• Elastomers and Composites
• /
• v.34 no.2
• /
• pp.156-176
• /
• 1999

Rubber chemicals such as accelerators, antidegradants, vulcanizing agents, processing agents and retarders are very important to the production and protection of tires and rubber goods. The use of accelerators and antidegradants are evaluated in various tire components. This paper will focus on how to vulcanize tires economically and maintain the physical properties of each tire component without severe degradation due to oxygen, heat and ozone. Also, new non-nitrosoamine accelerators and non-staining antiozonants will be discussed. Lastly, the future requirements of antidegradants and accelerators in the tire industry will be reviewed. Tires have been vulcanized with Sulfenamides as primary accelerators and either Guamdine's or Thiurams as secondary accelerators to achieve proper properties at service conditions. However, interior components such as the carcass can be vulcanized with Thiazoles as a primary accelerator to cure faster than the external components. Using the combination of Sulfenamide with secondary accelerators in a tire tread compound and the combination of a Thiazole and Guanidine in a carcass compound will be presented with performance data. Uniroyal Chemical and another Rubber Chemical Manufacturer have developed, "Tetrabenzyl Thiuram Disulfide," (TBzTD) as a non-Nitrosoamine accelerator, which could replace Nitrosoamine generating Thiurams. This new accelerator has been evaluated in a tread compound as a secondary accelerator. Also, Flexsys has developed N-t-butyl-2-benzothiazole Sulfenamide (TBSI) as a non-Nitrosoamine accelerator which could replace 2-(Morpholinothio) -benzothiazole (MBS), a scorch delayed Sulfendamide accelerator. TBSI has been evaluated in a Natural Rubber (NR) belt skim compound vs. MBS. An optimum low rolling resistant cure system has been developed in a NR tread with Dithiomorpholine (DTDM). Also, future requirements for developing accelerators will be discussed such as the replacement of DTDM and other stable crosslink systems. Antidegradants are divided into two different types for use in tire compounds. Internal tire compounds such as apex, carcass, liner, wire breaker, cushion, base tread and bead compounds are protected by antioxidants against degradation from oxygen and heat due to mechanical shear. The external components such as sidewall, chafer and cap tread com-pounds are protected from ozone by antiozonants and waxes. Various kinds of staining and non-staining antioxidants have been evaluated in a tire carcass compound. Also, various para-phenylene diamine antiozonants have been evaluated in a tire sidewall compound to achieve the improved lifetime of the tire. New non-staining antiozonants such as 2, 4, 6-tris-(N-1, 4-dimethylpentyl-p-phenylene diamine) 1, 3, 5 Trizine (D-37) and un-saturated Acetal (AFS) will be discussed in the tire sidewall to achieve better appearance. The future requirements of antidegradants will be presented to improve tire performance such as durability, better appearance and longer lasting tires.

• Proceedings of the Korean Society of Fisheries Technology Conference
• /
• 2002.10a
• /
• pp.107-108
• /
• 2002

일상생활에서 인간은 수많은 물리, 화학적 발암 원에 노출되어 살아가고 있으며 역학적으로 관찰해 보면 모든 암의 약 90％가 환경적 요인에 의하여 발생한다. 식품 중에도 여러 종류의 돌연변이원성 물질과 발암성 물질이 자연적으로 존재하고 있어 그 중 소량은 일상의 보통 식이를 통하여 섭취된다. 특히 단백질이나 아미노산이 풍부한 식품인 고기, 생선의 조리과정에 강력한 돌연변이원성 물질과 발암성 물질로 알려진 N-nitrosoamine(NA)이나 heterocyclic amine(HCA)들이 형성되며 다양한 종류가 분리, 동정 되어왔다. (중략)

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.27 no.5
• /
• pp.1015-1018
• /
• 1998

Capsaicin(8-methyl-N-vanillyl-6-nonenamide: CAP) known well as a major compound of not taste in hot pepper, was investigated for the inhibition effect on in vitro nitrosation. CAP(100$\mu$mol) inhibited the formation of N-nitrosoproline(NPRO) and N-nitrosothioproline(NTPRO) by 56% and 26%, respectively. Vanillyl alcohol inhibited the nitrosation of proline by a concentration-dependent manner, and vanillic acid and vanillin were less effective in blocking the nitrosation of proline compared to CAP and anillyl alcohol. The inhibitory effect of NPRO formation by CAP was evaluated to similar with alpha-tocopherol, and vanillyl alcohol was more effective than alpha-tocopherol in blocking the nitrosation of proline. Our results suggested that CAP and its metabolites such as vanillyl alcohol could inhibit endogenous nitrosation in hydrophobic biological environment.

• Journal of environmental and Sanitary engineering
• /
• v.3 no.1 s.4
• /
• pp.9-18
• /
• 1988

This investigation was carried out to find out the biological contamination, nitrogen compounds, physical and chemical test in fermented sea fishes. 60 species sample were collected from farm village, fishing village and free markets, its hygienical test period is taken about two years. The examined results obtained are as in bollow. 1. $hNO_3,\;HNO_2,\;NH_3-N$ was detected whole samples. 2. Some fermented sea fishes was showed under the exhortation quality. 3. Nitrogen compound really produce N-Nitrosoamine. 4. The amine compounds are caused of cancer and malignant disease. 5. All container, storaged method, processing method and delivery method are must be improve. 6. It is neccessary to do instruction for fermented sea fishes really meaning and attain to a fixed standardization.

• Journal of Mushroom
• /
• v.11 no.4
• /
• pp.261-268
• /
• 2013

This study was conducted to investigate the physiological activities and nutrition contents of Gonji No.10 and Solhyang, the strains of Neolentinus lepideus. In nutritional contents of two strains of N. lepideus, the content of free sugars and sugar alcohols and total polyphenol were more in Gonji No.10 than Solhyang. The total contents of amino acids and ${\beta}$-glucan in Solhyang are more than those in Gonji No.10. Solhyang also showed higher DPPH radical scavenging activity than Gonji No.10. In particular, hot water extract of Solhyang has higher inhibitory activity of ${\alpha}$-amylase and ${\alpha}$-amyloglucosidase while Gonji No.10 has higher anti-inflammatiory effect than Solhyang. But, they have similar effects on nitrite scavenging activity.