• Title/Summary/Keyword: N/L ratio

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Effect of Pre-NH3 Stripping on the Advanced Sewerage Treatment by BNR (BNR에 의한 하수의 고도처리에 미치는 NH3 스트리핑 전처리의 영향)

  • Seo, Jeong-Beom;An, Kwang-Ho
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.846-850
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    • 2006
  • The biological nutrient removal from domestic wastewater with low C/N ratio is difficult. Therefore, this study was performed to increase influent C/N ratio by ammonia stripping without required carbon source and for improving treatment efficiencies of sewerage by the combination process of ammonia stripping and BNR (StripBNR). The results of this study were summarized as follows. BOD removal efficiencies of BNR and StripBNR were 95.3% and 93.2%, respectively. T-N and T-P removal efficiencies of BNR were 53.3% and 40.8%, respectively. T-N and T-P removal efficiencies of StripBNR were 72.8% and 62.9%, respectively. Concentrations of $NH_3-N$, $NO_2-N$ and $NO_3-N$ at BNR effluent were 0.03 mg/L, 0.08 mg/L and 9.12 mg/L, respectively. On the other hands, concentrations of $NH_3-N$, $NO_2-N$ and $NO_3-N$ at StripBNR effluent were 5.79 mg/L, 0.01 mg/L and 0.14 mg/L, respectively. Consequently, influent C/N ratio of BNR process was increased by ammonia stripping. Removal efficiency of T-N and T-P was improved about 20% by the process of StripBNR.

A Study on Combustion Characteristics of Hybrid Rocket with the Variation of L/D Ratio (하이브리드 로켓의 L/D 비 변화에 따른 연소특성 연구)

  • Kim Soo-Jong;Kim Jin-Kon;Lee Seung-Chul;You Woo-Jun;Lee Jung-Pyo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.4
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    • pp.31-38
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    • 2005
  • In this paper, the combustion characteristics of a hybrid propulsion system were studied with various L/D(length vs diameter) ratio of the single po.1 type solid fuel. Experiments were performed for 2 cases with the fixed grain port diameter and fuel length respectively. For the first case, results show that there are no large variations for regression rates as the L/D ratio changes. And as the L/D ratio increases, the O/F ratio decreases and thrust, characteristic velocity tends to increase. For the second case, there is no large change for O/F ratio, thrust and characteristic velocity as L/D ratio changes. On the other hand, as the L/D ratio decreases, only the regression rate tends to increase. Experimentally, exponent n in $\dot{r}=a{G_0}^n$ was found about 0.5 and then the O/F ratio was shown nearly constant. In the experiment, PE and gas oxygen were used as a fuel and an oxidizer.

The Effect of Nutritional Balance between Carbon and other Nutrient Sources on the Growth of Sporobolomyces holsaticus (탄소원과 다른 영양원간의 영양균형이 Sporobolomyces holsaticus의 균체생육도에 미치는 영향)

  • Park, Wan-Soo;Koo, Young-Jo;Shin, Dong-Hwa;Min, Byung-Yong
    • Korean Journal of Food Science and Technology
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    • v.15 no.1
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    • pp.56-61
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    • 1983
  • Direct production of biomass from starch using amylolytic yeast, Sporobolomyces holsaticus FRI Y-5 was studied with varying the ratios between carbon and other nutrient sources in the medium. It was investigated under condition of constant C/P and C/S ratio to influence the initial concentration of starch $(S_o)$ and C/N ratio on its growth which is described as the specific growth rate $({\mu})$, cell yield (Y), the maximum concentration of cell $(X_m)$, and productivity (P). They were very dependent on both $S_o$ and C/N ratio. The form of the relationship between and ${\mu}$ and $S_o$ was observed to be similar to saturation kinetics at C/N = 100 but presented substrate inhibition at other C/N ratios. As $S_o$ was changed from 22.5 to 90 g/l, Y was observed to vary with C/N ratios but seemed to decrease as a wholes. $X_m$ was linearly related to $S_o$ at more than C/N = 50 but at less than C/N = 10 substrate inhibition was presented. P increased suddenly to $S_o$ = 45 g/l and then changed decreasingly at less than C/N = 50, but at more than C/N = 100 it changed increasingly. The effect of C/P ratio and C/S ratio on the yeast growth was also investigated at constant $S_o$ and C/N ratio. ${\mu}$ was dependent on C/P and C/S ratios, but Y, independent on them. But $X_m$ was reliant upon C/P ratio but not upon C/S ratio.

