• The Journal of Natural Sciences
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• v.7
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• pp.19-25
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• 1995

In this study, the Mossbauer effect of the $NiAl_0.8Fe_1.2O_4$ was investigated in the temperature range of 77K-1000K. The spectra were composed of two component, one is sixtet and the other doublet, at low temperature. From the temperature dependence of Mossbauer spectum, it is appeared that the magnetic properties of $NiAl_0.8Fe_1.2O_4$ varies from ferrimagnetism to paramagnetism as the increasing tempereture. And the magnetic relaxation patterns of the $NiAl_0.8Fe_1.2O_4$ were shown superparamagnetic effect.

• Korean Journal of Materials Research
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• v.5 no.7
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• pp.808-815
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• 1995

The magnetic states of nonstoichiometric substituted ferrite Fe$_{}1.429$(Al$_{4-x}$ Ga$_{x}$)$_{0.286}$ Si$_{0.143}$ /O$_4$ system have been investigated using Mossbauer spectroscopy and SQUID. The Mossbauer spectra at room temperature show well-defined two Zeeman patterns for x=0.2, superpositions of two Zeeman patterns and a doublet for x=0.4. The doublet peak seems to be originated from the superparamagnetic clusters. The system shows significant departures from the Neel's collinear model and seems to be the diluted ferrites. The Mossbauer spectra below R.T show various and complicated patterns, which can be explained by freezing of the superparamagnetic clusters. On cooling, magnetic states of the system may be various and multicritical, Resulting from SQUID measurements, there was an unexpected dip in magnetization curves below 50K. It was interpreted as an effect of spin canting including spin freezing or collective spin behavior.

• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.453-454
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• 2000

• Journal of the Korean Magnetics Society
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• v.8 no.3
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• pp.118-124
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• 1998

$Ni_{0.65}Zn_{0.35}Cu_{0.1}Fe{1.9}O_4$ has been studied with Mossbauer spectroscopy and X-ray diffraction. The crystal structure is found to be a cubic spinel with the lattice constant $a_0=8.390{\AA}$. Mossbauer spectra of $Ni_{0.65}Zn_{0.35}Cu_{0.1}Fe{1.9}O_4$ has been taken at various temperatures ranging from 12 K to 705 K. The isomer shift indicates that iron ions are ferric at tetrahedral [A] and octahedral sites [B], respectively. The Neel temperature is determined to be $T_N=705\;K$. As the temperature increases toward $T_N$ a systematic line broadening effect in the Mossbauer spectrum is observed and interpreted to originate from different temperature dependencies of the magnetic hyperfine fields at various iron sites. The quadrupole splitting just on $T_N$ is 0.41 mm/s whereas the quadrupole shift below $T_N$ vanishes. This implies that the orientation of the magnetic hyperfine field with respect to be principal axes of the electric field gradient is random.

• Journal of the Korean Vacuum Society
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• v.6 no.4
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• pp.337-342
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• 1997

We have investigated Mossbauer effect and emission properties of the Fe-doped GaAs grown by liquid phase epitaxy (LPE). The powder type of isotope $^{57}Fe$ was used as a dopant source in LPE-GaAs. From the analysis of Mossbauer effect the value of isomer shift, 0.303$\pm$0.018 mm/sec, is calculated at low temperature. This means that charge state of Fe ion in GaAs is 3+. The results of double crystal x-ray rocking curve (DCRC) and low temperature photoluminescence (PL) show the crystal quality of the epitaxial layers are good. Unusual luminescence peaks from the Fe-GaAs epitaxial layers appeared at emission energy of 0.99 eV and 1.15 eV. We attribute these emissions to Fe-acceptor related two deep radiative centers.

• Journal of the Korean Magnetics Society
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• v.9 no.1
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• pp.35-40
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• 1999

Sr substituted materials for some barium in M-type barium ferrite powder and Co-Ti substituted Sr-Ba hexagonal ferrite powder were prepared by citrate sol-gel method and 2 MOE sol-gel method these hexaferrite particles were reduced for 1hr in the hydrogen gas. The reduction temperatures were varied in the range of 250 $^{\circ}C$ to 500 $^{\circ}C$. X-ray diffraction patterns were measured using diffractometer with Cu $K_{\Alhpa}$ radiation. Mossbauer absorption spectra were measured with a constant acceleration spectrometer. We have focused on studying the origin of increasing $M_s$ by M$\"{o}$ssbauer spectroscopy. Ferrite particles which were sintered at 105$0^{\circ}C$ were found to be typical magnetoplumbite structure and single phase. XRD patterns with varying the reduction temperatures in $Sr_{0.5}Ba_{0.5}Fe_{10}O_{19}$ indicates ferrites particles become composite hexaferrites containing $\alpha$-Fe at T_{red}=350 \;$^{\circ}C$$. On the otherhand, it was found that $Co^{2+}$ ions and $Ti^{4+}$ ions in $Sr_{0.7}Ba_{0.3}Fe_{10}CoTiO_{19}$ prevent from changing $Fe^{3+}$ ions to $\alpha$-Fe during the $H_2$ reduction. Comparing Mossbauer results with XRD results, we have determined most of $\alpha$-Fe are reduced from $4f_{vi}$ sites and 12k sites of $Fe^{3+}$ ions. These $\alpha$-Fe phase bring the induced anisotropy and increase saturation magnetization $M_s$.TEX>.

