• Korean Chemical Engineering Research
• /
• v.50 no.1
• /
• pp.128-134
• /
• 2012

The pilot scale experiments can handle the flue gas up to 1,000 $Nm^3/hr$ for separation of carbon dioxide included in real flue gas at coal-fired power plant. The operational characteristics was analyzed with the main experimental variables such as flue gas flow rate, absorbent circulation rate using chemical absorbents mono-ethanolamine( MEA) and 2-amino-2-methyl-1-propanol(AMP). The more flue gas flow rate decreased in 100 $m^3/hr$ in the MEA 20 wt% experiments, the more carbon dioxide removal efficiency was increased 6.7% on average. Carbon dioxide removal efficiency was increased approximately 2.8% according to raise of the 1,000 kg/hr absorbent circulation rate. It also was more than 90% at $110^{\circ}C$ of re-boiler temperature. Carbon dioxide removal efficiency of the MEA was higher than that of the AMP. In the MEA(20 wt%) experiment, carbon dioxide removal efficiency(85.5%) was 10% higher than result(75.5%) of ASPEN plus simulation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.19 no.9
• /
• pp.669-678
• /
• 2007

In this study, the ventilation characteristics is investigated numerically of the longitudinal ventilation method in the curved long road tunnel. Numerical work has been conducted for the jet fan location by utilizing the commercial finite-volume code, FLUENT. Configuration of the tunnel is three-lane, 1600 m long, $120m^2$ in area, 3000 m curvature radius. The velocity profile, distribution of mono-dioxide carbon and flow rate of air are examined in the tunnel. Through the analysis, it is found that the difference of ventilation flow rate Is a little by the jet fan location, but tunnel outlet setup (CASEIII) of jet fans is the most efficient concerned with CO concentration.

• Korean Chemical Engineering Research
• /
• v.50 no.2
• /
• pp.244-250
• /
• 2012

In order to separate of carbon dioxide in the combustion exhaust gas, monoethanolamine (MEA) and piperazine (PZ) impregnated zeolite 13X adsorbents were used. A series of adsorbents were synthesized by impregnating 30, 50 and 70 wt% of MEA and PZ respectively on zeolite 13X pellet. XRD, FT-IR and BET were used to characterize the properties of impregnated pelletized zeolite 13X absorbents. In order to investigate the separation characteristics of carbon dioxide, zeolite pellet, MEA impregnated zeolite and PZ impregnated zeolite pellet were investigated at 25, 50 and $75^{\circ}C$. Amine impregnated pelletized zeolite absorbent has shown that adsorption decreases with increasing temperature. Finally, the carbon dioxide adsorption capacity when emission temperature of the combustion exhaust gas, PZ impregnated zeolite pellet was 1.8 times than zeolite pellet as well as 20 times than MEA impregnated zeolite pellet.

• Journal of Ecology and Environment
• /
• v.43 no.2
• /
• pp.212-218
• /
• 2019

Background: Allelopathy has been suggested as one potential mechanism facilitating the successful colonisation and expansion of invasive plants. The impacts of the ongoing elevation in atmospheric carbon dioxide (CO₂) on the production of allelochemicals by invasive species are of great importance because they play a potential role in promoting biological invasion at the global scale. Common ragweed (Ambrosia artemisiifolia var. elatior), one of the most notorious invasive exotic plant species, was used to assess changes in foliar mono- and sesquiterpene production in response to CO₂ elevation (389.12 ± 2.55 vs. 802.08 ± 2.69 ppm). Results: The plant growth of common ragweed significantly increased in elevated CO₂. The major monoterpenes in the essential oil extracted from common ragweed leaves were β-myrcene, DL-limonene and 1,3,6-octatriene, and the major sesquiterpenes were β-caryophyllene and germacrene-D. The concentrations of 1,3,6-octatriene (258%) and β-caryophyllene (421%) significantly increased with CO₂ elevation. Conclusions: These findings improve our understanding of how allelochemicals in common ragweed respond to CO₂ elevation.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.18 no.4
• /
• pp.337-347
• /
• 2016

