• Title/Summary/Keyword: N-values

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Correlation Analysis of Water Quality According to Land Use Types of Reservoir Watershed (유역 토지이용과 저수지 수질의 상관관계 분석)

  • Youn, Dong-Koun;Chung, Sang-Ok
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.614-619
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    • 2005
  • The object of this study was to presented regression equations for obtaining simply and quickly values of water quality items, BOD, COD, T-N, and T-P. Regression equations obtained to analyze relationships for water quality items to land use types in agricultural reservoir watersheds. In order to derive regression equations, a multiple linear regression analysis was used in this studying reservoirs. In this regression analysis, a independent values used land used types and dependent values used BOD, COD, T-N, T-P values in water quality items. The results showed that numbers of regression equation ranging above 0.90 in a multiple correlation coefficient (MCC) was not found, ranging from 0.70 to 0.90 in the MCC was 6, ranging from 0.40 to 0.70 in the MCC was 20, and ranging from 0.20 to 0.40 in the MCC was 4. The results of this study can be used as a basic information for evaluating simply and quickly water quality for proposing and designing steps in water quality policy.

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Solvolysis of Benzoyl Cyanide (시안화 벤조일의 가용매분해반응)

  • Jeong Wha Kim;Ikchoon Lee;Se Chul Sohn;Tae Sup Uhm
    • Journal of the Korean Chemical Society
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    • v.27 no.2
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    • pp.95-101
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    • 1983
  • The pseudo-first order rate constants have been obtained for the solvolysis of benzoyl cyanide in various aqueous solvent mixtures and ethanol-trifluoroethanol mixtures at 1, 5, 10, 15 and $20^{\circ}C$. Values of n in the Kivinen polt, m values of Grunwald-Winstein polt, $\beta$ values of Leffler relationship and values of m and l in the extended Grunwald-Winstein polt have been calculated and studied the transition state variation caused by solvent changes using the More O'Ferrall polt and quantum mechanical approach. It has been shown that the reaction proceed via the associative $S_N2$ mechanism, using the transition state parameters and quantum mechanical model approach.

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The Adhesion of Abrasive Particle during Poly-Si, TEOS and SiN CMP (Poly-Si, TEOS, SiN 막질의 CMP 공정 중의 연마입자 오염 특성 평가.)

  • Kim, Jin-Young;Hong, Yi-Kwan;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.561-562
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    • 2006
  • The purpose of this study was to investigate the root cause of adhesion of silica and ceria particles during Poly-Si, TEOS, and SiN CMP process, respectively. The zeta-potentials of abrasive particles and wafers were observed negative surface charges in the alkaline solutions. SAC and STI patterned wafers have intermediate values of their composition surface's zeta potentials. The theoretical interaction force and adhesion force of silica and ceria particle were calculated in solution with acidic, neutral and alkaline pH. A stronger attractive force was calculated for silica and ceria particles on wafers in acidic solutions than in alkaline solutions. The theoretical interaction forces of the SAC and STI patterned wafers have intermediate values of their constitution wafer's values. The adhesion forces is observed lower values in alkaline solutions than in acidic solutions. And the ceria particle has lower adhesion than that of the silica particle.

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Characteristics of Red Pepper (Capsicum Annuum L.) Powder Using $N_2-Circulated$ Low Temperature Drying Method (저온질소순환 건조방법에 의해 제조된 고춧가루의 품질 특성)

  • Kim, Chung-Hee;Ryu, Seung-Hee;Lee, Min-Ja;Baek, Jong-Won;Hwang, Hong-Cheol;Moon, Gap-Soon
    • Korean Journal of Food Science and Technology
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    • v.36 no.1
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    • pp.25-31
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    • 2004
  • Characteristics of good-quality red pepper powder produced using $N_{2}$-circulated low-temperature drying method were compared with those made through conventional sun and hot-air drying methods. Kimchi and kochujang were prepared with different types of red pepper powder, and their physicochemical and sensory properties were compared. Results revealed Hunter L (lightness), a (redness), and b (yellowness) values of $N_{2}$-circulated low temperature-dried red pepper were highest. Absorbance of crude capsanthin in hot air-dried red pepper powder ($0.584{\pm}0.001$) was significantly lower than sun-dried ($0.848{\pm}0.001$) and $N_{2}$-circulated low temperature-dried products ($0.832{\pm}0.002$. Use of $N_{2}$-circulated low-temperature drying method resulted in the highest amounts at reducing sugar and total vitamin C. Capsaicin content of $N_{2}$-circulated low temperature-dried products were higher than hot air-dried ones. The aL values of kochujaug made with sun-and low temperature-dried red peppers were higher than that of kochujang made with hot-dried red peppers. Physicochemical and sensory evaluation results showed red pepper powders made using $N_{2}$-circulated low-temperature drying method have the best quality among all samples tested.

