• Title/Summary/Keyword: Multicomponent

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Properties of the metallic glass thin films fabricated by multicomponent single alloying target and its applications in various industrial fields

  • Shin, S.Y.;Moon, K.I.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.77-77
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    • 2015
  • Metallic glass alloys having dense packing structure have short range ordered structure with long range homogeneity. Therefore, they can provide complete corrosion protection and unique electrical properties. Recently, metallic glass thin films have received much attention to extend its application fields combining with PVC coating technologies. The metallic glass thin films can change the surface properties of the conventional bulk materials which need anticorrosion properties. However, multi-component alloying targets are required to fabricate the metallic glass thin films because metallic glass alloys contain more than three elements. Recently, many researchers have been reported the properties of the metallic glass thin films synthesized with multi-cathode systems or amorphous target. But, it is difficult to fabricate the large sized sputtering targets for mass production equipment with high toughness and thermal stability. In this study, newly developed sputtering target with glass forming ability and the properties of the metallic glass thin films will be introduced with respect to the various application fields such as bipolar plate in PEM fuel cell and decorative coatings for electric device and construction fields.

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Numerical analysis of NOx formation characteristics in CH$_{4}$-air jet diffusion flame (CH$_{4}$-공기 분류 확산화염의 NOx 생성특성에 관한 수치해석)

  • O, Chang-Bo;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.2
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    • pp.193-204
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    • 1998
  • Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

Fabrication of Multicomponent Protein Microarrays with Microfluidic Devices of Poly(dimethylsiloxane)

  • Jeon, Se-Hoon;Kim, Ui-Seong;Jeon, Won-Jin;Shin, Chee-Burm;Hong, Su-Rin;Choi, In-Hee;Lee, Su-Seung;Yi, Jong-Heop
    • Macromolecular Research
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    • v.17 no.3
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    • pp.192-196
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    • 2009
  • Recently, the multi-screening of target materials has been made possible by the development of the surface plasmon resonance (SPR) imaging method. To adapt this method to biochemical analysis, the multi-patterning technology of protein microarrays is required. Among the different methods of fabricating protein microarrays, the microfluidic platform was selected due to its various advantages over other techniques. Microfluidic devices were designed and fabricated with polydimethylsiloxane (PDMS) by the replica molding method. These devices were designed to operate using only capillary force, without the need for additional flow control equipment. With these devices, multiple protein-patterned sensor surfaces were made, to support the two-dimensional detection of various protein-protein interactions with SPR. The fabrication technique of protein microarrays can be applied not only to SPR imaging, but also to other biochemical analyses.

First-Principles Calculations for Design of Efficient Electrocatalysts (제일원리 계산을 활용한 전기화학 촉매 연구)

  • Kim, Dong Yeon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.6
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    • pp.393-400
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    • 2021
  • As the recent climate problems are getting worse year after year, the demands for clean energy materials have highly increased in modern society. However, the candidate material classes for clean energy expand rapidly and the outcomes are too complex to be interpreted at laboratory scale (e.g., multicomponent materials). In order to overcome these issues, the first-principles calculations are becoming attractive in the field of material science. The calculations can be performed rapidly using virtual environments without physical limitations in a vast candidate pool, and theory can address the origin of activity through the calculations of electronic structure of materials, even if the structure of material is too complex. Therefore, in terms of the latest trends, we report academic progress related to the first-principles calculations for design of efficient electrocatalysts. The basic background for theory and specific research examples are reported together with the perspective on the design of novel materials using first-principles calculations.

