• Title/Summary/Keyword: N-Phenyl imides

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Synthesis and Herbicidal Activity of N-{2,4-dichloro-5-(3-pyrazolyl)Phenyl} imides (N-{2,4-Dichloro-5-(3-pyrazolyl)phenyl}imides 유도체의 합성 및 제초활성)

  • Kim, Kyoung-Mahn;Lee, Byung-Hoe;Ryu, Eung-Kul
    • The Korean Journal of Pesticide Science
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    • v.4 no.3
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    • pp.15-18
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    • 2000
  • A series of N-{2,4-dichloro-5-(3-pyrazolyl)Phenyl}imides 7 and 8 was prepared and evaluated their herbicidal activities. Those compounds in which either carboxylate or carboxamide moiety is on pyrazole moiety 7c-71 showed no herbicidal activity whereas, the compounds in which trifluoromethyl group is substituted in pyrazolyl moiety showed moderate herbicidal activities against barnyardgrass, monochria and flat-sedge under paddy conditions with good rice tolerance at rate 63-250 g/ha.

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Synthesis and Herbicidal Activity of New N-{5-[(Pyrazolylmethyl)oxy]phenyl}imides (새로운 N-{5-[(Pyrazolylmethyl)oxy]phenyl}imide 유도체들의 합성 및 제초활성)

  • Kim, Kyoung-Mahn;Song, Jong-Hwan;Jeon, Dong-Ju;Kim, Hyoung-Rae;Choi, Jung-Sup;Oh, Do-Yeon;Ryu, Eung-K.
    • The Korean Journal of Pesticide Science
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    • v.4 no.2
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    • pp.72-75
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    • 2000
  • 3,4-Dimethyl-N-[4-chloro-2-fluoro-5-{(pyrazolylmethyl)oxy}phenyl]maleimides or 3,4,5,6-tetrahydro-N-[4-chloro-2-fluoro-5-{(pylazolylmethyl)oxy} phenyl]phthalimides were prepared and evaluated their herbicidal activities under paddy conditions. Those compounds which have N-methyl-5-pyrazolylmethyloxy moiety showed good tolerance in transplanted rice and strong herbicidal activities on barnyardgrass below 60 g/ha of dose.

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Photosensitive Polyimides Having Aromatic Sulfonyloxyimide Groups in the Main Chain (주쇄에 광분해성 방향족 술포닐옥시이미드기를 함유한 감광성 폴리이미드)

  • 오세용;이지영;조성열;정찬문
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.407-417
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    • 2000
  • Photosensitive polyimides having cyclobutane or phenyl and aromatic sulfonyloxyimide units in the main chain have been synthesized and the photodegradation behavior was investigated in relation with the polymer structure. The polyimides were prepared by condensation polymerization of N-hydroxyl and sulfonyl chloride. The prepared polyimides were stable up to 25$0^{\circ}C$ without thermal degradation. It has been found that the photodegradation of polyimides upon irradiation of 254 nm UV light results from scission of N-O bonds or ring opening of imides moiety by spectroscopic measurements. The polyimides were useful as positive working photodegradable polymers. Especially, the positive tone image of polyimide containing a pyromellitic diimide moiety exhibited high sensitivity and resolution.

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