• Title/Summary/Keyword: Multi-layer coating structure

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Failure and Phase Transformation Mechanism of Multi-Layered Nitride Coating for Liquid Metal Injection Casting Mold

  • Jeon, Changwoo;Lee, Juho;Park, Eun Soo
    • Korean Journal of Materials Research
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    • v.31 no.6
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    • pp.331-338
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    • 2021
  • Ti-Al-Si target and Cr-Si target are sputtered alternately to develop a multi-layered nitride coating on a steel mold to improve die-casting lifetime. Prior to the multi-layer deposition, a CrN layer is developed as a buffer layer on the mold to suppress the diffusion of reactive elements and enhance the cohesive strength of the multi-layer deposition. Approximately 50 nm CrSiN and TiAlSiN layers are deposited layer by layer, and form about three ㎛-thickness of multi-layered coating. From the observation of the uncoated and coated steel molds after the acceleration experiment of liquid metal injection casting, the uncoated mold is severely eroded by the adhesion of molten metallic glass. On the other hand, the multi-layer coating on the mold prevents element diffusion from the metallic glass and mold erosion during the experiment. The multi-layer structure of the coating transforms the nano-composite structured coating during the acceleration test. Since the nano-composite structure disrupts element diffusion to molten metallic glass, despite microstructure changes, the coating is not eroded by the 1,050 ℃ molten metallic glass.

A Study on the Improvement of Multi-Layer Coating Method on Concrete Base (성형 콘크리트 복층마감도장 공법 개선에 관한 연구)

  • Kim, Chong-Weon;Choi, In-Sung
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.1
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    • pp.93-105
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    • 2003
  • The Precast Concrete(PC) method was developed for a large production of a structure in Europe. Afterwards, this PC method has been applied to a structure and an outside Coating of buildings extensively. The outside Coating of the building applied this PC method is a method to put tiles or stones to base concrete. And there is a method to use paints for, so the expression of various patterns is possible. The Multi-Layer Coating is one of the methods to use paints. This Multi-Layer Coating method can show various designs of external appearance with Foam when it is made with the PC panel. Also, the paint film of the PC panel enables a splendid appearance, and a protective function of concrete is possible, too. Therefore, it makes good durability of the PC. Besides, maintenance is easy to manage because it is free from pollution when it uses metallic materials, stones, or any other materials. You might have no trouble in applying the Multi-Layer Coating method in order to save a merit of an outside Coating on the PC panel. However, the Multi-Layer Coating method used as a current outside Coating method has pollution and bad working environment because Oil Epoxy Resins have toxicity and flammability. Therefore, a lot of warnings are required for coating work in order to have appropriate quality because working hours are short, and production efficiency is low too. These reasons make the cost of construction of the Multi-Layer Coating method increase. And employers or designers may have problems in selecting this Multi-Layer Coating method. Therefore, the purpose of this study is to get activation of the Multi-Layer Coating method by offering improvement measures about the problems of the existing Multi-Layer Coating method.

Analysis of Wear Properties for $Ni_{3}Al$ Layer coated on Ferrous Materials by Diffusion Treatment after Combustion Synthesis at low Temperature (저온 연소합성 후 확산 열처리한 $Ni_{3}Al$ 금속간화합물 코팅층의 미끄럼 마모거동)

  • Lee, Han-Young
    • Tribology and Lubricants
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    • v.25 no.1
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    • pp.7-12
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    • 2009
  • Coating brittle intermetallic compounds on metal can enlarge the range of their use. It is found that intermetallic compound coating layers made by only combustion synthesis in an electric furnace have porous multi-phase structures containing several intermediate phases, even though the coating layers show good wear resistance. In this study, dense $Ni_{3}Al$ single phase layer corresponding to the initial composition of the mixed powder is coated on two different ferrous materials by the diffusing treatment after combustion synthesis. After- ward, sliding wear behaviors of the coating layer are evaluated in comparison with that of the coating layer with porous multi-phase structure made by only combustion synthesis. As a result, the wear properties of the coating layer composed of dense $Ni_{3}Al$ single phase are considerably improved at the range of low sliding speed com- pared with that of the coating layer with porous multi-phase structure, particularly in the running-in wear region. This is attributed to the fact that wear of the coating layer is progressed by shearing as a sequence of adhesion, not by occurring of pitting on the worn surface due to having dense structure without pores.