An adaptive approach for the chloride diffusivity of cement-based materials

  • Tran, Bao-Viet;Pham, Duc-Chinh;Loc, Mai-Dinh;Le, Minh-Cuong
    • Computers and Concrete
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    • v.23 no.2
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    • pp.145-153
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    • 2019
  • Adaptive schemes are constructed in this paper for modeling the effective chloride diffusion coefficient of cement-based materials (paste and concrete). Based on the polarization approximations for the effective conductivity of isotropic multicomponent materials, we develop some fitting procedures to include more information about the materials, to improve the accuracy of the scheme. The variable reference parameter of the approximation involves a few free scalars, which are determined through the available numerical or experimental values of the macroscopic chloride diffusion coefficient of cement paste or concrete at some volume proportions of the component materials. The various factors that affect the chloride diffusivity of cement-based material (porous material structure, uncertainty of value of the chloride diffusion coefficient in water-saturated pore spaces, etc.) may be accounted to make the predictions more accurate. Illustrations of applications are provided in a number of examples to show the usefulness of the approach.

Pressure Swing Adsorption Based Hydrogen Purification Vessel 3D Modeling and Feasibility Study (Pressure Swing Adsorption 기반 수소정제용기 3차원 모델링 및 타당성 검증 연구)

  • CHA, YOHAN;CHOI, JAEYOO;JU, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.4
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    • pp.197-204
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    • 2021
  • Pressure swing adsorption is a purification process which can get pure hydrogen. The purification process is composed of four process: compression, adsorption, desorption and discharge. In this study the adsorption process was simulated by using the Fluent and validated with experimental results. A gas used in experiment is composed of H2, CO2, CH4, and CO. Adsorption process conducted under 313 kelvin and 3 bar and bituminous-coal-based (BPL) activated carbon was used as the adsorbent. Langmuir model was applied to explain the gas adsorption. And diffusion of all the gases was controlled by micro-pore resistances. The result shows that, the most adsorbed gas was carbon dioxide, followed by methane and carbon monoxide. And carbon monoxide took the least amount of time to reach the maximum adsorption amount. The molar fraction of the off-gas became the same as the molar fraction of the gas supplied from the inlet after adsorption reached the equilibrium.

A Study on the Counseling Practice for Obesity in Korean Medicine Clinics and the Satisfaction for Counseling Manual for the Standardized Management of Obesity in Korean Medicine (한의 일차의료기관에서 한의 비만 상담 표준매뉴얼을 활용한 한의 비만 상담 내용 분석 및 사용자 만족도에 관한 연구)

  • Han, Kyungsun;Kim, Sungha
    • Journal of Korean Medicine for Obesity Research
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    • v.20 no.2
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    • pp.131-137
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    • 2020
  • Objectives: Korean Medicine Doctors (KMDs) have treated patients with obesity using a holistic approach with a multicomponent approach on counseling. However, there is currently no data regarding KMDs' counseling practices for weight loss. We conducted a retrospective chart review to better understand the Korean medicine counseling practice for weight loss. Methods: Twenty-one KMDs were involved in this project as practitioners. The contents of counseling were categorized based on patterns according to the counseling manual for the standardized management of obesity in Korean Medicine. Results: The counseling was conducted based on the theory of Korean medicine and the contents of counseling were different from patterns. However, the quality of the counseling were different from each KMD, and the counseling were focused on evaluating patient conditions and not on providing specific recommendations for lifestyle changes. Conclusions: Therefore, specific guidance of counseling for healthier lifestyle and dietary habits, and the training of the standardized manual training are needed.

Synthesis, Docking Study and In-vitro Evaluation of Anti-Tuberculosis Activity of Tri Substituted Imidazoles Containing Quinoline Moiety

  • Sahana, S.;Vijayakumar, G.R.;Sivakumar, R.;Sriram, D.;Saiprasad, D.V.
    • Journal of the Korean Chemical Society
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    • v.66 no.3
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    • pp.194-201
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    • 2022
  • A simple, efficient, and cost-effective method has been employed for the synthesis of 2,4,5-trisubstituted imidazole derivatives (3a-j) containing quinoline substituent at 2nd position. Title compounds were obtained by multicomponent reaction (MCR), involving aryl substituted 1,2-diketone, quinoline carbaldehyde and ammonium acetate in the presence of acetic acid solvent under mild reaction conditions. The newly synthesized quinoline containing imidazole derivatives were confirmed through FT-IR, 1H-NMR, 13C-NMR and mass spectral analysis. In-vitro microplate alamar blue assay (MABA) to determine the MIC (minimum inhibitory concentration) values against Mycobacterium tuberculosis H37Rv was performed for the synthesized compounds. The synthesized compounds exhibited activity against Mycobacterium tuberculosis and among which compounds, 3d, 3f and 3i showed good activity. The highest activity was showed with compound 3i. The anti-mycobacterial activity results are well correlated with the computational molecular docking analysis, which was performed for the synthesized compounds prior to the evaluation of the activity.