Carbon dioxide ($CO_2$) and methane ($CH_4$) were measured in a rice-barley double cropping and rice mono cropping paddy fields, which are located in the southwestern coast of Korea, over a one-year period. Net ecosystems $CO_2$ exchange (NEE) and ecosystem respiration (Re) were estimated by the eddy covariance (EC) method, and an automatic open/close chamber (AOCC) method was used to measure $CH_4$ fluxes. Environmental factors (solar radiation, air temperature, precipitation etc.) were also measured along with fluxes. After the quality control and gap-filling, the observed fluxes were analyzed. As a result, NEE was -603.0 and $-471.5g\;C\;m^{-2}\;yr^{-1}$ in rice-barley double cropping and rice mono cropping paddy field, respectively. $CH_4$ emissions increased during the course of flooded days and were similar in two cropping paddy field. Accoding to rough results considering only fluxes of $CO_2$ and $CH_4$, it was estimated that the carbon absorbation in rice-barley double cropping paddy field was higher than that in rice mono cropping paddy field by $128.9g\;C\;m^{-2}\;yr^{-1}$.

• Journal of Korean Society of Water and Wastewater
• /
• v.12 no.1
• /
• pp.88-95
• /
• 1998

The Electron/Hole Pair is generated when the Activation Energy produces by Ultraviolet Ray illumination to the Semiconductor. And $OH^-$ ion produces by Water Photo-Cleavage reacts with Positive Hole. As a result, OH Radical acting as strong oxidant is generated and then Photocatalytic Oxidation Reaction occurs. The Photocatalytic Oxidation can oxidize the chlorophenol to Chloride and Carbon Dioxide easier, safer and shorter than conventional Water Treatment Process With the same degree of chlorination, the $Cl^-$ ion at para (C4) position is most easily replaced by the OH radical. And then, the blocking effect of $OH^-$ ion between the $Cl^-$ ions and $Cl^-$ ions at symmetrical location is easily replaced by the OH radical. For mono-, di-, tri-chlorophenols, there is no obvious difference in decomposition rate, decomposition efficiency and completeness of the decomposition reaction except for 2,3-dichloropheno, 2,4,5-, 2,3,4-trichlorophenol. The decomposition efficiency is higher than 75% and completeness of the decomposition reaction is higher than 70%. Therefore, continuous flow photocatalytic reactor is promising process to remove the chlorinated aromatic compounds which is more toxic than non-chlorinated aromatic compound.

• Proceedings of the KSME Conference
• /
• 2008.11b
• /
• pp.2765-2770
• /
• 2008

The purpose of tunnel ventilation system for long road tunnels is to keep certain levels of Visibility Index and the concentration of CO. Additional equipments such as jet fans are used in road tunnel to discharge pollutants in the road tunnel. The control algorism of tunnel ventilation system takes the value of sensors as input, and then gives the operation method of jet fans in tunnel as output. Information on the variation of CO concentration in tunnel when jet fans are running is needed to minimize their operation time. Numerical analysis is used in this paper because of the difficulty of conducting experiments under standard condition for ventilation of road tunnel. The concentration of CO has been calculated by using 3-dimensional CFD under transient condition with speed of cars, quantity of air ventilation, and the results for various operation position of jet fans are compared.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.19 no.5
• /
• pp.386-393
• /
• 2007

This paper studies the ventilation characteristics according to the jet fan location at the long road tunnel using the CFD software 'FLUENT' which is based on the finite volume method. The tunnel model used in the analysis has a length of 1600m, a cross sectional area of $120m^3$, and is composed of 3 lanes and one way. The velocity profile, the distribution of CO concentration and the ventilation flow rate within the tunnel are analyzed, respectively. In the analysis, it is found that the dependence of the ventilation flow rate upon the jet fan location is small, but the CO concentration in the tunnel is at the lowest when the jet fans are installed near the tunnel outlet. An air stream right below the jet fan is almost inactive due to the strong stream injection near the jet fan. Thus, the pollution level below the jet fan must be higher than the other area.

• Korean Chemical Engineering Research
• /
• v.45 no.2
• /
• pp.197-202
• /
• 2007

This research was basically carried out to extend the application of $CO_2$ absorption processes for flue-gas system, which are mainly applied to a reforming process in petro-chemical industries. In general, MEA absorbent has some problems in flue-gas treatment, such as, degradation, regeneration energy and absorption capacities. As we known, sterical hindered amine, typically AMP (2-amino 2-methyl 1-propanol), have a good potential to improve these problems. In this paper, the characteristics of $CO_2$ absorption in aqueous AMP solution were measured and compared with that of MEA. It has been found that the $CO_2$ absorption capacity in AMP is double than that of MEA in the low $CO_2$ partial pressure system such as flue-gas. Also, the equilibriums of $CO_2$-AMP system were partially suggested, which are essentially needed to design the absorption process.