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Enhancement of Denitrification Capacity of Pseudomonas sp. KY1 through the Optimization of C/N ratio of Liquid Molasses and Nitrate (액상 당밀과 질산성 질소의 C/N 비율에 따른 Pseudomonas sp. KY1의 탈질 능력 및 그 최적비율에 관한 연구)

  • Lee, Kyuyeon;Lee, Byung Sun;Shin, Doyun;Choi, Yongju;Nam, Kyoungphile
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.9
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    • pp.654-659
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    • 2013
  • This study was conducted to identify an optimal ratio of carbon to nitrogen (C/N ratio) for denitrification of nitrate using molasses as an external carbon source. A series of batch and column tests was conducted using an indigenous bacterium Pseudomonas sp. KY1 isolated from a nitrate-contaminated soil. For the initial nitrate-nitrogen concentration of 100 mg-N/L, batch test results indicated that C/N ratio of 3/1 was the optimal ratio with a relatively high pseudo-first-order reaction constant of $0.0263hr^{-1}$. At C/N ratio of 3/1, more than 80% of nitrate-nitrogen concentration of 100 mg-N/L was removed in 100 hrs. Results of column tests with a flow velocity of 0.3 mL/min also indicated that the C/N ratio of 3/1 was optimal for denitrification with minimizing remaining molasses concentrations. After 172 hrs of column operation (35 pore volumes) with an influent nitrate-nitrogen concentration of 100 mg-N/L, the effluent met the drinking water standard (i.e., 10 mg $NO_3$-N/L).

Relationship Between C/N Ratio and Nitrogen Removal in Intermittently Aerated Activated Sludge System (간헐폭기 활성슬러지공정에서 C/N비와 질소제거의 관계)

  • 서인석;김병군;이상일
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.57-65
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    • 1998
  • In this research, Effect of C/N ratio on nutrient removal in intermittently aerated activated sludge system(IAASS) was investigated with dormitary, building and swine wastewater. Three types (2-stage, 4-stage, modified) of IAASS were operated. Time interval of aeration/nonaeration in IAASS was 1hr/1hr. In treatment of Dormitary wastewater(BOD/T-N ratio : 4.4), Building wastewater (BOD/T-N ratio : 3.14) and swine wastewater(BOD/T-N ratio : 3.84), Nitrogen removal efficiency of 80, 70 and 90.4% was achieved, respectively. Nitrogen removal in IAASS was a great influenced on influent C/N ratio, efficient nitrogen removal was achieved at BOD/T-N ratio over 4. In IAASS operation, $\Delta $BOD mg/L/$\Delta $ nitrogen mg/L ratio was about 4-6. Simultaneous removal of organic, nitrogen and phosphorus in IAASS can achieved. And influent organic was efficiently utilized in denitrification. IAASS could be one of the best alternative process for the retrofit of conventional activated sludge system for the removal of nutrients.

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Nitrogen Mineralization of Cereal Straws and Vetch in Paddy Soil by Test Tube Analysis

  • Cho, Young-Son;Lee, Byong-Zhin;Choe, Zhin-Ryong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.2
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    • pp.102-105
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    • 1999
  • Mineralization of organic N is an important factor in determining the appropriate rate of organic matter application to paddy fields. A kinetic analysis was conducted for nitrogen mineralization of rice, barley, Chinese milk Ovetch (Astragalus sinicus L.; MV) and narrow leaf vetch straw in paddy soil. Nitrogen immobilization occurred rapidly and its rate increased in straw with high C/N ratio. The amount of nitrogen mineralization was rapid in the first year of rice-vetch cropping system. The rate constant (K) depended on the C/N ratio of organic matter. Mineralization of straw increased at high temperature. The amount of available N increment resulted in fast mineralization of straw, especially in rice and barley straw. Chinese milk vetch had the greatest mineralization rate at all temperatures and fertilization levels followed by narrow-leaf vetch. However, rice and barley straws with high C/N ratio immobilized the soil N at the initial incubation duration. Chinese milk vetch or narrow leaf vetch was not effectively mineralized in mixed treatments with rice or barley straw. The mineralization rate of organic matter was mostly affected by the C/N ratio of straw and temperature of incubation. Organic matter with low C/N ratio should be recommended to avoid the immobilization of soil N and the increasing mineralization rate of straw.

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Copolymerization of Ethylene and Cycloolefin with Metallocene Catalyst: I. Effect of Catalyst (메탈로센 촉매를 애용한 에틸렌과 시클로올레핀의 공중합 : I. 촉매의 영향)

  • 이동호;정희경;김우식;민경은;박이순
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.445-452
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    • 2000
  • The copolymerization of ethylene (E) and norbornene (N) was examined by using various metallocene catalysts and modified-MAO(MMAO) cocatalyst. For $C_2$-symmetry catalysts such as rac-Et(Ind)$_2$ZrC $l_2$, M $e_2$Si(Ind)$_2$ZrC $l_2$, M $e_2$Si(Cp)$_2$ZrC $l_2$ and Cs-symmetrical iPr(FluCp)ZrC $l_2$ as well as CGC and di-bridged zirconocene, the effects of catalyst structure and [N]/[E] feed ratio on catalyst activity, thermal property and [N] content of copolymer (COC) was investigated. For rac-Et(Ind)$_2$ZrC $l_2$ catalyst of a constant [N]/[E] feed ratio, the appropriate conditions of [Al]/[Zr] mole ratio, polymerization temperature and cocatalyst structure were found to be 3000, 4$0^{\circ}C$, MMAO cocatalyst, respectively. As [N]/[E] feed ratio increased, the incorporation of norbornene to copolymer increased while, the activity of catalyst decreased except for iPr(FluCp)ZrC $l_2$ With consideration of catalyst activity as well as N content, it was found that rac-Et(Ind)$_2$ZrC $l_2$/MMAO system exhibited relatively high activity and controllable $T_{g}$. Monomer reactivity ratio was determined by Kelen-Tudos method..