Improving printability by designing a multi-layered coating structure (I) - The effect of binder properties in the pre-coating layer on the characteristics of the top-coating layer - (다층도공층의 설계에 의한 인쇄적성 개선 (제1보) - 프리코팅층의 바인더 물성이 탑코팅층의 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Won, Jong Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.27-33
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    • 2016
  • This study was carried out in order to investigate the effect of binder properties in pre-coating layer on the characteristics of top-coating layer and print mottle of coated paper. Four different latices were used as a binder in pre-coating layer, and coating color prepared with a same formulation was applied for top-coating. The properties and print mottle of coated paper were evaluated. It was found that glass transition temperature (Tg) was the important factor to control the properties of pre- and top-coating layer. PPS roughness of coated paper was decreased and paper gloss was increased with applying binder which has lower Tg. Properties of top-coating layer were affected by the binder used in pre-coating layer. Print mottle of coated paper was improved with using binder which has lower Tg in pre-coating layer. These results indicate that final printability and properties of top-coating layer can be improved with using suitable binder in pre-coating layer.

Improvement of printability by the new designe of the multi-layered coating structure (II) - The effect of pigment blending in pre-coating layer on characteristics of top-coating layer - (다층도공층의 설계에 의한 인쇄적성 개선(제2보) - 프리코팅층의 안료배합이 탑코팅층의 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Won, Jong Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.61-67
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    • 2016
  • This study was carried out in order to investigate the effect of pigment properties in a pre-coating layer on the characteristics of a top-coating layer and the print mottle of the coated paper. Five different pigments were applied for this study as raw materials for the pre-coating layer. The properties and print mottle of the coated paper samples were evaluated according to the coating color formulation. Type of pigments appliied in a pre-coating layer was one of the most important factor to control the properties of pre and top coating layer. Surface properties of pre and top coated paper were improved by blending GCC which had smaller particle size, with clay. Properties of a top-coating layer was affected by the pigment properties used in the pre-coating layer. It was found that print mottle of coated paper can be improved by replacing part of GCC with smaller particle size GCC or clay in pre-coating layer.

A Study on the Anti-Reflection Coating Effects of Polymer Eyeglasses Lens (폴리머 안경렌즈의 반사방지 코팅효과 연구)

  • Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.216-221
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    • 2017
  • Reducing optical reflection in the visible light range, in order to increase the share of transmitted light and avoid the formation of ghost images in imaging, is important for polymer lens applications. In this study, polymer lenses with refractive indices of n=1.56, 1.60, and 1.67 were fabricated by the injection-molding method with a polymer lens monomer, dibutyltin dichloride as the catalyst and an alkyl phosphoric ester as the release agent. To investigate their anti-reflection (AR) effects, various AR coating structures, viz. a multi-layer AR coating structure, tri-layer AR coating structure with a discrete approximation Gaussian gradient-index profile, and tri-layer AR coating structure with a quarter-wavelength approximation, were designed and coated on the polymer lens by an E-beam evaporation system. The optical properties of the polymer lenses were characterized by UV-visible spectrometry. The material properties of the thin films, refractive index and surface roughness, were analyzed by ellipsometry and AFM, respectively. The most effective AR coating structure of the polymer lens with low refractive index, n=1.56, was the both side coating of multi-layer AR coating structure. However, both side coating of the tri-layered discrete approximation Gaussian gradient-index profile AR coating structure gave comparable results to the both side coating of the multi-layer AR coating structure for the polymer lens with a high refractive index of n=1.67.

Contact Damage and Fracture of Poreclain/Glass-Infiltrated Alumina Layer Structure for Dental Application (치아 응용을 위한 /유리침윤 알루미나 이중 층상구조의 접촉손상 및 파괴)

  • 정연길;여정구;최성설
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1257-1265
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    • 1998
  • Hertzian contact tests were used to investigate the evolution of fracturedamage in the coating layer as functions of contact load and coating thickness by studying crack patterns in porcelain on glass-infiltrated alumina bilayer system conceived to simulate the crown structure of a tooth. Cone cracks initiated at the coating top surface without delamination at interface and crack propagation to substrate. Preferentially the cracks made multi-cracks at the coating top surface rather than proceeding to interface. The cracks were highly stabilized with wide ranges between the loads to initiate first cracking and to cause final failure im-plying damage-tolerant capability. Finite element modelling was used to evaluate the stress distribution. Maximum tensile stress were responsible for the cracking at the coating layer and had a profound influence on the crack pattern and fracture damage in the layered structure materials.

