• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.83-84
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• 2002

For estimation of chain-matching phenomena between normal paraffin as a solvent and straight-chain fatty acid as an additive, the density measurement of n-dodecane, n-tetradecane and n-hexadecane were carried out at oil temperature 313K and pressure up to 1.3 GPa. Their solidification pressure were easily determined by the appearance of molecular crystal, abrupt volumetric contraction and generation of heat of solidification and showed minima under the matching condition. The bulk modulus K of molecular crystal was evaluated using phase diagram. The bulk modulus showed maxima under the each matching condition. The chain matching effect on the bulk modulus beyond the scope of the interfacial phenomena are confirmed.

• Journal of Microbiology and Biotechnology
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• 제9권1호
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• pp.32-38
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• 1999

A biosurfactant produced by Tsukamurella sp. 26A was purified by procedures including acid precipitation, ethylacetate extraction, and adsorption chromatography. The purified biosurfactant reduced the surface tension of water from 72 mN/m to 30 mN/m at a concentration of 250 mg/l, whereas the minimum interfacial tension against n-hexadecane was lowered to 1.5 mN/m at a concentration of 40 mg/i. The compound stabilized oil-in-water emulsions with a variety of commercial oils and had strong emulsification and stabilization activities when compared to those of commercial emulsifiers and stabilizers. Surface tension was stable over a broad range of pH (2-12) and temperature ($100^{\circ}C$, 3h). The biosurfactant was identified as glycolipid having a hydrophilic moiety of trehalose.

• Korean Chemical Engineering Research
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• 제50권4호
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• pp.733-737
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• 2012

본 연구는 미세유체의 수력학적 조절을 통한 단분산성 다중 액적 형성방법을 기술한다. 다중 액적을 형성하기 위해 별도의 표면 개질이 필요 없는 co-flowing stream 시스템과 유리 모세관을 이용하여 미세유체 칩을 제작하였다. 유리모세관 미세유체 칩 내부로 0.5 wt% Tween 20이 함유된 증류수, n-hexadecane (5 wt% Span 80), 그리고 10 wt% poly(vinyl alcohol) (PVA) 수용액을 흘려줌으로써 단분산성 다중 액적(W/O/W)을 성공적으로 형성하였다. 더불어, 내부 액적의 개수를 제어하기 위해 수력학적 변수로 작용하는 중간 유체와 최외각 유체의 부피유속을 고정시키고 내부 유체의 부피유속을 조절하는 방법을 사용하여 다양한 내부 액적을 지니는 다중 유화 액적을 성공적으로 완성하였다. 이와 같은 미세유체 시스템을 통해 형성된 다중 액적은 내부물질의 종류에 따라 다양한 화학반응을 위한 하나의 독립된 마이크로 반응기로 사용될 수 있을 것으로 기대한다.

• 한국항공우주학회지
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• 제44권10호
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• pp.887-894
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• 2016

고상-액상 상변화물질(PCM, Phase Change Material)을 이용한 위성부품 열제어장치를 설계 및 제작하였으며 열환경시험을 수행함으로써 온도제어 성능을 분석하였다. 설계온도에 부합하는 n-Hexadecane을 PCM으로 채용하였고, 낮은 열전도도를 보완하기 위하여 내부에 전열휜이 장착된 용기를 Al6061로 제작하였다. 위성에 장착하였을 때와 동일한 작동조건을 확보하기 위하여, 부품과 방열판 사이를 열관으로 연결하였으며 열관의 단열부가 관통하도록 PCM 열제어장치를 설치하였다. 동일한 모양과 부피의 열적완충질량(TBM, Thermal Buffer Mass)도 제작하여, 주기적인 가열-냉각 실험을 수행하였다. 실험결과 상변화 잠열에 의한 PCM의 열제어 성능을 확인할 수 있었으며, TBM에 비하여 질량과 보온히터의 소모전력을 절감할 수 있음을 확인하였다.

• 한국식품영양과학회지
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• 제27권2호
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• pp.252-258
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• 1998

Biosurfactant를 생산하는 미생물을 토양으로부터 분리하였다. 그 중에서 표면장력 및 계면장력 감소능에서 가장 우수한 L-417주를 순수분리하여 동정한 결과, No-Cardia속으로 판명되었다. Biosurfactant 생산을 위한 최적 배지조성은 3% n-hexadecane, 0.1% $NaNO_3$, 0.02% $K_2HPO_4$, 0.01% $KH_2PO_4$, 0.01% $MgSO_4 \;.\;7H_2O$, 0.01% $CaCl_2$ 0.02% yeast extract였으며, 최적 온도와 pH는 각각 $30^{\circ}C$와 6.0이였다. 이러한 조건에서 500ml용 shaking flask에 최적 배지 50ml를 넣어 배양했을 경우 대수증식기 말기인 4일째에 균의 증식과 유화활성이 가장 높게 나타남에 따라 Nocardia sp. L-417에 의한 bio-surfactant의 생산은 균의 생육과 밀접한 관련이 있는 것으로 판단된다. 이계면활성제는 산업적으로 널리 사용되는 bunker A, paraffin, corn oil 및 oilve oil 등에 대해서도 비교적 높은 유화활성을 나타내였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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• pp.216-217
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• 2014

