• Title/Summary/Keyword: N-R Method

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Hybrid Water Treatment of Tubular Alumina MF and Polypropylene Beads Coated with Photocatalyst: Effect of Nitrogen Back-flushing Period and Time (관형 알루미나 정밀여과와 광촉매 코팅 폴리프로필렌 구의 혼성 수처리: 질소 역세척 주기와 시간의 영향)

  • Park, Jin Yong;Choi, Min Jee;Ma, Jun Gyu
    • Membrane Journal
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    • v.23 no.3
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    • pp.226-236
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    • 2013
  • The effect of $N_2$ back-flushing period (FT) and time (BT) was compared with the previous result used PES (polyethersulfone) beads loaded with titanium dioxide photocatalyst in hybrid process of alumina microfiltration and PP (polypropylene) beads coated with photocatalyst in viewpoints of membrane fouling resistance ($R_f$), permeate flux (J), and total permeate volume ($V_T$). The reason of nitrogen back-washing instead of the general air back-washing method is to minimize the possible effect of oxygen included in air on water quality analysis. As decreasing FT, $R_f$ decreased and J and $V_T$ increased. Treatment efficiency of dissolved organic matters (DOM) was 82.0%, which was the higher than 78.0% of the PES beads result. This means that PP beads coated with photocatalyst was the more effective than PES beads loaded with photo-catalyst in the DOM removal. As increasing BT, the final $R_f$ decreased and the final J increased, but $V_T$ was the maximum at BT 15 sec. The average treatment efficiency of turbidity did not have any trend as changing BT. As BT increasing from 6 sec to 30 sec, the treatment efficiency of DOM increased 11.8%, which was a little higher than the result of PES beads.

Size Distribution and Temperature Dependence of Magnetic Anisotropy Constant in Ferrite Nanoparticles

  • Yoon, Sunghyun
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.104-105
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    • 2012
  • The temperature dependence of the effective magnetic anisotropy constant K(T) of ferrite nanoparticles is obtained based on the measurements of SQUID magnetometry. For this end, a very simple but intuitive and direct method for determining the temperature dependence of anisotropy constant K(T) in nanoparticles is introduced in this study. The anisotropy constant at a given temperature is determined by associating the particle size distribution f(r) with the anisotropy energy barrier distribution $f_A(T)$. In order to estimate the particle size distribution f(r), the first quadrant part of the hysteresis loop is fitted to the classical Langevin function weight-averaged with the log?normal distribution, slightly modified from the original Chantrell's distribution function. In order to get an anisotropy energy barrier distribution $f_A(T)$, the temperature dependence of magnetization decay $M_{TD}$ of the sample is measured. For this measurement, the sample is cooled from room temperature to 5 K in a magnetic field of 100 G. Then the applied field is turned off and the remanent magnetization is measured on stepwise increasing the temperature. And the energy barrier distribution $f_A(T)$ is obtained by differentiating the magnetization decay curve at any temperature. It decreases with increasing temperature and finally vanishes when all the particles in the sample are unblocked. As a next step, a relation between r and $T_B$ is determined from the particle size distribution f(r) and the anisotropy energy barrier distribution $f_A(T)$. Under the simple assumption that the superparamagnetic fraction of cumulative area in particle size distribution at a temperature is equal to the fraction of anisotropy energy barrier overcome at that temperature in the anisotropy energy barrier distribution, we can get a relation between r and $T_B$, from which the temperature dependence of the magnetic anisotropy constant was determined, as is represented in the inset of Fig. 1. Substituting the values of r and $T_B$ into the $N{\acute{e}}el$-Arrhenius equation with the attempt time fixed to $10^{-9}s$ and measuring time being 100 s which is suitable for conventional magnetic measurement, the anisotropy constant K(T) is estimated as a function of temperature (Fig. 1). As an example, the resultant effective magnetic anisotropy constant K(T) of manganese ferrite decreases with increasing temperature from $8.5{\times}10^4J/m^3$ at 5 K to $0.35{\times}10^4J/m^3$ at 125 K. The reported value for K in the literatures is $0.25{\times}10^4J/m^3$. The anisotropy constant at low temperature region is far more than one order of magnitude larger than that at 125 K, indicative of the effects of inter?particle interaction, which is more pronounced for smaller particles.

