• 한국수소및신에너지학회논문집
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• 제13권3호
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• pp.181-189
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• 2002

A series of multicomponent $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{1-x}Fe_{x}$ (x=0.00, 0.08, 0.15, 0.22, and 0.30) alloys are prepared and their oystal structure and P-C-T curves are examined. The electrochemical properties of these allqys such as activation conditions, discharge capacity, cycling performance are also investigated. $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{1-x}Fe_{x}$ (x=0.00, 0.08, 0.15, 0.22 and 0.30) have the C14 Laves phase hexagonal structure. The electrode was activated by the hot-charging treatment. The best activation conditions were the current density 120 mA/g and the hot-charging time 12h at $80^{\circ}C$ in the case of the alloy with x=0.00. The discharge capacity increased rapidly until the fourth cycle and then decreased. The discharge capacity increased again from the 13th cycle, arriving at 234 mAh/g at the 50th cycle. The discharge capacily just after activation decreases with the increase in the amount of the substituted Fe but the cycling performance is improved. The discharge capacity after activation of the alloy with x=0.00 is 157 mAh/g at the current density 120 mA/g. $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}Fe_{0.15}$ is a good composition with a medium quantity of discharge capacities and a good cycling performance. The ICP analysis of the electrolyte for these electrodes after 50 charge-discharge cycles shows that the concentrations of V and Zr are relatively high. Another series of multicomponent $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}M_{0.15}$ (M = Fe, Co, Cu, Mo and Al) alloys are prepared. They also have the C14 Laves phase hexagonal structure. The alloys with M = Co and Fe have relatively larger hydrogen storage capacities. The discharge capacities just after activation are relatively large in the case of the alloys with M = Al and Cu. They are 212 and 170 mAh/g, respectivety, at the current density 120mA/g. The $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}Co_{0.15}$ alloy is the best one with a relatively large discharge capacity and a good cycling performance.

• Nuclear Engineering and Technology
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• 제27권3호
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• pp.301-316
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• 1995

아래를 향한 가열 수평 평판이 있는 수조에서의 자연대류 현상을 규명하기 위한 실험적, 해석적인 연구를 수행하였다. 이는 압력용기 하부에 용융물이 있을때 캐비티내에서의 열수력현상을 규명하기 위한 간단화된 모델에 관한 연구이다. 압력 용기는 하부에 가열평판이 부착된 직육면체 단열 상자로 모의하고 이 상자는 물이 차 있는 수조에 설치된다. 냉각기는 정상상태의 유동 조건을 만들기 위해 상자와 수조사이의 U자 형태의 유동 영역에 설치된다. 실제 압력용기 하부에서는 다상 유동이 발생할 확율이 크나본 연구는 복잡한 다상 유동의 열수력 현상을 규명하기 위한 첫 단계 시도로서 단상유체를 사용한 실험 및 해석 연구이다. 본 연구에서는 가열 평판 아래에서의 자연대류현상특성을 더욱 잘 이해하기 위해 LDV와 열전대를 사용하여 속도와 온도를 측정하였다. 또한 입자가 부상된 유동장을 사진 찍어 유동을 가시화 하였다. 실험결과는 다음과 같다. 유체는 가열판과 냉각기가 작동할 때 매우 효과적으로 전 유동장에 걸쳐 순환한다. 가열판 하부에서 유동이 정체된 영역이 있고 매우 얇은 열 경계층을 갖는 두드러진 온도의 성층현상이 관찰되었다. FLUTAN Code를 이용한 해석은 속도를 합리 적으로 예측할 수 있다는 결과를 보여 주었다.

• 지구물리와물리탐사
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• 제12권3호
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• pp.246-254
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• 2009

균질매질과 자유면 경계에서 선형입자운동을 하는 파를 타원형 입자운동을 하는 파로부터 분리하기 위한 새로운 분극필터를 다성분 복소트레이스 분석법에 근거하여 개발하였다. 균질매질에서의 입자운동을 모사한 합성파를 통해 이 필터의 성능을 검증한 결과, P파와 레일리파의 수평성분/수직성분 진폭비 $C_L$과 $C_R$를 알고 있을 경우, 이 분극필터는 레일리파 성분을 완벽하게 제거하여 이상적인 결과를 보인다. 이 분극필터 결과의 수직성분 오차는 $C_R$/$C_L$에 따라 증가하고, 수평성분 오차는 $C_R$ $C_L$에 따라 증가한다. 특히 수직성분 오차는 $C_L$과 $C_R$의 적용값/모델값 비율($C_L'$/$C_L$와 $C_R'$/$C_R$)이 작을 때 급격히 증가하며, 입사각이 작을 때는 $C_R'$/$C_R$에, 클 때는 $C_L'$/$C_L$에 각각 민감하다. S파와 레일리파가 중첩되어 있는 경우는, 입사각이 P파 입사각의 보각인 경우와 동일하다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.200-200
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• 2010