Reactive Transport Modeling for Investigating Elemental Cycling at the Groundwater-Surface Water Interface (지하수-지표수 물질순환 평가를 위한 반응성 운송 모형 연구)

  • Heewon Jung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.16-16
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    • 2023
  • 기후변화로 인한 가뭄, 홍수, 녹조 등 이상기후 현상들이 본격화함에 따라 안정적인 수자원 관리의 필요성이 증가하고 있다. 특히 급변하는 환경조건 속에서도 안정적인 수자원 확보를 가능하게 하는 지하수 자원의 적극적인 활용은 기후변화대응에 있어 핵심적인 요소이다. 지하수는 하천, 호수 연안지역 등 다양한 지표의 수문환경과 연결되어 천층지권의 수문생태적 특성을 결정하기 때문에, 지속가능한 수자원 활용을 위해서는 지하수와 지표수의 상호작용에 대한 통합적인 검토가 이루어져야 한다. 하지만 긴밀하게 연계된 특성에도 불구하고 지하수와 지표수에 대한 연구는 오랜기간 개별수문환경에 대해 독립적으로 수행되어왔다. 이러한 연구경향은 저류시간이 크게 다른 지하수와 지표수의 수문적 특성뿐 아니라 개별수문환경에서 나타나는 작용들을 통합적으로 다룰 수 있는 모델의 부제에도 기인한다. 최근 비약적인 연산능력의 향상과 함께 지하수-지표수 환경을 연계한 통합수문모델(Integrated Hydrology Model)의 개발 및 활용이 이루어짐에 따라 기후변화 및 수자원 활용에 따른 수문환경변화 대한 통합적인 연구 시도가 이루어지고 있다. 본 발표에서는 최근의 통합수문모델과 다중요소 반응성 운송 모형(Multicomponent Reactive Transport Model)의 연계를 통한 물질순환 연구의 최신 동향을 소개하고(농도-유량 상관관계, 지표수계의 화학적 풍화와 이산화탄소 저감, 녹조 등), 데이터 기반 모형을 통한 통합수문모델의 연산 효율 및 정확성 향상을 위한 방법에 대해 모색하고자 한다.

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Molybdenum isotopes separation using squared-off optimized cascades

  • Mahdi Aghaie;Valiyollah Ghazanfari
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3291-3300
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    • 2023
  • Recently molybdenum alloys have been introduced as accident tolerating materials for cladding of fuel rods. Molybdenum element has seven stable isotopes with different neutron absorption cross section used in various fields, including nuclear physics and radioisotope production. This study presents separation approaches for all intermediate isotopes of molybdenum element by squared-off cascades using a newly developed numerical code with Salp Swarm Algorithm (SSA) optimization algorithm. The parameters of cascade including feed flow rate, feed entry stage, cascade cut, input feed flow rate to gas centrifuges (GCs), and cut of the first stage are optimized to maximize both isotope recovery and cascade capacity. The squared off and squared cascades are studied, and the efficiencies are compared. The results obtained from the optimization showed that for the selected squared off cascade, Mo94 in four separation steps, Mo95 in five steps, Mo96 in six steps, Mo97 in seven steps, and Mo98 in two steps are separated to the desired concentrations. The highest recovery factor is obtained 63% for Mo94 separation and lowest recovery factor is found 45% for Mo95.