• Title/Summary/Keyword: N concentration

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Pulsed DC Bias Effects on Substrate in TiNx Thin Film Deposition by Reactive RF Magnetron Sputtering at Room Temperature (반응성 RF 마그네트론 스퍼터링에 의한 TiNx 상온 성막에 있어서 기판 상의 펄스상 직류 바이어스 인가 효과)

  • Kim, Seiki
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.342-349
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    • 2019
  • Titanium nitride(TiN) thin films have been deposited on PEN(Polyethylene naphthalate) substrate by reactive RF(13.56 MHz) magnetron sputtering in a 25% N2/Ar mixed gas atmosphere. The pulsed DC bias voltage of -50V on substrates was applied with a frequency of 350 kHz, and duty ratio of 40%(1.1 ㎲). The effects of pulsed DC substrate bias voltage on the crystallinity, color, electrical properties of TiNx films have been investigated using XRD, SEM, XPS and measurement of the electrical properties such as electrical conductivity, carrier concentration, mobility. The deposition rates of TiNx films was decreased with application of the pulsed DC substrate bias voltage. The TiNx films deposited without and with pulsed bias of -50V to substrate exhibits gray and gold colors, respectively. XPS depth profiling revealed that the introduction of the substrate bias voltage resulted in decreasing oxygen concentration in TiNx films, and increasing the electrical conductivities, carrier concentration, and mobility to about 10 times, 5 times, and 2 times degree, respectively.

Rapid Nutrient Diagnosis of Cucumber by Test Strip and Chlorophyll Meter (Test Strip과 Chlorophyll Meter를 이용한 오이의 신속한 영양진단)

  • Kim, Kwon-Rae;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.5
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    • pp.272-279
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    • 2003
  • This study was performed to develop a more rapid and simple nutrient diagnosis method of plants than the conventional leaf analysis method. Cucumber (Cucumis sativus L. cv. jangil banbaek) was planted in the mixed media produced by mixing perlite and rock wool at 1:1 (v/v) ratio. The Yamazakki nutrient solution for cucumber was supplied to the media using micro-drip irrigation system. Experimental plots were consisted of no fertilization, deficient fertilization, adequate fertilization, and surplus fertilization for N, P and K. Specific color difference sensor value (SCDSV) measured by chlorophyll meter was closely related to total-N concentration in leaves measured by the conventional method. Nitrate, $PO_4$ and K concentration in petiole sap measured by test strips showed a significant relationship with total-N, P and K concentration in leaves. Linear regression equations between $NO_3$, $PO_4$ and K concentration in petiole sap and total-N, P and K concentration in the leaves were prepared. Optimum levels of $NO_{3}$, $PO_{4}$ and K in petiole sap were obtained by plugging the optimum concentrations of total-N, P and K in the leaves by other researchers into the equations. In conclusion, the SCDSV measured by chlorophyll meter and the concentration of $NO_3$, P and K in petiole sap measured by the test strips would be suitable for rapid estimation of plant nutrient status.

A Study on the Visualization of NO Concentration Distributions in $CH_4/O_2N_2$ Premixed Flames by PLIF (평면 레이저 유도 형광법(PLIF)을 이용한 $CH_4/O_2N_2$ 예혼합화염의 NO 농도 분포 가시화에 관한 연구)

  • Park, Kyoung-Suk;Lee, Sei-Hwan
    • Journal of ILASS-Korea
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    • v.6 no.3
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    • pp.1-7
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    • 2001
  • In this study, quantitative measurement of nitric oxide concentration distributions visualization were investigated in the laminar $CH_4/O_2N_2$ nixed flame by Planar laser-induced fluorescence(PLIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and $O_2$ fluorescence. The measurements were taken in $CH_4/O_2N_2$ premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flow rate of 3slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to MO formation in $CH_4/O_2N_2$ premixed flame. Furthermore, this trend was well matched with previous works.

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Study on Nutrient Loss in Surface Runoff by Rainfall from Slurrigated Area Using Digested Animal Manure (부숙처리된 축산분뇨슬러리 살포지역의 강우에 의한 영양물질 유출에 관한 연구)

  • ;;Osamu Tsuji;Fujio Tsuchiya
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.3
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    • pp.43-51
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    • 1997
  • The nutrients runoff including nitrogen and phosphorous was investigated to find out the characteristics of nutrient discharge from the slurrigated area using digested animal manure. The results obtained are summarized as follows: 1.The concentrations of T-N, $NH_4$- N, EC, T- P and Cl- were high in flood runoff. 2.The concentration of nutrients by the surface runoff, except for $NO_3$-N, showed a tendency of increasing when the period of dry days before the rain fall was long. And the concentration of N$NO_3$-N increased in the inflow section where subsurface drainage flowed in. 3.The quality of water was generally influenced by the discharge of water quantity from slurrigated area. However the runoff concentration influenced the water quality when it was high enough. 4.To reduce loss of the nutrients and improve the fertilization effect, it is not recommended to apply slurry in rainy season.

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The C-Axis Preferred Orientation Characteristic of AIN Thin Film as Sputtering parameter of Presputtering (Presputtering 공정변수에 따른 AIN 박막의 c축 배향특성)

  • 박영순;김덕규;소병문;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.246-250
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    • 2000
  • Reactive radio frequency (RF)magnetron sputter has been used to deposit AlN thin film on a Si substrate. (002)Preferred orientation of AlN thin film has been obtained at low sputtering pressure and high $\textrm{N}_2$ concentration. Also it has been shown that properties of AlN thin film are affected by presputtering time. As presputtering time increased aluminum and nitride concentration of AlN thin film decreased. But oxygen concentration and grain size increased. The good preferred orientation was shown with the short presputtering time.