In recent times, metal oxide semiconductors thin films transistor (TFT), such as zinc and indium based oxide TFTs, have attracted considerable attention because of their several advantageous electrical and optical properties. There are many deposition methods for fabrication of ZnO-based materials such as chemical vapor deposition, RF/DC sputtering and pulsed laser deposition. However, these vacuum process require expensive equipment and result in high manufacturing costs. Also, the methods is difficult to fabricate various multicomponent oxide semiconductor. Recently, several groups report solution processed metal oxide TFTs for low cost and non vacuum process. In this study, we have newly developed solution-processed TFTs based on Ti-related multi-component transparent oxide, i. e., InTiO as the active layer. We propose new multicomponent oxide, Titanium indium oxide(TiInO), to fabricate the high performance TFT through the sol-gel method. We investigated the influence of relative compositions of Ti on the electrical properties. Indium nitrate hydrate [$In(NO^3).xH_2O$] and Titanium isobutoxide [$C_{16}H_{36}O_4Ti$] were dissolved in acetylacetone. Then monoethanolamine (MEA) and acetic acid ($CH_3COOH$) were added to the solution. The molar concentration of indium was kept as 0.1 mol concentration and the amount of Ti was varied according to weighting percent (0, 5, 10%). The complex solutions become clear and homogeneous after stirring for 24 hours. Heavily boron (p+) doped Si wafer with 100nm thermally grown $SiO_2$ serve as the gate and gate dielectric of the TFT, respectively. TiInO thin films were deposited using the sol-gel solution by the spin-coating method. After coating, the films annealed in a tube furnace at $500^{\circ}C$ for 1hour under oxygen ambient. The 5% Ti-doped InO TFT had a field-effect mobility $1.15cm^2/V{\cdot}S$, a threshold voltage of 4.73 V, an on/off current ratio grater than $10^7$, and a subthreshold slop of 0.49 V/dec. The 10% Ti-doped InO TFT had a field-effect mobility $1.03\;cm^2/V{\cdot}S$, a threshold voltage of 1.87 V, an on/off current ration grater than $10^7$, and a subthreshold slop of 0.67 V/dec.

• 한국컴퓨터정보학회논문지
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• 제28권12호
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• pp.155-166
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• 2023

이 연구는 치매안심센터 인지재활 프로그램의 현황 및 실태분석을 통한 활성화 방안과 다차원적 치료레크리에이션 프로그램에 대한 개발방향과 내용을 도출하고자 D시의 치매안심센타 인지재활 치료프로그램 참여 노인 각 50명씩(5개구)을 선정하였고, 9명을 전문가 집단 의견수렴 대상으로 선정하였다. 수집된 자료는 SPSS ver. 18.0 통계 프로그램을 이용하여 기술통계와 구성요소별 중요도 및 우선순위는 계층구조분석을 시행함으로써, 첫째, 현재 제공되고 있는 인지재활 지원 프로그램은 이용자의 요구와는 달리 지원프로그램이 충분하지 않아 경험이 상당히 낮게 나타났으며, 이에 대한 개선점으로는 돌봄이나 보호시설 확대와 이용자의 요구를 충족할 다양한 프로그램 개발이 중요하다고 나타났고, 둘째, 치료레크리에이션 구성요소별 중요도와 우선순위는 대분류(6개) 운동요법, 중분류(16개) 운동요법의 행동중심 접근법, 소분류(47개) 힘뇌체조, 실버건강체조가 가장 높게 나타났다. 이는 치료레크리에이션 프로그램 개발시 각 영역의 우선순위를 고려한 다차원적 프로그램 계획이 이루어져야 함을 보여주는 결과라 할 수 있다.