The effect of 4,4'-bis(N,N-diethylamino)benzophenone on the degree of conversion in liquid photopolymer for dental 3D printing

  • Lee, Du-Hyeong;Mai, Hang Nga;Yang, Jin-Chul;Kwon, Tae-Yub
    • The Journal of Advanced Prosthodontics
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    • v.7 no.5
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    • pp.386-391
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    • 2015
  • PURPOSE. The purpose of this preliminary study was to investigate the effects of adding 4,4'-bis(N,N-diethylamino) benzophenone (DEABP) as a co-initiator to a binary photoinitiating system (camphorquinone-amine) to analyze on the degree of conversion (DC) of a light-cured resin for dental 3D printing. MATERIALS AND METHODS. Cylindrical specimens (N=60, n=30 per group, ${\phi}5mm{\times}1mm$) were fabricated using bisphenol A glycerolate dimethacrylate (BisGMA) both with and without DEABP. The freshly mixed resins were exposed to light in a custom-made closed chamber with nine light-emitting diode lamps (wavelength: 405 nm; power: $840mW/cm^2$) for polymerization at each incidence of light-irradiation at 10, 30, 60, 180, and 300 seconds, while five specimens at a time were evaluated at each given irradiation point. Fourier-transform infrared (FTIR) spectroscopy was used to measure the DC values of the resins. Two-way analysis of variance and the Duncan post hoc test were used to analyze statistically significant differences between the groups and given times (${\alpha}$=.05). RESULTS. In the DEABP-containing resin, the DC values were significantly higher at all points in time (P<.001), and also the initial polymerization velocity was faster than in the DEABP-free resin. CONCLUSION. The addition of DEABP significantly enhanced the DC values and, thus, could potentially become an efficient photoinitiator when combined with a camphorquinone-amine system and may be utilized as a more advanced photopolymerization system for dental 3D printing.

Can We Rely on GLOBOCAN and GBD Cancer Estimates? Case Study of Lung Cancer Incidence and Mortality Rates and Trends in Iran

  • Vardanjani, Hossein Molavi;Heidari, Mohammad;Hadipour, Maryam
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.7
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    • pp.3265-3269
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    • 2016
  • Background: Around half of input data in the global burden of disease cancer collaboration (GBD-CC) and GLOBOCAN projects come from low quality sources, mainly from developing countries. This may lead to loss of precision in estimates. Our question was: Are the absolute values and trends of the GBD-CC and GLOBOCAN estimates for lung cancer (LC) in Iran consistent with available statistics?. Materials and Methods: Incidence and mortality statistics were extracted from national reports (N.IRs & N.MRs) and GBD-CC (GBD-incidence & mortality) and GLOBOCAN databases for 1990-2013 where available. Trends were analyzed and absolute values and annual percentage changes (APCs) were estimated and compared. Incompleteness of case ascertainment at the Iranian national cancer registry and Iranian national civil registration was assessed for better understanding. Results: Trends of N.IRs were significantly rising for males (APC: 19.4; 95% CI: 12.5-26.7) and females (23.2; 16.0-30.8). Trends of GBD-incidence were stable for males (-0.2; -1.5-1.1) and females (-1.0; -2.3-0.4). Absolute N.IRs were less than GBD-incidence steadily except for 2009. Trend of N.MRs was increasing up to 2004, but stable thereafter. Trends of GBD-mortality were also stable. Absolute N.MRs were less than GBD-mortality for years up to 2003 and more than GBD-mortality since 2005. The estimates of GLOBOCAN were more than N.IRs and N.MRs. Conclusions: The GBD-CC and GLOBOCAN values for LC in Iran are underestimates. Generation of data quality indices to present along with country specific estimates is highly recommended.

The Study of Rates of Substitution Reaction [Pd(ONN)Cl] + Y$^-\;{\rightleftharpoons}$ [Pd(ONN)Y] + Cl$^-$ (Y = SCN$^-$, CN$^-$, N$_3^-$, Imidazole, Pyridine) ([Pd(ONN)Cl] 착물의 SCN$^-$, CN$^-$, N$_3^-$, Imidazole, Pyridine에 대한 치환반응 속도연구 (제 1 보))

  • Oh Sang-Oh;Yeo, Hwan Jin;Cho Iee Yeung
    • Journal of the Korean Chemical Society
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    • v.35 no.4
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    • pp.362-367
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    • 1991
  • Rates of nucleophilic substitution reaction ([Pd (ONN) Cl] + Y$^-\;{\rightleftharpoons}$ [Pd (ONN)Y] + Cl$^-$ ; Y = SCN$^-$, CN$^-$, N$_3^-$, imidazole, pyridine) have been measured in methanol by spectrophotometric method at various temperatures. A set of nucleophilic reactivity constants, n$_{Pd}^{\circ}$ has been calculated. These values show an order of nucleophilicity CN$^-$ > SCN$^-$ > N$_3^-$ > Imidazole > Pyridine. The enthalpy of activation are small positive values and the entropy of activation are large negative values. From these results, it can be inferred that the nucleophilic substitution reaction proceeds through an associative (A) mechanism.

