• 제목/요약/키워드: N-Donor

검색결과 525건 처리시간 0.026초

Phenol과 DMA 간의 수소결합 (Intermolecular Hydrogen Bond between Phenol and DMAs)

  • 김복혜;이익춘
    • 대한화학회지
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    • 제10권1호
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    • pp.15-17
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    • 1966
  • Phenol과 각 종 Dimethylaniline(DMA)간의 수소결합을 Infrared Spectrophotometer로 연구하였다. 일반으로 DMA는 n-donor 및 ${\pi}$-donor의 2중 역활을 하나 주로 n-donor로 작용하며 phenol의 O-H stretching frequency의 shift(${\Delta}{\nu}$)는 DMA의 basicity에 비례하였고 (${\Delta}{\nu}$) 와 Hammett의 σcontant사이에는 linearity가 성립함을 알았다.

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각종 수소공여체의 첨가에 의한 $NO_3^--N$ 함유 폐수의 탈질 (Denitrification of the wastewater containing nitrate by various hydrogen donor addition)

  • 김형석;은종극;박승조
    • 한국환경과학회지
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    • 제4권3호
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    • pp.77-77
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the NO3--N removal efficiency by various hydrogen donor addition, determination of optimum COD/$NO_3^--N$ ratio and characteristics of granular sludge.

USB 공법에 의한 $NO_3^--N$ 함유 폐수처리 (Treatment of wastewater containing nitrate using upflow sludge blanket process)

  • 김형석;은종극;박승조
    • 한국환경과학회지
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    • 제4권3호
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    • pp.87-87
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

각종 수소공여체의 첨가에 의한 $NO_3^--N$ 함유 폐수의 탈질 (Denitrification of the wastewater containing nitrate by various hydrogen donor addition)

  • 김형석;은종극;박승조
    • 한국환경과학회지
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    • 제4권3호
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    • pp.229-237
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the NO3--N removal efficiency by various hydrogen donor addition, determination of optimum COD/$NO_3^--N$ ratio and characteristics of granular sludge.

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USB 공법에 의한 $NO_3^--N$ 함유 폐수처리 (Treatment of wastewater containing nitrate using upflow sludge blanket process)

  • 김형석;은종극;박승조
    • 한국환경과학회지
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    • 제4권3호
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    • pp.239-247
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

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Reducing the donor site morbidity in radial forearm free flaps by utilizing a narrow radial forearm free flap

  • Shaikh, Safdar Ali;Bawa, Amber;Shahzad, Noman;Yousufzai, Zara;Ghani, Muhammad Shahab
    • Archives of Plastic Surgery
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    • 제45권4호
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    • pp.345-350
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    • 2018
  • Background The radial forearm free flap (RFFF) has remained a leading choice of many plastic surgeons as a fasciocutaneous flap due to its versatility, pedicle length, and simple elevation technique. However, donor site morbidity has led many reconstructive surgeons to limit their use of the RFFF and to use other flaps instead. We propose that using a narrow RFFF (nRFFF) decreases the aesthetic and functional morbidity of the donor site. Methods We report our experiences with the nRFFF from April 2012 through May 2015 at the Department of Plastic, Reconstructive, and Hand Surgery at Liaquat National Hospital, Karachi. The donor defects were closed primarily. The Stony Brook Scar Evaluation Scale and comparison with the contralateral hand were used to assess aesthetic and functional outcomes, respectively. Results A total of 24 patients underwent nRFFF procedures during the study period. The donor arm showed excellent motor function in 22 cases (91.7%), and very good function in the remaining two cases (8.3%). The aesthetic outcomes were excellent in four patients (16.6%), very good in eight patients (33.3%), good in 10 patients (41.6%), and fair in two patients (8.3%) who developed a hypertrophic scar. All flaps were successful and there were no cases of partial or complete loss. Conclusions For small to medium-sized soft tissue defects, the nRFFF had acceptable outcomes due to its thinness, pliability, and major reduction in donor site aesthetic and functional morbidity.

Oxovanadium(IV) Complexes Containing VO(ONS) Basic Core: Synthesis, Structure, and Spectroscopic Properties

  • Jang, Yoon-Jung;Lee, Uk;Koo, Bon-Kweon
    • Bulletin of the Korean Chemical Society
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    • 제26권1호
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    • pp.72-76
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    • 2005
  • Some mononuclear oxovanadium(IV) complexes having the general formula [VOL(bidentate)] (1-4) of which L is tridentate ONS-donor salicylaldehyde S-methyldithiocarbazate (sal-mdtc$^{2-}$) or salicylaldehyde 4- phenylthiosemicarbazate (sal-phtsc$^{2-}$) and bidentate stands for 2,2'-bipyridyl (bpy) or 1,10-phenanthroline (phen) have been synthesized. The complexes were characterized by elemental analyses, FAB mass, UV, IR spectroscopy, and cyclic voltammetry. Two of the complexes [VO(sal-mdtc)(bpy)] (1) and [VO(sal-mdtc) (phen)] (2) were crystallographically characterized. The structures revealed that vanadium atom is octahedrally coordinated by the O, N, and S donor atoms of the tridentate ligand, the two N atoms of bidentate ligand, and the oxo atom. The oxygen donor, occupying an apical position has a trans-labilizing effect, resulting in elongation of the V-N bond. The cyclic voltammograms of the complexes exhibited one cathodic response in the range −d1.45 $\sim$ −f1.52 V due to the reduction of V(IV) to V(III).

Donor-Site Morbidity after Partial Second Toe Pulp Free Flap for Fingertip Reconstruction

  • Kim, Hyung Su;Lee, Dong Chul;Kim, Jin Soo;Roh, Si Young;Lee, Kyung Jin;Yang, Jae Won;Ki, Sae Hwi;Harijan, Aram
    • Archives of Plastic Surgery
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    • 제43권1호
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    • pp.66-70
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    • 2016
  • Background In this study, we characterize the morbidity at the donor-site of partial second toe pulp free flaps in terms of wound management as well as long-term outcomes. Methods A single-institutional retrospective review was performed for patients who had undergone partial second toe pulp free flap transfer to the fingertip. Patient charts were reviewed for infection, skin necrosis, wound dehiscence, and hematoma for the donor site. Additionally, a questionnaire survey was given to patients who had a follow-up of longer than 1 year to characterize long-term postoperative pain and appearance. Results The review identified a total of 246 cases. Early wound complications were significant for wound dehiscence (n=8) and hematoma (n=5) for a wound complication rate of 5.3%. The questionnaire was distributed to 109 patients, and 54 patients completed the survey. Out of these 54 patients, 15 patients continued to have donor-site pain (28%) at a mean follow-up period of 32.4 months. However, the pain intensity was relatively low in the range between 2 to 5, on a 0-10 scale. None of these patients felt this donor-site pain interfered significantly with daily activity, nor did any patient require pain medications of any type. Donor-site appearance was satisfactory to most patients. Conclusions The partial second toe pulp flap was associated with low rates of wound complications and favorable long-term outcomes. Given the functional and aesthetic gain in the recipient finger, donor-site morbidities appear acceptable in this patient population. This study can be helpful in counseling patients regarding donor-site morbidity during the informed consent process.