• 제목/요약/키워드: Multi-Walled Carbon Nanotubes

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Dynamic mechanical analysis of silicone rubber reinforced with multi-walled carbon nanotubes

  • Li, Rui;Sun, L.Z.
    • Interaction and multiscale mechanics
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    • 제4권3호
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    • pp.239-245
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    • 2011
  • The dynamic mechanical behavior of silicone rubber reinforced with multi-walled carbon nanotubes (MWCNTs) has been investigated in this study. The MWCNT-reinforced nanocomposites are tested in compression mode through dynamic mechanical analysis (DMA). Multiple effects including MWCNT loading, testing frequency, dynamic strain amplitude, and pre-strain level are taken into consideration. Results show that, by adding 5 wt% of MWCNTs, the dynamic stiffness and damping coefficient of the silicone rubber are significantly enhanced. It is further observed that the dynamic mechanical properties of the nanocomposites are sensitive to dynamic strain amplitude but only slightly affected by pre-strains.

카복실산으로 표면개질된 다중층 탄소나노튜브의 구조분석 (Structural Analysis of Carboxylic Acid-functionalized Multi-walled Carbon Nanotubes)

  • 김정수;이건웅;오원태
    • 한국전기전자재료학회논문지
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    • 제20권10호
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    • pp.878-882
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    • 2007
  • Carboxylated multi-walled carbon nanotubes (MWNTs) were in detail characterized by XRD, XPS, FTIR, and thermogravimetric measurements. Carboxylic acid groups were functionalized to MWNTs under aqueous acid condition. The changes of sonication and reflux conditions rarely influenced the degree of carboxylation on MWNTs, but decreased the thermal stability of the resultant carboxylated MWNTs. XRD results showed that the diffraction peaks (100), (101), and (102) of pristine MWNTs disappeared after acid treatment, but the diffraction peak (002) was Preserved in the carboxylated MWNTs. The introduction of carboxylic acid groups on MWNTs caused to improve the dispersibility of the resultant carboxylated MWNTs in water.

Structural Analysis of Carboxylic Acid-Functionalized Multi-walled Carbon Nanotubes

  • 오원태;김정수;이건웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.63-63
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    • 2007
  • Carboxylated multi-walled carbon nanotubes (MWNTs) were in detail characterized by XRD, XPS, FTIR, and thermogravimetric measurements. Carboxylic acid groups were functionalized to MWNTs using aqueous acid solutions. The change. of sonication and reflux conditions rarely influenced the degree of carboxylation on MWNTs, but reduced the thermal stability of the resulting carboxylated MWNTs. The characteristic Bragg peaks of pristine and carboxylated MWNTs were analyzed by XRD measurements. After acid treatment the diffraction peaks (100), (101), and (102) of pristine MWNTs disappeared, but the diffraction peak (002) was preserved in the carboxylated MWNTs. The introduction of carboxylic acid groups on MWNTs caused to improve the dispersibility of the resulting carboxylated MWNTs in water.

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Facile Fabrication of Carbon Nanotubes@CuO Composites by Microwave Method

  • Kim, Tae Hyeong;Cha, Dun Chan;Jeong, Jung-Chae;Lee, Seunghyun
    • Elastomers and Composites
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    • 제56권3호
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    • pp.113-116
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    • 2021
  • In this study, we report a facile fabrication of multi-walled carbon nanotubes (MWCNTs)-CuO composites synthesized by a microwave method using MWCNTs and copper oxide (CuO). The number of copper hydrate precursors affect the size and number of CuO domains formed along the MWCNTs in the composites. The domain size is controllable from 239 nm to 348 nm. The composites are characterized by transmission electron microscopy, energy dispersive spectrometry, X-ray diffraction (XRD), Raman spectroscopy, and UV-Vis spectroscopy. The CuO produced in the composites is confirmed to be tenorite with a monoclinic crystal structure through the XRD patterns of (-111), (111) and (-202).

Effects of multi-walled carbon nanotubes on the hydration heat properties of cement composites

  • Ha, Sung-Jin;Rajadurai, Rajagopalan Sam;Kang, Su-Tae
    • Advances in concrete construction
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    • 제12권5호
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    • pp.439-450
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    • 2021
  • In recent years, nano-reinforcing materials are widely utilized in cement composites due to their unique multifunctional properties. This study incorporated multi-walled carbon nanotubes (MWCNTs) into the cementitious composites at ratios of 0.1%, 0.3%, and 0.5%, and investigated their influence on the flowability, mechanical strength, and hydration heat properties. The addition of MWCNTs enhanced the compressive and split tensile strengths approximately by 18-51%. In the semi-adiabatic temperature rise test, the internal hydration heat of the composites reduced by 5%, 9%, and 12% with the increase of MWCNTs in 0.1%, 0.3%, and 0.5%. This study further performed hydration heat analysis and estimated the adiabatic temperature rise, thermal stress, and thermal crack index. The internal hydration heat of the concrete decreased by 5%, 10%, and 13% with the increase of MWCNTs. The thermal stress of the concrete decreased with increase in the addition of MWCNTs, and the obtained temperature crack index was effective in controlling the thermal cracks.