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ELECTRICAL PROPERTIES OF ELECTROCHROMIC INDIUM NITRIDE THIN FILMS PREPARED BY RF ION PLATING

  • Asai, N.;Inoue, Y.;Sugimura, H.;Takai, O.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.276-280
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    • 1999
  • Electrical properties of electrochromic (EC) InN thin films prepared by rf ion plating were studied. There was a correlation between the electrical properties and the electrochromism in the InN films, particularly, carrier concentration changes were responsible for the electrical resistivity changes of the films due to the electrochromism. These carrier concentration changes were caused by chemisorbed hydroxyl groups and protons. From these results, it was proved that the carrier concentration changes of the InN films was responsible for the electrochromism in the visible and near-infrared region.

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Effects of Li$^+$ and Ag$^+$ Ions on the Rotational Barrier in Acetamide and propionamide System

  • Kwon, Dae-Keun;Choi, Young-Sang;Yoon, Chang-Ju
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.1-5
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    • 1986
  • The influences of $LiNO_3\;and\;AgNO_3$ on the N-C(O) rotational barrier of N,N-dimethylacetamide and N,N-dimethylpropionamide have been investigated. The rotational activation free energy $({\Delta}G^{\neq})\;for\;Li^{+}$-amide complexes is found to increase with increasing salt concentration. On the other hand, that for $Ag^+$-amide complexes increases in the presence of $Ag^+$ ion up to 0.25 M ion concentration and then decreases as the concentration of $Ag^+$ ion is further increased. Such an unusual behavior of $Ag^+$-amide complexes has been interpreted in terms of ion-pairing and diluent effect on the amides. However, $^{13}C$ nmr chemical shift data for the amides have shown that both of these ions interact primarily with the carbonyl group in amides.

A Study on Safety Treatment of NOx by Discharge Plasma Reaction (방전Plasma 반응에 의한 NOx의 안전처리에 관한 연구)

  • Choi, Jae-wook;Yamaguma, Mizuki
    • Journal of the Korean Society of Safety
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    • v.15 no.2
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    • pp.92-96
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    • 2000
  • In this experiment, we studied about concentration characteristics of $NO_x$ and generation of ozone in the reactor of corona discharge type by using mixed gas of $NO/N_2$ and $N_2/O_2$. In the case of the initial NO concentration increased, decrease rate of NO concentration was weakened and discharge input power of minimum NO concentration became high. When NO concentration was high, NO decomposition limit was appeared. And NO reduction rate was decreased, when initial NO concentration and discharge input power increased. When discharge input power was 5W, we could know the most proper energy value for treatment of NO. When the concentration of initial NO increased, generation of ozone decreased and in the case of same concentration of NO, according to discharge input power increase, generation of ozone increased.

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An experimental study on the viscosity of visco-elastic fluids (점탄성유체의 점성에 관한 실험적 연구)

  • 김춘식;이영호
    • Journal of Advanced Marine Engineering and Technology
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    • v.6 no.2
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    • pp.21-41
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    • 1982
  • Viscosity, especially characteristic among various properties of visco-elastic fluids such as high polymer solutions, is affected mainly by temperature and concentration. Hence, it is important for fluid engineering to express, by some equations, how the fluid characteristics vary with the change of temperature and concentration and to analyze them to obtain consistent viscous characteristics. High polymer solutions, synthetic products of modern chemical industry, suggest many interesting investigations because they are typical visco-elastic materials. Experimentation was made to derive some useful fluid characteristic equations of SEPARAN-NP10 (polyacylamide) expressed by n (flow behavior index) and K' (consistency index) when it is given temperature and concentration variation. To measure viscosity, capillary viscometer was adopted and the range of experimentation is 0-2,000 P.P.M. in concentration and 15-55 .deg.C in temperature. The experimental results are summarized as follows: The flow behavior index n 1) has nearly constant results irrespective of temperature variation at same conentration and the results are shown in (Table. 4-4-3) 2) has following equation, regardless of temperature, for the variation of concentration. n=-1.0765*10$^{-4}$ P+0.9915 (P:P.P.M.) The consistency index K' 1) has different results for the variation of temperature at same concentration and the results are given in (Table.4-7-2) 2) has following equation for the variation of concentration at same temperature. log 10$^{4}$K' =6.4785*10$^{-4}$ P-1.0529 (P:P.P.M)

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EFFECTS OF WATERY VAPOR CONCENTRATION ON DROPLET EVAPORATION IN HOT ENVIRONMENT

  • Lee, M.J.;Kim, Y.W.;Ha, J.Y.;Chung, S.S.
    • International Journal of Automotive Technology
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    • v.2 no.3
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    • pp.109-115
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    • 2001
  • A study has been conducted to clarify the effect of watery vapor concentration in hot ambient on droplet evaporation. Droplets of water, ethanol, n-hexadecaneand n-heptane were used in this experimental study. Ambient conditions are fixed at 470 K in temperature, 0.1 MPa in pressure and 2 m/s in velocity of ambient air. Watery vapor concentration was changed 0%~40% by 10% by add water to air. To obtain the time histories of droplet diameter after exposed in ambient, a suspended droplet in hot and humid ambient stream was synchronized with a back flash light, and enlarged droplet images were taken by a CCD camera. The evaporation rate constant of water droplet decreases slightly with the vapor concentration because diffusion velocity reduction of droplet vapor occurs on the surface. The values of ethanol and n-heptane droplet actively increase by effect that water from condensation of vapor flows into the droplet. The evaporation rate constant of n-hexadecane which has higher boiling point than water increases within around 30% of the concentration.

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