Optimum finishing position, thickness and phase change temperature of winter and summer season were selected and suitability of finishing materials was evaluated based on temperature measurement of specimens applying the coating material mixed phase change materials(PCM). As a result, when finishing position was interior and finishing thickness of coating material mixed n-Octadecane(28℃ PCM) was 4mm, thermal performance was effective. n-Octadecane in summer season and n-Hexadecane(18℃ PCM) in winter season are indicated effective on energy savings, respectively.

• Journal of Microbiology and Biotechnology
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• 제6권3호
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• pp.184-188
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• 1996

The Acinetobacter sp. BE-254 isolated from soil sources produced a bioemulsifier in the medium supplemented with n-hexadecane. This bioemulsifier was purified by the procedures of fractionation (ammonium sulfate and chilled acetone), extraction by hexane, and column chromatography on silica gel 60. The results from various color reactions indicated that the bioemulsifier was a glycolipid. The purified emulsifier was very stable at pHs ranging from 4 to 10 and under heat treatment at $100^{\circ}C$ for 30 min. Emulsification activity was also hardly influenced by pH. The critical micelle concentration (CMC) and surface tension at the point ($\gamma_{cmc}$) of the bioemulsifier were approximately 35 mg/l and 30 mN/m, respectively. The bioemulsifier showed a fairly good emulsification activity and stability in comparison with other commercial emulsifiers in the basic formula composed of emulsifier, oil, and water.

• Journal of Advanced Marine Engineering and Technology
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• 제22권4호
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• pp.551-559
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• 1998

Evaporation and ignition characteristics of fuel droplet have major influences on the efficiency and performance of engine. In the present study the experiment of evaporation and self-ignition of single fuel was performed under the various ambient conditions. An individually suspended droplet of n-heptane n-hexadecane ethyl-alcohol and light oil were employed as a liquid droplet. Evaporation and ignition characteristics were measured by using the video-camera and image processing technique under the various ambient temperatures (up to 1000310 OC)and partial pressure of oxigen(up to 60%) The evaporation curve shows that the droplet life time ignition delay time decreases as the ambient temperature and partial pressure of oxigen increase, The temperature variations of droplet were also reported for various fuel and ambient temperatures. The numerical simulations were carried out to predict droplet diameter and temperature with favorable agreement.

• International Journal of Automotive Technology
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• 제2권3호
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• pp.109-115
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• 2001

A study has been conducted to clarify the effect of watery vapor concentration in hot ambient on droplet evaporation. Droplets of water, ethanol, n-hexadecaneand n-heptane were used in this experimental study. Ambient conditions are fixed at 470 K in temperature, 0.1 MPa in pressure and 2 m/s in velocity of ambient air. Watery vapor concentration was changed 0%～40% by 10% by add water to air. To obtain the time histories of droplet diameter after exposed in ambient, a suspended droplet in hot and humid ambient stream was synchronized with a back flash light, and enlarged droplet images were taken by a CCD camera. The evaporation rate constant of water droplet decreases slightly with the vapor concentration because diffusion velocity reduction of droplet vapor occurs on the surface. The values of ethanol and n-heptane droplet actively increase by effect that water from condensation of vapor flows into the droplet. The evaporation rate constant of n-hexadecane which has higher boiling point than water increases within around 30% of the concentration.

• 한국지하수토양환경학회지:지하수토양환경
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• 제17권2호
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• pp.7-14
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• 2012

Batch tests were carried out to evaluate the thermal treatment of low volatile organic compounds in low-permeability soil. The chemical oxidation by sodium persulfate catalyzed by heat and Fe (II) was evaluated. Enhanced persulfate oxidation of n-decane (C-10), n-dodecane (C-12), n-tetradecane (C-14), n-hexadecane (C-16), and phenanthrene was observed with thermal catalyst, indicating increased sulfate radical production. Slight enhancement of the pollutants oxidation was observed when initial sodium persulfate concentration increased from 5 to 50 g/L. However, the removal efficiency greatly decreased as soil/water ratio increased. It indicates that mass transfer of the pollutants as well as the contact between the pollutants and sulfate radical were inhibited in the presence of solids. In addition, more pollutants can be adsorbed on soil particles and soil oxidant demand increased when soil/water ratio becomes higher. The oxidation of the pollutants was significantly improved when catalyzed by Fe(II). The sodium persulfate consumption increased at the same time because the residual Fe(II) acts as the sulfate radical scavenger.