Thin CNTs nanoliquid film development over a rough rotating disk

  • Swatilekha Nag;Susanta Maity;Sanjeev K. Metya
    • Advances in nano research
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    • 제15권2호
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    • pp.91-104
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    • 2023
  • Development of thin carbon nanotubes (CNTs) nanoliquid film over the rough surface of a horizontal rotating disk is investigated by considering symmetric roughness either along the azimuthal or radial directions. The disk surface is either heated or cooled axisymmetrically from below. The effects of single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNTs) are analyzed on the film thinning process with different types of base liquids. Closed form solutions for velocity and temperature field are obtained for small values of Reynolds number whereas the numerical solution is derived for moderate values of Reynolds number. It is found that fluid retention / depletion takes place when the roughness is symmetric along the azimuthal / radial directions. It is also seen that the film thinning rate enhances for MWCNTs compare to SWCNTs. Further it is found that two different heat transfer regions exits within the flow domain depending on the fact that heat is transferred from disk to liquid film and vice-versa.

경계조건에 따른 다중벽 탄소나노튜브의 유체유발 불안정성 변화 (Flow-induced Instability of Multi-wall Carbon Nanotubes for Various Boundary Conditions)

  • 윤경재;송오섭
    • 한국소음진동공학회논문집
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    • 제20권9호
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    • pp.805-815
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    • 2010
  • This paper studies the influence of internal moving fluid and flow-induced structural instability of multi-wall carbon nanotubes conveying fluid. Detailed results are demonstrated for the variation of natural frequencies with flow velocity, and the flow-induced divergence and flutter instability characteristics of multi-wall carbon nanotubes conveying fluid and modelled as a thin-walled beam are investigated. Effects of various boundary conditions, Van der Waals forces, and non-classical transverse shear and rotary inertia are incorporated in this study. The governing equations and three different boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extended Galerkin's method which enables us to obtain more exact solutions compared with conventional Galerkin's method. This paper also presents the comparison between the characteristics of single-wall and multi-wall carbon nanotubes considering the effect of van der Waals forces. Variations of critical flow velocity for different boundary conditions of two-wall carbon nanotubes are investigated and pertinent conclusion is outlined.

Free vibration analysis of chiral double-walled carbon nanotube using non-local elasticity theory

  • Rakrak, Kaddour;Zidour, Mohamed;Heireche, Houari;Bousahla, Abdelmoumen Anis;Chemi, Awda
    • Advances in nano research
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    • 제4권1호
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    • pp.31-44
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    • 2016
  • This article is concerned with the free vibration problem for chiral double-walled carbon nanotube (DWCNTs) modelled using the non-local elasticity theory and Euler Bernoulli beam model. According to the governing equations of non-local Euler Bernoulli beam theory and the boundary conditions, the analytical solution is derived and two branches of transverse wave propagating are obtained. The numerical results obtained provide better representations of the vibration behaviour of double-walled carbon nanotube, where the aspect ratio of the (DWCNTs), the vibrational mode number, the small-scale coefficient and chirality of double-walled carbon nanotube on the frequency ratio (${\chi}^N$) of the (DWCNTs) are significant. In this work, the numerical results obtained can be used to predict and prevent the phenomenon of resonance for the forced vibration analyses of double -walled carbon nanotubes.

유체유동효과를 고려한 다중벽 탄소나노튜브의 진동 및 안정성 해석 (Vibration Stability Analysis of Multi wall Carbon Nanotubes Considering Conveying Fluid Effect)

  • 윤경재;최종운;송오섭
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2012년도 춘계학술대회 논문집
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    • pp.219-224
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    • 2012
  • In this paper, vibration and flow-induced flutter instability analysis of cantilever multiwall carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

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Influence of Surface Treatment of Multi-walled Carbon Nanotubes on Interfacial Interaction of Nanocomposites

  • Kim, Ki-Seok;Park, Soo-Jin
    • Carbon letters
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    • 제11권2호
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    • pp.102-106
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    • 2010
  • In this work, the effect of aminized multi-walled carbon nanotubes (NH-MWNTs) on the mechanical interfacial properties of epoxy nanocomposites was investigated by means of fracture toughness, critical stress intensity factor ($K_{IC}$), and impact strength testing, and their morphology was examined by scanning electron microscope (SEM). It was found that the incorporation of amine groups onto MWNTs was confirmed by the FT-IR and Raman spectra. The mechanical interfacial properties of the epoxy nanocomposites were remarkably improved with increasing the NH-MWNT content. It was probably attributed to the strong physical interaction between amine groups of NH-MWNTs and epoxide groups of epoxy resins. The SEM micrographs showed that NH-MWNTs were uniformly embed and bonded with epoxy resins, resulted in the prevention of the deformation and crack propagation in the NH-MWNTs/epoxy nanocomposites.