• Title/Summary/Keyword: N value

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Solvolysis of (1S)-(+)-Menthyl Chloroformate in Various Mixed Solvents

  • Koh, Han Joong;Kang, Suk Jin
    • Journal of the Korean Chemical Society
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    • v.65 no.5
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    • pp.309-312
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    • 2021
  • The solvolysis of (1s)-(+)-menthyl chloroformate (1) were studied kinetically in 28 pure and various mixed solvents. The analysis using the extended Grunwald-Winstein equation in the solvolysis of 1 obtained the l value of 2.46 ± 0.18, the m value of 0.91 ± 0.07, and the correlation coefficient of 0.950. The solvolysis of 1 might proceed via an associative SN2 mechanism enhancing bond making than bond breaking in the transition state (TS). The value of l/m is 2.7 within the ranges of value found in associative SN2 reaction. This interpretation is further supported by a relatively large solvent kinetic isotope effect (SKIE, 2.16).

ON HARMONICITY IN A DISC AND n-HARMONICITY

  • Lee, Jae-Sung
    • Bulletin of the Korean Mathematical Society
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    • v.47 no.4
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    • pp.815-823
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    • 2010
  • Let ${\tau}\;{\neq}\;\delta_0$ be either a power bounded radial measure with compact support on the unit disc D with $\tau(D)\;=\;1$ such that there is a $\delta$ > 0 so that ${\mid}\hat{\tau}(s){\mid}\;{\neq}\;1$ for every $s\;{\in}\;\Sigma(\delta)$ \ {0,1}, or just a radial probability measure on D. Here, we provide a decomposition of the set X = {$h\;{\in}\;L^{\infty}(D)\;{\mid}\;lim_{n{\rightarrow}{\infty}}\;h\;*\;\tau^n$ exists}. Let $\tau_1$, ..., $\tau_n$ be measures on D with above mentioned properties. Here, we prove that if $f\;{in}\;L^{\infty}(D^n)$ satisfies an invariant volume mean value property with respect to $\tau_1$, ..., $\tau_n$, then f is n-harmonic.

ON CONSTANT-SIGN SOLUTIONS OF A SYSTEM OF DISCRETE EQUATIONS

  • Agarwal, Ravi-P.;O'Regan, Donal;Wong, Patricia-J.Y.
    • Journal of applied mathematics & informatics
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    • v.14 no.1_2
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    • pp.1-37
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    • 2004
  • We consider the following system of discrete equations $u_i(\kappa)\;=\;{\Sigma{N}{\ell=0}}g_i({\kappa},\;{\ell})f_i(\ell,\;u_1(\ell),\;u_2(\ell),\;{\cdots}\;,\;u_n(\ell)),\;{\kappa}\;{\in}\;\{0,\;1,\;{\cdots}\;,\;T\},\;1\;{\leq}\;i\;{\leq}\;n\;where\;T\;{\geq}\;N\;>\;0,\;1\;{\leq}i\;{\leq}\;n$. Existence criteria for single, double and multiple constant-sign solutions of the system are established. To illustrate the generality of the results obtained, we include applications to several well known boundary value problems. The above system is also extended to that on $\{0,\;1,\;{\cdots}\;\}\;u_i(\kappa)\;=\;{\Sigma{\infty}{\ell=0}}g_i({\kappa},\;{\ell})f_i(\ell,\;u_1(\ell),\;u_2(\ell),\;\cdots\;,\;u_n(\ell)),\;{\kappa}\;{\in}\;\{0,\;1,\;{\cdots}\;\},\;1\;{\leq}\;i\;{\leq}\;n$ for which the existence of constant-sign solutions is investigated.

A Study on the Correlation between Standard Penetration Resistance Value and Static Cone Penetration Resistance Value of the Soft Ground Subsurface of Yongdong Area (표준관입저항치와 정적콘관입저항치의 상관성에 관한 연구 - 영동지역의 연약지반을 중심으로 -)

  • Kim, Jinam;Park, Heunggyu
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.5
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    • pp.13-20
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    • 2006
  • We have conducted standard penetration tests and static cone penetration tests that are widely used the land base examination on the soft ground subsurface of Yongdong area, and examined the correlation between them. We have also made a comparative analysis of the correlation between the indoor tests on the materials collected on the site and on-the-spot penetration tests. The results are as follows : The relationship between Standard Penetration Test N-value and Dutch Cone Tset show $Q_c=1.93N+0.29$ for organic soil, $Q_c=2.19N+0.20$ for clay, $Q_c=2.34N+1.06$ for silt, $Q_c=3.02N+0.54$ for silty sand, and $Q_c=3.47N+0.46$ for sand. In this case of sand $Q_c/N$ increases when the soil particles are larger. The relationship between standard penetration test N-value and Unconfined Compression Strength $q_u$ show $q_u=0.11N+0.03$ for organic soil, $q_u=0.11N+0.25$ for clay, and $q_u=0.18N-0.03$ for silt.