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Contrasting Sources of Plant Wax n-alkanes and n-alkanoic Acids in Gulf of Mexico Sediments (ODP 625B) (멕시코만 코어 퇴적물(ODP 625B)의 식물왁스 탄화수소(n-alkanes)와 지방산(n-alkanoic acids)의 생성기원 비교 연구)

  • Suh, Yeon Jee
    • Ocean and Polar Research
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    • v.41 no.2
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    • pp.89-97
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    • 2019
  • Long chain plant waxes (n-alkanes, n-alkanoic acids, and n-alcohols) and their carbon isotopic compositions (${\delta}^{13}C$) in geologic archives are valuable tools for paleovegetation reconstruction. However, the sensitivity of different plant wax constituents to vegetation shift is not well understood. This study explores controls on the variation in ${\delta}^{13}C$ values of long-chain n-alkanes ($C_{27}$ to $C_{33}$) and n-alkanoic acids ($C_{26}-C_{30}$) in the Gulf of Mexico core sediments (ODP 625B) near the Mississippi River delta. n-Alkanoic acids' ${\delta}^{13}C$ values were higher than those of n-alkanes by 1-2‰ on average and such a pattern is the opposite from their isotope fractionation observed in living plants: 1-2‰ smaller in n-alkanes than n-alkanoic acids. We attribute this offset to contributions from aquatic plants or microbes that produce high concentrations of $^{13}C-enriched$ long-chain n-alkanoic acids. The sensitivity of n-alkanes and n-alkanoic acids to vegetation and climate varied among chain lengths. The $n-C_{33}$ alkanes were most sensitive to $C_4$ grassland expansion among n-alkane homologues, while no specific trend was observed in n-alkanoic acids. This is due to the similarity in n-alkanoic acid concentrations between $C_3$ and $C_4$ plants by homologues and low terrestrial plant-derived n-alkanoic acid contributions to the sediments. The results of this study suggest that long chain n-alkanoic acids' ${\delta}^{13}C$ values in sediments may be influenced by contributions from different sources such as aquatic plants or microbial inputs and therefore interpretations regarding this matter should be cautiously formulated. We suggest that there is a need for further studies on characterizing long-chain n-alkanoic acids ($C_{26}-C_{34}$) in aquatic plants and microbes from various climates and environments in order to investigate their production and integration into sedimentary archives.

Electron Energy Distribution Function in SF6-He Gas by Simulation (시뮬레이션에 의한 SF6-He 혼합기체에서 전자에너지 분포함수)

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.1
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    • pp.19-23
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    • 2014
  • This paper describes the electron transport characteristics in $SF_6$-He gas calculated E/N values 0.1~700[Td] by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters obtained by TOF method. This study gained the values of the electron swarm parameters such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients for $SF_6$-He gas at a range of E/N. A set of electron collision cross section has been assembled and used in Monte Carlo simulation to predict values of swarm parameters. The result of Boltzmann equation and Monte Carlo Simulation has been compared with experimental data by Ohmori, Lucas and Carter. The swarm parameter from the swarm study are expected to sever as a critical test of current theories of low energy scattering by atoms and molecules.

The Correlation Study on the Desorption Enthalpy Changes of Sun- Cured Tobacco (향끽미종 잎담배의 탈착 엔탈피 변화에 관한 상관성 연구)

  • 최승찬
    • Journal of the Korean Society of Tobacco Science
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    • v.6 no.1
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    • pp.33-37
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    • 1984
  • The net enthalpy changes for the water desorption of sun-cured tobacco have been studied. In order to compare the values of net enthalpy changes for the samples at the same moisture contents, correlation analyses have been performed. The results are summarizing as followings : 1 . As temperature and water vapor pressure increased, equlibrium moisture content were approaching to the saturated vapor pressure of water. 2. The values of 1nP against the reciprocal of absolute temperature were linear for the water desorption of samples. 3. Multiple regression was analyzed to calculate the values of 1nP at the same moisture content. The significance of $x^2$-test for the multiple regression was 0.5%. 4. The values of net enthalpy changes for Basma were greater than those of Sohyang at the same moisture content.

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