond and equal conformation of N-O bond, sp-form is favored, but the conformation of N-O bond with equal configuration and equal conformation of C-N bond ap-form is more stable. The major part of the stabilization energies can be accounted for by the electrostatic energies between the atoms involved.

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Effect of N2 flow rate on growth and photoluminescence properties of GaN nanorods grown by using molecular beam epitaxy (분자선 에피택시를 이용하여 GaN 나노로드를 성장시 구조 및 광학적인 특성에 미치는 N2의 양의 효과)

  • Park, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.16 no.4
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    • pp.298-304
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    • 2007
  • We have studied the effect of $N_2$ flow rate on the structural and optical properties of GaN nanorods grown on (111) Si substrates by radio-frequency plasma-assisted molecular-beam epitaxy. The hexagonal shape nanorods with lateral diameters from 80 to 190 nm with increasing $N_2$ flow rate from 1.1 to 2.0 sccm are obtained. However, the ratio of length (thickness) and compact region increases with increasing $N_2$ flow rate up to 1.7 sccm and then saturate. From the photoluminescence, free exciton transition is clearly observed for GaN nanorods with low $N_2$ flow rate. And the PL peak energies are blue-shifted with decreasing diameter of the GaN nanorods due to size effect. Temperature-dependent photoluminescence spectra for the nanorods with $N_2$ flow rate of 1.7 sccm show an abnormal behavior like "S-shape" with increasing temperature.

Nitrogen Management with Split Application of Urea for Direct-Seeding Rice in Wet Paddy

  • Lee, Ho-Jin;Seo, Jun-Han;Lee, Jung-Sam;Jung, Yong-Sang;Fred E. Below
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.43 no.1
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    • pp.49-53
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    • 1998
  • Direct-seeding has major advantages such as labor and cost saving by eliminating preparation of seed bed and transplanting. But, it required increased input of fertilizers and pesticides because of the extended paddy period. Direct seeding in wet paddy (DSWP) gives faster growth and more uniform seedling emergence than direct-seeding in dry paddy. This research had an objective to develop an efficient N management practices for DSWP with split application of N fertilizer. A paddy field experiment was conducted to evaluate effects of starter N and N-topdressing which was delayed N application until 5-leaf stage, with comparison to transplanting (TP). Total amount of N application were two levels; 110kg and 77kg/ha. The N applications were split four times during rice growth stages; starter, topdressing at 5-leaf stage, top dressing at tillering stage, and topdressing at panicle initiation stage. DSWP had more tillers/$m^2$ than TP, but with the delayed heading. The DSWP plots which received N-topdressing at 5-leaf stage without starter N had higher leaf area index (LAI) and leaf greenness than the TP plot. Also, these DSWP plots had high leaf-N concentration at the heading stage, as calculated from leaf chlorophyll meter readings. Rice yield in DSWP with N-topdressing at 5-leaf stage was significantly higher than that in TP and in DSWP with starter N. Energy and N use efficiency were improved in DSWP with N-topdressing at 5-leaf stage. But, there were no significant differences in grain yield between the two levels of total amounts of N applications, 77kg and 110kg/ha. We concluded that starter N could not be used effectively by rice seedlings, but topdressing N at 5-leaf stage was an efficient N management for rice growth and yield in DSWP system.

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