• Journal of the Korean Magnetics Society
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• v.19 no.6
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• pp.227-232
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• 2009

Fe compounds of scoria samples distributed in the western seaside area of Jeju island were investigated by means of X-ray fluorescence spectroscopy (XRD), X-ray diffractometry (XRF) and $^{57}Fe$ Mossbauer spectroscopy. The samples were prepared from five parasite volcanos. We found that the samples were a typical basalt from the contents ratio of $SiO_2,\;Al_2O_3$ and Fe, and that they were silicate minerals. Underwater volcanoes scoria samples are shown only doublets in Mossbauer spectra and others scoria samples are shown sextets due to hematite and magnetite. And the balence state of Fe in the underwater volcanoes scoria samples are chiefly 2+ charge state with a little of the 2+ charge state. But the balence state of Fe in the others scoria samples are chiefly 3+ charge state.

• Korean Journal of Materials Research
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• v.9 no.7
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• pp.701-706
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• 1999

The crystal structure and magnetic properties of magnetic oxide system (F $e_2$ $O_3$)$_{5}$(A $l_2$ $O_3$)$_{4-x}$(G $a_2$ $O_3$)$_{x}$)SiO has been studied using X-ray diffraction and Mossbauer spectroscopy The changes of magnetic structure by the Ga ion substitution and the temperature variation have been investigated using Mossbauer spectroscopy, and the results are compared with those of the SQUIB measurements. Results of X-ray diffraction indicated that the crystal structures of the system change from a cubic spinel type to an orthorhombic via the intermediate region. This magnetic oxide system seems to be new kind of spinel type ferrites containing high concentration of cation vacancies. Various and complicated Mossbauer spectra were observed in the samples (x>0.2) at temperatures lower than room temperature. This result could be explained by freezing of the superparamagnetic dusters. On cooling and substitution, magnetic states of the system show various and multicritical properties. Unexpected dip in magnetization curves below 50K was observed in SQUID measurements. It was interpreted as an effect of spin canting including spin freezing or collective spin behavior.ior.r.

• Korean Journal of Materials Research
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• v.11 no.10
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• pp.859-862
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• 2001

The crystal structure and magnetic properties of the $Ni_{1-x} Cd_xFeAlO_4$(0$\leq$x$\leq$0.5) have been investigated by means of X-ray diffractometry and Mossbauer spectroscopy. The samples($0\leq$x$\leq$0.5) have been prepared by the ceramic sintering method. The X-ray diffraction pattern shows that the crystal structure of the samples is a cubic spinel type. The lattice constant has been found by extrapolation using the Nelson- Riley function and it increases slightly from $8.321{\AA}$ to $8.410{\AA}$ with Cd concentration. The Mossbauer spectra for x<0.4 show a superposition of two sextets and a paramagnetic doublet at room temperature. The cation distribution for x=0 was determined to be $[Fe_{0.75}Al_{0.25}]^A[NiFe_{0.25}Al_{0.75}^BO_4$. The superparamagnetic doublet for x< 0.4 seems to be due to A1 ion in tetrahedral site by the superparamagnetic clustering effect.

• Korean Journal of Materials Research
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• v.9 no.8
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• pp.854-857
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• 1999

The properties of Fe-Se-Te system(FeSe(sub)1-xTe(sub)x, x=0.2, 0.5, 0.8) have been studied by means of the X-ray diffraction method and Mossbauer spectroscopy. The results of X-ray diffraction patterns show that three samples have the ixed structure of tetragonal PbO and a small amount of hexagonal NiAs structure respectively. For x=0.5 the lattice parameters of tetragonal PbO structure are a=3.795$\AA$, c=5.896$\AA$ and c/a=1.55. The Mossbauer spectra were obtained with the various temperature variation and than they do not exhibit magnetic hyperfine structure but show a strong doublet. The values of observed isomer shift and quadrupole splitting suggest that the irons of all samples exist in the +2 oxidation state with a major covalent contribution. The temperature dependence of isomer shift values for x=0.8 seems to be originated from the second order Doppler effect.