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FINITE ELEMENT STRESS ANALYSIS OF A CLASS II COMPOSITE RESIN RESTORATION (2급 와동의 복합레진 충전에 관한 유한요소법적 응력분석)

  • Song, Bo-Kyung;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.20 no.2
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    • pp.627-643
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    • 1995
  • The resistance to fracture of the restored tooth may be influenced by many factors, among these are the cavity dimension and the physical properties of the restorative material. The placement of direct composite resin restorations has generally been found to have a strengthening effect on the prepared teeth. It is the purpose of this investigation to study the relationship between the cavity isthmus and the fracture resistance of a tooth in composite resin restorations. In this study, MO cavity was prepared on the maxillary left first molar and then filled with composite resin. Three dimentional model with 3049 nodes and 2450 8-node blick elements was made by the serial photographic method and isthmus (1/4, 1/3, 1/2 and 2/3 of intercusplal distance between mesiobuccal cusp tip and mesiolingual cusp tip) was varied. Two types of model(B and R model) were developed. B model was assumed perfect bonding between the restoration and cavity wall and R model was left unfilled. A load of 1500N was applied vertically on the node from the lingual slope of the mesiobuccal cusp. The results were as follows : 1. There was a significant decrease of stress resulting in increase of fracture resistance in B model when compared with R model. 2. When it comes to stress distribution, the stress was concentrated in the facio-gingival line angle and the buccal side of the distal margin of the cavity in both Band R model. 3. With the increase of the isthmus width, the stress decreased in the area of the facio-gingival line angle, and increased in the area of facio-gingival line angle as well as the buccal side of the distal margin of the cavity in B model. In R model, the stress increased both in the area of facio-gingival line angle and the buccal side of the distal margin of the cavity, therefore the possibility of crack increased. 4. As the width of cavity increased, in B model, the direction of crack moved from horizontal to vertical on the facio-gingival line angle and the facio-pulpal line angle. In R model, the direction of the crack was horizontal on the facio-gingival line angle and moved from horizontal to the $45^{\circ}$ direction on the facio-pulpal line angle.

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The Changes of Solid, Nitrogen and Phosphorus Concentrations in Pig Slurry Stored at Various Depth of Slurry Storage Tank (돼지분뇨슬러리의 액비조내 저장깊이별 고형물 및 질소, 인의 함량분포에 관한 연구)

  • Jeong, Kwang-Hwa;Chung, Eui-Soo;Park, Chi-Ho;Kwag, Jung-Hoon;Choi, Dong-Yoon;Yoo, Yong-Hee
    • Journal of Animal Environmental Science
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    • v.12 no.3
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    • pp.161-168
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    • 2006
  • This paper describes the changes of characteristics of pig slurry according to storing depth. Most of the substances containing pollutants, such as were Management of manure and wastewater from animal confinement facilities is a critical factor for pollution control. With proper treatment processing method in both solid and liquid forms, it can be used as a fertilizer and soil conditioner. In Korea, liquid-manure handling system is very popular because its treatment and application is easy and labor saving. In the storage tank treatment, the period of fermentation process and solids-liquid separation averages six months and the supernatant liquid is being used as a fertilizer. In this study, the changes in chemical characteristics of pig slurry at varying depths of the storage tank were investigated. Results showed that the pH value of the fermented pig slurry was > 7, while the major pollutants such as BOD, SS, N and P were highest in the bottom of the tank. Therefore, the above findings proved that varying depths in the storage tank can influence the concentration of pollutants of the fermented pig slurry.

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Method of Nitrate Nitrogen Determination for Plant, Soil and Water Analysis by E. coil Cells (E. coli 세포(細胞)를 이용한 식물(植物), 토양(土壤) 및 수질(水質)의 질산태(窒酸態) 질소(窒素) 분석방법(分析方法))