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The Study on the Reflection Coating Design Scheme in the Thin-Film Silicon Solar Cell (박막 실리콘 태양전지의 반사코팅 설계기술 연구)

  • Kim, Chang-Bong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.11
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    • pp.5172-5177
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    • 2011
  • This paper presents a reflection coating design scheme in the thin-film silicon solar cell. The antireflection(high reflection) coating skill is needed in the front(back) panel of the thin-film solar cell to improve an efficiency of light absorbing. In the single structure a reflectivity is changed according to the thickness of coating for antireflection scheme and its minimum value can be obtained by controlling thickness of coating. In the symmetric multi layer structure low reflectivity can be obtained in the wide wavelength range. And we also find that high reflectivity can be obtained through multi layer structure, which has alternate layers of high and low material, for high reflection scheme in the back panel.

Fabrication of Porous Reaction Bonded Silicon Carbide with Multi-Layered Pore Structures (다층 기공구조를 갖는 다공성 반응소결 탄화규소 다공체 제조)

  • Cho, Gyoung-Sun;Kim, Gyu-Mi;Park, Sang-Whan
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.534-539
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    • 2009
  • Reaction Bonded Silicon Carbide(RBSC) has been used for engineering ceramics due to low-temperature fabrication and near-net shape products with excellent structural properties such as thermal shock resistance, corrosion resistance and mechanical strength. Recently, attempts have been made to develop hot gas filter with gradient pore structure by RBSC to overcome weakness of commercial clay-bonded SiC filter such as low fracture toughness and low reliability. In this study a fabrication process of porous RBSC with multi-layer pore structure with gradient pore size was developed. The support layer of the RBSC with multi-layer pore structure was fabricated by conventional Si infiltration process. The intermediate and filter layers consisted of phenolic resin and fine SiC powder were prepared by dip-coating of the support RBSC in slurry of SiC and phenol resin. The temperature of $1550^{\circ}C$ to make Si left in RBSC support layer infiltrate into dip-coated layer to produce SiC by reacting with pyro-carbon from phenol resin.

Effects of Stoichiometry on Properties of NiAl Intermetallics coated on Carbon Steel through Combustion Synthesis (연소합성 코팅된 NiAl 금속간화합물의 화학양론이 미끄럼 마모특성에 미치는 영향)

  • Lee, Han-Young;Lee, Jae-Sung
    • Tribology and Lubricants
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    • v.36 no.3
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    • pp.124-132
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    • 2020
  • The effect of the stoichiometry on the sliding wear properties of NiAl coatings has been investigated. Three different powder mixtures with the compositions of Ni-50at%Al, Ni-54at%Al and Ni-42at%Al were diepressed respectively, and which were subsequently coated on mild steel through combustion synthesis in an induction heating system. Sliding wear behavior of the coatings was examined against an alloyed tool steel using a pin-on-disc type sliding wear test machine. As results, it could be seen that powder mixture(Ni-54at%Al) with displaying Al-rich deviations from the stoichiometry of NiAl(Ni-50at%Al) was promoted the most the synthetic reactivity. The microstructure of the coating layer with the compositions of Ni-54at%Al exhibits the porous NiAl single phase structure. However, the microstructure of the coating layer of the compositions of Ni-42at%Al exhibits the denser multi-phase structure containing several intermediate phases in addition to NiAl. Densification of the coating layer was enhanced by increasing the reacting temperature. On the other hand, the wear properties of the coating layers showed that the wear mode at speeds of around 1 m/s was severe wear, regardless of the stoichiometry and reacting temperature. However, wear properties of coating layer with the compositions of Ni-42at%Al were superior to those of coating layer with the compositions of Ni-54at%Al. This would be attributed by the fact that coating layer with the compositions of Ni-42at%Al develops little void and much intermediate phases with high strength.