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Annual Change and C:N:P ratio in Particulate Organic Matter in Chinhae Bay, Korea (한국진해만 입자유기물 함량과 C:N:P 비의 연변화)

  • LEE, PIL-YONG;KANG, CHANG-KEUN;PARK, JONG-SOO;PARK, JOO-SUCK
    • 한국해양학회지
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    • v.29 no.2
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    • pp.107-118
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    • 1994
  • An investigation of the annual change and C:N:P ratio in particulate organic matter (POM) in Chinhae Bay, a semi-enclosed bay of the southern coast of Korean Peninsula, was carried out for a period of 12 months between January and December, 1993. The concentrations of POM have a broad range: 198∼4,416 ugC/l, 24∼792 ugN/l and 4.5∼69.0 ugP/l, Marked seasonal changes of POM, particularly particulate organic carbon (POC) and nitrogen (PON), were observed in the surface water. Generally, the concentration of POM peaks in summer. The C:N:P composition ratio of particulate organic matter, which is high in summer, also shows a seasonal change. The C:N assimilation ratio is constant at 6.53, which is consistent with the Redfield ratio. The significant linear relationship between POM and chlorophyll-a in the surface water during the survey period (except for January and February) and the C:N ratio suggest that the concentration of POM is controlled by phytoplankton biomass. POM peaks in summer, a period characterized by high freshwater input and the strong stratification, as a result of the intense proliferation of phytoplankton by a large amount of nutrient loading from the tributaries. On the other hand, the high C:P and N:P ratios in summer indicate that P is limited for phytoplankton growth owing to N-enrichment from a high input of freshwater with a high dissolved inorganic N:P ratio.

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N,N'-Dimethylethylenediamine-N,N'-di-α-butyric Acid Cobalt(III) Complexes Utilizing Oxidation of Sulfur of S-Methyl-L-cysteine

  • Kim, Hyun-Jin;Youm, Kyoung-Tae;Yang, Jung-Sung;Jun, Moo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.851-856
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    • 2002
  • The Reaction of S-methyl-S-cysteine(L-Smc) with racemic $s-cis-[Co(demba)Cl_2]-1$ (Hydmedba = $NN'-dimethylethylenediamine-NN'-di-\alpha-butyric$, acid) yields ${\Delta}$-s-cis-[Co(dmedba)(L-Smc)] 2 with N, O-chelation. Oxidation of sulfur of 2 with $H_2O_2$ in a 1 : 1 mole ratio gives ${\Delta}$-s-cis[Co(dmedba)(L-S(O)mc)] 3 having an uncoordinated sulfenate group. Oxidation of sulfur of L-Sm with $H_2O_2in$ a 1: 1 mole ratio produces S-methyl-L-cysteinesulfenate (L-S(O)me) 5. Direct reaction of 1 with 5 in basic medium gives an N.O-chelated ${\Delta}$s-cis[Co(dmedba)(L-S(O)mc)-N.O], which turmed out be same as obtained by oxidation of 2, while an N, S-chelated ${\Delta}$-s-cis-[Co(dmedba)(S-S(O)mc)-N,O] complex 4 is obtained in acidic medium from the reaction of 1 with 5. This is one of the rare $[$Co^{III}$(N_2O_2-type$ ligand)(amino acid)] type complex preparations, where the reaction conditions determine which mode of N, O and N, S caelation modes is favored.

Pseudomonas oleovorans의 유가식 배양에 의한 medium chain length Polyhydroxyalkanoates (MCL-PHA) 생산

  • Kim, Beom-Su;Im, Hui-Yeon
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.207-210
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    • 2000
  • Pseudomonas oleovorans was cultivated to produce medium chain length polyhydroxyalkanoates (MCL-PHA) fram octanoic acid and ammonium nitrate as carbon and nitrogen source, respectively, by a pH-stat fed-batch culture technique. The octanoate concentration of the culture broth was maintained below 4 g/L by feeding the mixture of octanoic acid and ammonium nitrate when the culture pH rose above high limit. The effect of the ratio of octanoic acid to ammonium nitrate (C/N ratio) in the feed on the PHA production was examined. The final cell concentrations of 62.5, 54.7, and 9.5 g/L, PHA contents of 62.9, 75.1, and 67.6% of dry cell weight, and productivities of 1.03, 0.632, and 0.161 g/L/h were obtained when the C/N ratio in the feed were 10, 20, and 100 g octanoic acid/g ammonium nitrate, respectively.

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