  • Sohn, Sang Mok;Kucke, Martin;Lee, Yoon Gun
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.4
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    • pp.361-369
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    • 1997
  • A microbiological nitrate determination method by E. coli is modified in Korea, using K12 wildtype, KCTC 1116, for the quantitative reduction of $NO_3{^-}$ to $NO_2{^-}$. The nitrate in plant, soil or water sample is determined spectrophotometrically after being diazotized with sulfaniamide and N-(1-naphthl)-ethlenediamine. The modified E. coli cell method and principle for nitrate determination using Korean wildtype E. coli strain is described, and cell culture and preparation of stock suspension for E. coli as well. This modified E. coli cell method can be managed simply and fast, it is suitable for the investigation of the large serials, it can be also automated and has a high degree of sensitivity up to 0.01ppm $NO_3{^-}-N$ in the sample solution. The applicability of the modified E. coli cell method has been tested for plant, soil and water analysis on a wide range of different samples. Recovery rates of added nitrate have been determined and comparisons with other standard nitrate analytical procedures have been carried out. The results with the modified E. coli cell method show high correlation ($r^2=0.98$) with those gained by the standard analytical procedures. The advantages and disadvantages of the method are also discussed to other nitrate determination methods.

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Effect of Cosurfactant on Microemulsion Formation and Cleaning Efficiency in Systems Containing Alkyl Ethoxylates Nonionic Surfactant, D-Limonene and Water (보조계면활성제 첨가가 Alkyl Ethoxylates계 비이온 계면활성제, D-limonene, 물로 이루어진 시스템에서의 마이크로에멀젼 형성 및 세정력에 미치는 효과)

  • Lee, Jong Gi;Bae, Sang Soo;Cho, In Sik;Park, So Jin;Park, Byeong Deog;Park, Sang Kwon;Lim, Jong Choo
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.664-671
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    • 2005
  • In this study, the effect of sosurfactant on microemulsion phase behavior was investigated in ternary systems containing alkyl ethoxylates nonionic surfactant, water and d-limonene. The addition of a cosurfactant produced a microemulsion phase over a wide range of temperature and promoted formation of a microemulsion phase at lower temperatures. In particular, small amounts of n-propanol, as a cosurfactant, were found to be the most effective in extending a microemulsion phase region over a wide range of temperature. Temperature sensitivity of a nonionic surfactant system was effectively relieved by addition of the anionic surfactant sodium dodecyl sulfate. And the formation of one phase microemulsion was not affected by pH, hardness concentration and addition of an antioxidation agent. The cleaner candidates were determined from microemulsion phase behavior study, and their cleaning efficiency was tested using a dipping method. All the cleaner candidates selected during this study showed excellent removal efficiency for abietic acid over a temperature range from 30 to $40^{\circ}C$ presumably due to a decrease in interfacial tension.

Assessment of actual evapotranspiration using modified satellite-based priestley-taylor algorithm using MODIS products (MODIS 위성자료를 이용한 Modified Satellite-Based Priestley-Taylor (MS-PT)의 적용 및 실제 증발산 평가)

  • Baik, Jongjin;Park, Jongmin;Choi, Minha
    • Journal of Korea Water Resources Association
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    • v.49 no.11
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    • pp.903-912
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    • 2016
  • Accurate understanding and estimating Evapotranspiration (ET) is essential for understanding the mechanism of water cycle and water budget. ET has been analyzed by many researchers in worldwide while Ground-based ET has limiation in analyzing the spatio-temporal pattrens of ET. Thus, many researches have been conducted to represent the spatio-temporal variation of ET by using hydrometeorological variables estimated from remote sensing datasets. Previous remote sensing based ET algorithms, however, have disadvantage in that various hydrometeological input datasets were required. In this study, actual ET was estimated by MODIS-based Rn and MS-PT algorithm requiring relatively less input data than previous method. The result confirmed that the observed $R_N$ and latent heat flux from the eddy-covariance based fluxtowers located at CFK and SMK showed high correlation with the estimated $R_N$ and ET. The average determination coefficients ($R^2$) of ET estimated from satellite dataset over study periods were 0.77 (0.72-0.81) in Cheongmi (CFK) and 0.70 (0.67-0.78) in Sulma (SMK), respectively. Comparing with the actual ET of two flux tower sites, however, SMK showed more overestimated patterns than CFK due to the vegetation and radiation related errors.

