• 제목/요약/키워드: N concentration

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테들러백에서 N2O농도의 시간적 변동성 연구 (Temporal Variability of N2O Gas Concentration Collected in Tedlar Bag)

  • 홍윤정;강성민;조창상;윤현기;전의찬
    • 한국기후변화학회지
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    • 제9권1호
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    • pp.59-67
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    • 2018
  • In this study, the $N_2O$, emitted from combustion facility, were analyzed by using simulated gas and field samples to find out how long samples can be stored in Tedlar bag. According to the results of the experiment using simulated gases (1 ppm, 5 ppm, 10 ppm) in Tedlar bag, After 144hr, $N_2O$ concentration of simulated gases changed that 1 ppm is 5.3%, 5 ppm is 12.8%, and 10ppm is 10.5%. The higher initial concentration of simulated gas was, the larger rate of $N_2O$ concentration was changed. In case of high concentration samples, it need to be careful when it was analyzed after 144 hr. Stability evaluation in Tedlar bag was carried out through field samples such as combustion facility of bituminous coal, B-C oil and LNG. The concentration rate of field samples, which is under 1 ppm of average initial concentration, was evaluated using statistical method. As a result, $N_2O$ concentrations were changed to field samples in the bag even when 96 hr had passed. And after sampling, it is necessary that sample analysis should be quickly as soon as possible.

하수중의 질소.인 제거를 위한 $A^2$/O공정의 적용 (Application of $A^2$/O Process for Removal of Nitrogen and Phosphorus in Sewage)

  • 안철우;박진식;문추연
    • 한국환경보건학회지
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    • 제26권4호
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    • pp.9-14
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    • 2000
  • In this study, the removal efficiencies of organics, nitrogens and phosphorus from municipal wastewater using $A^2$/O process were investigated. BO $D_{5}$ removal efficiencies were indicated 95% and 94% with HRT of 12 hr and 10 hr, respectively. CO $D_{Cr}$ average removal efficiency and concentration of effluent were indicated 87% and 34mg/$\ell$. SS average removal efficiency and concentration of effluent were indicated 93% and 4~17mg/$\ell$. T-N removal efficiency and concentration of effluent were shown as 60~80% and below 15mg/$\ell$. In aerobic basin, removal efficiency of N $H_4$-N was shown over 97% with N $H_4$-N volume load 0.16kg N $H_4$-N/㎥.d and in anoxic basin, denitrification efficiency was indicated over 80% with return sludge rate 0.5Q and internal recirculation rate 2.5Q. Removal efficiency and effluent concentration of phosphorus were shown over 80% and below 2 mg/$\ell$ with return sludge rate 0.5Q.Q.

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아산화질소 농도 및 적용방법에 따른 생리학적 변화 (Determination of Physiological Changes according to Nitrous Concentration and Application Method)

  • 이대우;한지훈;양연미
    • 대한소아치과학회지
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    • 제43권4호
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    • pp.435-442
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    • 2016
  • 본 연구는 $N_2O/O_2$ 흡입진정을 시행하였을 때, 농도 및 투여방법에 따른 환자의 생징후 변화, 주관적인 증상 및 부작용에 대해 알아보고자 하였다. 본 연구는 흡입진정법에 대한 금기증이 없는 19 - 35세 성인 남녀 65명을 대상으로 실험조사를 진행하였다. 흡입진정법은 $N_2O$의 농도를 약 1분 간격으로 10%씩 높여주는 방법으로 적정하거나, 한 번에 $N_2O$의 농도를 원하는 수준으로 올려주는 방법을 시행하였다. 각각의 방법으로 30% 또는 50% $N_2O$ 농도에 도달되도록 하였다. 산소포화도는 $N_2O$ 농도와 투여방법에 따라서 유의성 있는 결과를 보이지 않았다. 맥박수는 한 번에 $N_2O$를 고농도로 투여하는 경우 진정법 중과 100% $O_2$ 5분 투여 후 유의성 있는 감소를 보였다. 따라서 $N_2O$ 농도는 서서히 올려주는 것이 환자 맥박수의 감소량을 줄이는 것이 안전하다.

고효율 HIT Solar Cell 제작을 위한 AFORS HET 시뮬레이션 실험 (AFORS HET Simulation for Optimization of High Efficiency HIT Solar Cell)

  • 조수현;허종규;이준신
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.450-451
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    • 2008
  • 비정질 실리콘 태양전지는 n-i-p형 구조가 일반적이며, 각 층의 두께와 도핑농도가 태양전지의 효율을 결정하는 중요한 요인이다. 최대의 효율을 얻을 수 있는 태양전지 설계를 위해 AFORS HET 시뮬레이션을 통하여 n층의 두께와 도핑농도, 그리고 p층의 도핑농도롤 변화시켰다. 최적화 결과, a-Si:H(n) 층의 두께 1nm, a-Si:H(n)층의 도핑농도 $2\times10^{20}cm^{-3}$, a-Si:H(p+)층의 도핑농도 $1\times10^{19}cm^{-3}$에서 $V_{oc}$=679.5mV, $J_{sc}$=39.02mA/$cm^2$, FF=83.71%, Efficiency=22.21%의 고효율을 얻을 수 있다. 본 연구를 통하여 실제의 높은 효율을 갖는 태양전지 설계와 제조 시에 이용할 수 있을 것이다.