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Estimation of b-value for Earthquakes Data Recorded on KSRS (KSRS 관측자료에 의한 b-값 평가)

  • 신진수;강익범;김근영
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2002.09a
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    • pp.28-34
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    • 2002
  • The b-value in the magnitude-frequency relationship logN(m) = $\alpha$ - bmwhere N(m) is the number of earthquakes exceeding magnitude m, is important seismicity parameter In hazard analysis. Estimation of the b-value for earthquake data observed on KSRS array network is done employing the maximum likelihood technique. Assuming the whole Korea Peninsula as a single seismic source area, the b-value is computed at 0.9. The estimation for KMA earthquake data is also similar to that. Since estimate is a function of minimum magnitude, we can inspect the completeness of earthquake catalog in the fitting process of b-value. KSRS and KMA data lists are probably incomplete for magnitudes less than 2.0 and 3.0, respectively. Examples from probabilistic seismic hazard assessment calculated for a range of b-value show that the small change of b-value has seriously effect on the prediction of ground motion.

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THREE-POINT BOUNDARY VALUE PROBLEMS FOR HIGHER ORDER NONLINEAR FRACTIONAL DIFFERENTIAL EQUATIONS

  • Khan, Rahmat Ali
    • Journal of applied mathematics & informatics
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    • v.31 no.1_2
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    • pp.221-228
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    • 2013
  • The method of upper and lower solutions and the generalized quasilinearization technique is developed for the existence and approximation of solutions to boundary value problems for higher order fractional differential equations of the type $^c\mathcal{D}^qu(t)+f(t,u(t))=0$, $t{\in}(0,1),q{\in}(n-1,n],n{\geq}2$ $u^{\prime}(0)=0,u^{\prime\prime}(0)=0,{\ldots},u^{n-1}(0)=0,u(1)={\xi}u({\eta})$, where ${\xi},{\eta}{\in}(0,1)$, the nonlinear function f is assumed to be continuous and $^c\mathcal{D}^q$ is the fractional derivative in the sense of Caputo. Existence of solution is established via the upper and lower solutions method and approximation of solutions uses the generalized quasilinearization technique.

A study of a n.0, pplication of marketing to library management (도서관경영에 있어서 마아케팅의 도입에 관한 연구)

  • 권은경
    • Journal of Korean Library and Information Science Society
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    • v.14
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    • pp.99-120
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    • 1987
  • This paper tries to a n.0, pply the concept and process of marketing which have been developed in profit sector to library management. Since the end of 60's certain marketing researchers, among them Kotler, Levy, and Shapiro have advanced the theseses that marketing is not just a business organization as well. Recently libraries have been interested in markeing also. Marketing is a concept of sensitively serving and satisfying human needs through voluntary exchanges of value. Library is a value exchange system in which library service is exchanged with community's patronage. In order for library user to involve in the value exchange system voluntarily, library should analyze user's needs and offer products satisfying the needs. For doing this, library should understand marketing. In this paper, author introduces the marketing concepts and process, tries to show how to a n.0, pply the key concepts and process to public library management. The needs of marketing in library sector, the effectiveness and barriers in a n.0, pplying marketing to library also discussed.

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EIGENVALUE PROBLEMS FOR SYSTEMS OF NONLINEAR HIGHER ORDER BOUNDARY VALUE PROBLEMS

  • Rao, A. Kameswara;Rao, S. Nageswara
    • Journal of applied mathematics & informatics
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    • v.28 no.3_4
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    • pp.711-721
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    • 2010
  • Values of the parameter $\lambda$ are determined for which there exist positive solutions of the system of boundary value problems, $u^{(n)}+{\lambda}p(t)f(\upsilon)=0$, $\upsilon^{(n)}+{\lambda}q(t)g(u)=0$, for $t\;{\in}\;[a,b]$, and satisfying, $u^{(i)}(a)=0$, $u^{(\alpha)}(b)=0$, $\upsilon^{(i)}(a)=0$, $\upsilon^{(\alpha)}(b)=0$, for $0\;{\leq}\;i\;{\leq}\;n-2$ and $1\;{\leq}\;\alpha\;\leq\;n-1$ (but fixed). A well-known Guo-Krasnosel'skii fixed point theorem is applied.

Analysis of Underground Box Structures with Inelastic Soil Spring (비탄성 지반 스프링을 이용한 지하 구조물의 해석)

  • Oh, Chi-Woong;Chung, Jae-Hoon;Yhim, Sung-Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.3
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    • pp.91-96
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    • 2002
  • There are many methods for analyzing underground box structures. One is the method of Iterative removal of tensional spring. The other is the method of modeling of ground to 8-node elastic-plastic planar element. In this study, We use inelastic soil spring element for analyzing underground box structures. First, if N-value is over 50, the results of inelastic soil spring method is the same as the method of 8-node planar element in last stage. Second, as N is increasing, element forces in two methods are generally decreasing. Third, as N-value is increasing, element forces in two method are generally decreasing and displacement has decreasing incline. This is the same as the force-displacement curve of general underground structures.

A Study on the Effect of Fluid Flow on the Microstructure of High Purity Al Ingot under Forced Flow (강제대류시 고순도 Al괴의 응고조직에 미치는 유동의 영향)

  • Kim, Kyoung-Min;Kim, Heon-Joo;Ha, Ki-Yun;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.13 no.6
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    • pp.540-546
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    • 1993
  • The effects of fluid flow on the purification of aluminum were studied. As the revolution rate(N) increased, the size of columnar grain decreased gradually. The concentration of solidified crystal was decreased with increasing distance from chill and revolution rate(N). Distribution boundary layer thickness(${\delta}$) was calculated from the solute distribution obtained in solid experimentally and by use of BPS equation. The value of ${\delta}$ changed from about $60{\mu}m$ at N value of 27rpm to about $15{\mu}m$ at N value of 1000rpm. From this result, high purification was obtained by decreasing the diffusion boundary layer under forced convection.

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