Anti-oxidative Activity and Moisturizing Effect of Fermented Puer Tea Extract (발효보이차 추출물의 항산화활성 및 보습효과)

  • Kim, In-Young;Zhoh, Choon-Koo;Han, Sa-Ra;Bang, Young-Bae;Li, Ri-Yuan
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.272-279
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    • 2013
  • The fermented puer tea leaves were high concentrated extracted with 50% ethanolic solution in this study. Also, evaluating the anti-oxidative activity and anti-aging effect of this extract, we expected to apply the cosmetic industry. The yield of fermented puer tea extract was 17.9%. The total polyphenol content was 37.5%, tannin content was 7.5%, polysaccharide was 17.9%, unknown compound was 22%, and water content was 8%. Anti-oxidative activity (in-vitro) of fermented puer tea extract by DPPH method was $33.7{\pm}1.8%$ in 30mg/mL, $39.4{\pm}2.2%$ in 50mg/mL respectively. Therefore, we could know that anti-oxidative activity of fermented puer tea extract was effect higher than tocopheryl acetate and greentea extract. The collagen synthesis activity (in-vitro) of fermented puer tea extract was increased with $102.9{\pm}9.9%$ in 1 mg/mL, $111.5{\pm}9.9%$ in 5 mg/mL, $122.7{\pm}12.2%$ in 10 mg/mL, $131.5{\pm}13.7%$ in 30 mg/mL (*p-value£0.05, n=3). Skin moisturizing activity of fermented puer tea extract after application 8 hours was increased 38.5% higher than control samples both tocopheryl acetate and greentea extract. Total moisturizing effect was increased about 32.7% compared to before treatment. Fermented puer tea extract of this study can be applied to the skin care cosmetics industry.

Evaluation of Acetylcholinesterase Inhibitory and Antioxidative Activities of Rhus javanica (오배자 추출물의 Acetylcholinesterase 저해 및 항산화 활성 평가)

  • Bae, Jong-Sup;Lee, Hyun-Shik;Lee, Ha Yeong;Yoo, Byung-Hyuk;Kim, Taewan;Kim, Yong Han;Kim, Tae Hoon
    • Food Science and Preservation
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    • v.19 no.5
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    • pp.751-756
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    • 2012
  • Antioxidant capacity and acetylcholinesterase (AChE) inhibitory activity of the aqueous methanolic extract of Rhus javanica were investigated in vitro. The antioxidant properties was measured by radical scavenging assays using DPPH and $ABTS^+$ radicals. The AChE inhibitory efficacy of R. javanica was tested by Ellman's assay and the total phenolic content was determined using a spectrophotometric method. All tested samples showed a dose-dependent AChE inhibitory and radical scavenging activities. In particularly, ethyl acetate (EtOAc)-soluble portion from the methanolic extract of R. javanica showed significantly higher inhibitory activity than other organic solvent soluble-portions in an AChE and radical scavenging assay systems. These results suggest that R. javanica may be possess potential benefits which might be useful in development of antioxidant and anti-alzheimer's disease ingredient.

Ferroelectric Properties of ErMnO3 Thin Film Prepared by Sol-gel Method (졸겔법으로 제조한 ErMnO3 박막의 강유전 특성)

  • Kim, Yoo-Taek;Kim, Eung-Soo;Chae, Jung-Hoon;Ryu, Jae-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.829-834
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    • 2002
  • Ferroelectric properties of $ErMnO_3$ thin films deposited on Si(100) substrate using Sol-gel process with metal salts were investigated. $ErMnO_3$ thin films with a (001) preferred orientation were crystallized at 800$^{\circ}C$. The $ErMnO_3$ thin film post-annealed at 800$^{\circ}C$ for 1 h showed the dielectric constant(k) of 26 and the dielectric loss(tan ${\delta}$) of 0.032 at the frequency range from 1 to 100 KHz. The grain size of $ErMnO_3$ thin film post-annealed at 800 for 1 h was 10∼30 nm. The remanent polarization($P_r$) of the $ErMnO_3$ thin films increased with increasing (001) preferred orientation. The $ErMnO_3$ thin films post-annealed at 800$^{\circ}C$ for 1 h showed the remanent polarization($P_r$) of 400 nC/$cm^2$, with the increase of post-annealing time at 800$^{\circ}C$, the coercive field($E_c$) of thin films was lowered because the dense and homogeneous thin films were obtained.