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The Mg Solid Solution far the P-type Activation of GaN Thin Films Grown by Metal-Organic Chemical Vapor Deposition

  • Kim, KeungJoo;Chung, SangJo
    • Transactions on Electrical and Electronic Materials
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    • 제2권4호
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    • pp.24-29
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    • 2001
  • GaN films were grown for various Mg doping concentrations in metal-organic chemical vapor deposition. Below the Mg concentration of 10$^{19}$ ㎤, the thermally annealed sample shows the compensated phase to n-type GaN in Hall measurement. In the MB concentration of 4$\times$10$^{19}$ ㎤ corresponding to the hole carrier concentration of 2.6$\times$1$^{19}$ ㎤ there exists a photoluminescence center of the donor and the acceptor pair transition of the 3.28-eV band. This center is correlated with the defects for a shallow donor of the $V_{Ga}$ and for an acceptor of $Mg_{Ga}$ . The acceptor level shows the binding energy of 0.2-0.25 eV, which was observed by the photon energy of the photocurrent signal of 3.02-3.31 eV. Above the Mg concentration of 4$\times$10$^{19}$ ㎤, both the Mg doping level and Mg concentration were saturated and there Is a photoluminescence center of a deep donor and an acceptor pair transition of the 2.76-eV blue band.

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Determination of Critical Nitrogen Concentration and Dilution Curve for Rice Growth

  • Lee, Byun-Woo;Cui, Ri-Xian;Kim, Min-Ho;Kim, Jun-Hwan;Nam, Hong-Shik
    • 한국작물학회지
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    • 제47권2호
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    • pp.127-131
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    • 2002
  • Critical nitrogen concentration (Nc), which is defined as the minimum % N in shoots required to maintain the maximum growth rate of top dry weight (W) at any time, was determined for rice plant. Using two rice varietal groups, japonica varieties and an indica $\times$ japonica "Dasanbyeo", 18 data points fulfilling the statistical criteria for determining Nc were obtained through eight N-fertilization experiments over two years at Suwon (37$^{\circ}$16'N), Korea. Nc dilution curve for each variety was obtained by fitting the Nc-W relationship to power function. However, The critical nitrogen curves for the two variety groups were not different statistically. Thus, a Nc dilution curve was fitted for the Nc data points pooled over the two variety groups and proposed in rice as: Nc=4.08, where W<1.73 t h $a^{-1}$ , Nc=5.197 $W^{0.425}$3/ ($R^2$=0.964), where 1.73 t h $a^{-1}$ <W<12 t h $a^{-l}$. The Nc for W<1.73 t h $a^{-l}$ were estimated as a constant value of 4.08%, the mean value of the maximum N concentration for N-limiting condition and the minimum N concentration for N non-limiting condition. The model for Nc is applicable to diagnosing the nitrogen nutrition status during the rice growth period from emergence to heading stage. The Nc curve well discriminated the 144 data points between the N limiting and the N non-limiting groups regardless of varieties, cultural methods, and years.-limiting groups regardless of varieties, cultural methods, and years.

Reaction of Methylenethioxanthene with Thiyl Radical: Formation of A Vinyl Sulfide

  • Kim, Eun-Kyung;Kim, Kyong-Tae;Shin, Jung-Hyu
    • Bulletin of the Korean Chemical Society
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    • 제8권5호
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    • pp.380-384
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    • 1987
  • Reactions of methylenethioxanthene (3) with n-propanethiol in the presence of di-t-butyl peroxide(DTBP) afforded preferentially propyl 9-thioxanthenylidenemethyl sulfide(8) rather than propyl 9-thioxanthenylmethyl sulfide(9) regardless of the concentration of n-propanethiol. On the other hand reactions of 3 with a low concentration of n-propanethiol in the presence of dibenzoyl peroxide(DBPO) gave 8, 1,2-bisthioxanthenylidene ethane(11), and thioxanthenylidenemethyl benzoate(12) but only 8 was formed at high concentration of the thiol. The formations of these products were rationallized by an electron transfer mechanism.