• Molecules and Cells
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• 제43권11호
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• pp.899-908
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• 2020

Intrinsically disordered proteins or regions (IDPs or IDRs) are widespread in the eukaryotic proteome. Although lacking stable three-dimensional structures in the free forms, IDRs perform critical functions in various cellular processes. Accordingly, mutations and altered expression of IDRs are associated with many pathological conditions. Hence, it is of great importance to understand at the molecular level how IDRs interact with their binding partners. In particular, discovering the unique interaction features of IDRs originating from their dynamic nature may reveal uncharted regulatory mechanisms of specific biological processes. Here we discuss the mechanisms of the macromolecular interactions mediated by IDRs and present the relevant cellular processes including transcription, cell cycle progression, signaling, and nucleocytoplasmic transport. Of special interest is the multivalent binding nature of IDRs driving assembly of multicomponent macromolecular complexes. Integrating the previous theoretical and experimental investigations, we suggest that such IDR-driven multiprotein complexes can function as versatile allosteric switches to process diverse cellular signals. Finally, we discuss the future challenges and potential medical applications of the IDR research.

• 대한화학회지
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• 제61권4호
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• pp.157-162
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• 2017

In the present study, nanocrystalline mixed metal oxide, $CuMnO_3$ catalyst have been synthesized by mechanochemical method with green chemistry approach. The synthesized catalyst was characterized by analytical techniques including FTIR, XRD, SEM, TEM and BET surface area. The synthesized catalyst shows high surface area is $121.06m^2/g$ with particle size 18 nm. The one pot four component synthesis of substituted 2-phenyl-4(3H) quinazolinone from the reaction of anthranilic acid, benzoyl chloride, hydrazine hydrate and substituted benzaldehyde in presence of $CuMnO_3$ nanocatalyst has been carried out. It affords the corresponding products with high yield (76-95%) in very short reaction time. All the obtained products were characterized with $^1HNMR$, $^{13}CNMR$, FTIR and EIMS.

• Applied Microscopy
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• 제45권1호
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• pp.32-36
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• 2015

The microstructural features of FeCoCrNi, FeCoCrNiAl and FeCoCrNiSix (x=0, 5, 10, 15, 20) alloys have been investigated in the present study. The microstructure of FeCoCrNi alloy changes dramatically with equiatomic addition of Al. The fcc irregular shaped grain structure in the as-cast FeCoCrNi alloy changes into the bcc interconnected structure with phase separation of Al-Ni rich and Cr-Fe rich phases in the as-cast FeCoCrNiAl alloy. The microstructure of FeCoCrNi alloy changes with the addition of Si. With increasing the amount of Si, the fcc structure of the grains is maintained, but new phase containing higher amount of Si forms at the grain boundary. As the amount of Si increases, the fraction the Si-rich grain boundary phase increases.

• 한국물환경학회지
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• 제16권4호
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• pp.555-563
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• 2000

The study was conducted to evaluate the adsorption equilibrium of heavy metals on bone charcoal made of livestock bone which was sintered at $550{\sim}600^{\circ}C$. Analysis of bone charcoal by XRD and FT-IR showed that crystal structure was similar to that of synthetic hydroxyapatite. Adsorption equilibrium capacity of single component (Pb, Cd, and Zn) on bone charcoal could be expressed as Langmuir, Freundlich, and Sips equations. Sips isotherm was best among the three isotherms. The values predicted by IAST(ideal adsorbed solution theory) showed good relationship to the experimental data in multicomponent adsorption equilibrium. Adsorption affinity was in order of Pb, Cd, and Zn. The order was same in case of activated carbon or synthetic hydroxyapatite. Through the study results. it would be expected that bone charcoal made of livestock could be used in field of wastewater treatment plants as adsorbent to remove heavy metal.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2001년도 추계학술대회 논문집
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• pp.272-276
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• 2001

Multicomponent $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk matallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state.1) In this study, DSC and X-ray diffractometry have been performed to confirm the amorphous structure of the master $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy. To investigate the mechanical properties and deformation behaviors of the bulk metallic $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$ and at the various initial strain rates from $2{\times}10^{-4}s^{-1}\;to\;2{\times}10^{-2}s^{-1}$. There are two types of nominal stress-strain curves. The one shows linear stress-strain relationship meaning fracture at maximum stress, the other shows plastic deformation including steady-state flow. Also DSC analysis for the compressed specimens has been performed to investigate the change of thermal stability and crystallization behavior for the various test conditions.