기상 관측선 기상 1호에서 관측한 황해의 에어로졸과 구름응결핵 수농도 특성 연구 (Characteristics of Aerosol and Cloud Condensation Nuclei Concentrations Measured over the Yellow Sea on a Meteorological Research Vessel, GISANG 1)

  • 박민수;염성수;김나진;차주완;류상범
    • 대기
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    • 제26권2호
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    • pp.243-256
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    • 2016
  • Total number concentration of aerosols larger than 10 nm ($N_{CN10}$), 3 nm ($N_{CN3}$), and cloud condensation nuclei ($N_{CCN}$) were measured during four different ship cruises over the Yellow Sea. Average values of $N_{CN10}$ and $N_{CCN}$ at 0.6% supersaturation were 6914 and $3353cm^{-3}$, respectively, and the minimum value of $N_{CN10}$ was $2000cm^{-3}$, suggesting significant anthropogenic influence even at relatively clean marine environment. Although $N_{CN10}$ and $N_{CN3}$ increased near the coast due to anthropogenic influence, $N_{CCN}$ was relatively constant and therefore $N_{CCN}/N_{CN10}$ ratio tended to decrease, suggesting that coastal aerosols were relatively less hygroscopic. In general $N_{CN10}$, $N_{CN3}$, and $N_{CCN}$ during the cruises seemed to be significantly influenced by wet scavenging effects (e.g. fog) and boundary layer height variation. Only one new particle formation (NPF) event was observed during the measurement period. Interestingly, the NPF event occurred during a dust storm event and spatial scale of the NPF event was estimated to be larger than 100 km. These results demonstrate that aerosol and CCN concentration over the Yellow Sea can vary due to various different factors.

임간초지 개발에 관한 연구 XII. 차광조건하에서 질소시비수준이 계절별 , 생육시기별 목초의 질산태질소함량과 수용성탄수화물함량에 미치는 영향 (Studies on the Grassland Development in the Forest XII. Effect of nitrogen fertilization on nitrate nitrogen concentration and water soluble carbohydrate content of grasses by growing season and growth stage under shading condition)

  • 서성
    • 한국초지조사료학회지
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    • 제12권2호
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    • pp.104-110
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    • 1992
  • This experiment was carried out to determine the effects of nitrogen(N) fertilization levels(0. 120, 240 and 360 kg/ha/y) on seasonal nitrate nitrogen($NO_3$-N) concentration and water soluble carbohydrate (WSC) content of grasses grown under shading condition. The plants were sampled on 7. 14, 21, 28 and 35 days after harvesting in spring(May), summer(July) and autumn(September), 1988. respectively. Shading degree was controlled artificially ca. 45-50%, and each annual level of N was distributed 5 times equally. The $NO_3$-N concentration of grasses was very low(0.064 %) in spring, high in summer(O.l98 %) and autumn(0.234%), and NO,-N was slightly decreased with growing of grasses. Also the NO,-N concentration of grasses was increased significantly with increasing level of N. In spring, the $NO_3$-N of grasses was very safety(less than 0.1 %), regardless of plant height and N level. In summer and autumn, however, plant heights of below 40 cm(summer) and 44 cm(autumn), and N levels of over 210 kg(summer) and 140 kg(autumn) were over toxic level to animals, respectively. The WSC content of grasses was slightly decreased with grass growth. and significantly decreased with high level of N. From the above results, it is suggested that 200 kg/ha of N in this experiment is effective for forage quality. Also a little more amount of N(50-70kgltimes) in spring. and low level of N(20-30 kgltimes) in summer and autumn season may be desirable on woodland posture.

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바이오순환림의 저농도액비 시용에 따른 토양수 및 지하수 수질 영향 분석 (Effect of Low Concentration Liquid Manure application on Soil Water and Groundwater Quality in Bio-Circulation Experimental Forest)

  • 홍은미;최진용;유승환;남원호;여진기;최인규
    • 한국농공학회논문집
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    • 제52권5호
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    • pp.37-45
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    • 2010
  • Manure recycling as fertilizer is one of solutions for the environmental problem related with livestock manure treatment as well as the ocean dumping ban act prohibiting manure disposal to the ocean. For the manure disposal, forest area can be a candidate place because the area has a wide range of applicable sites. However, the manure application to the forest has a possibility of causing environmental impacts including water quality problems due to nutrient loading. Therefore it is necessary to investigate water quality impact from manure disposal to the forestry plantation. In this study, ground and soil water quality had been monitored in the bio-circulation experimental forest where low concentration liquid manure (LCLM) was applied. Soil and groundwater samples were collected and analyzed weekly from April to October in 2008 and 2009. The mean and variation of NO3-N concentration in soil water of LCLM treatment places showed higher concentration than the reference places declining during growing season. In the case of groundwater from monitoring well in the downstream of disposal site, the $NO_3$-N concentration was 3.59 mg/L in 2008 and 3.26 mg/L in 2009 in average showing higher concentration than the reference well although the concentration was not exceed the national drinking water standard. To investigate the source of nitrate, $\delta^{15}N$ isotope analysis was also implemented. Its result showed that the LCLM application could be the nitrate source requiring further long-term monitoring soil and water quality.