• Korean Journal of Materials Research
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• v.31 no.6
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• pp.331-338
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• 2021

Ti-Al-Si target and Cr-Si target are sputtered alternately to develop a multi-layered nitride coating on a steel mold to improve die-casting lifetime. Prior to the multi-layer deposition, a CrN layer is developed as a buffer layer on the mold to suppress the diffusion of reactive elements and enhance the cohesive strength of the multi-layer deposition. Approximately 50 nm CrSiN and TiAlSiN layers are deposited layer by layer, and form about three ㎛-thickness of multi-layered coating. From the observation of the uncoated and coated steel molds after the acceleration experiment of liquid metal injection casting, the uncoated mold is severely eroded by the adhesion of molten metallic glass. On the other hand, the multi-layer coating on the mold prevents element diffusion from the metallic glass and mold erosion during the experiment. The multi-layer structure of the coating transforms the nano-composite structured coating during the acceleration test. Since the nano-composite structure disrupts element diffusion to molten metallic glass, despite microstructure changes, the coating is not eroded by the 1,050 ℃ molten metallic glass.

• Korean Journal of Materials Research
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• v.28 no.7
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• pp.423-427
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• 2018

For diamond/metal composites it is better to use diamond particles coated with metal carbide because of improved wettability between the diamond particles and the matrix. In this study, the coating of diamond particles with a chromium carbide layer is investigated. On heating diamond and chromium powders at $800{\sim}900^{\circ}C$ in molten salts of LiCl, KCl, $CaCl_2$, the diamond particles are coated with $Cr_7C_3$. The surfaces of the diamond powders are analyzed using X-ray diffraction and scanning electron microscopy. The average thickness of the $Cr_7C_3$ coating layers is calculated from the result of the particle size analysis. By using the molten salt method, the $Cr_7C_3$ coating layer is uniformly formed on the diamond particles at a relatively low temperature at which the graphitization of the diamond particles is avoided. Treatment temperatures are lower than those in the previously proposed methods. The coated layer is thickened with an increase in heating temperature up to $900^{\circ}C$. The coating reaction of the diamond particles with chromium carbide is much more rapid in $LiCl-KCl-CaCl_2$ molten salts than with the molten salts of $KCl-CaCl_2$.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.6
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• pp.459-463
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• 2017

Hot dip galvanizing in the steel plant is one of the most widely used methods for preventing the corrosion of steel materials including structures, steel sheets, and materials for industrial facilities. While hot dip galvanizing has the advantage of stability and economic feasibility, it has difficulty in repairing equipment and maintaining the facilities due to high-temperature oxidation caused by Zn Fume where molten zinc used in the open spaces. Currently, SM45C (carbon steel plate for mechanical structure, KS standard) is used for the equipment. If a part of the equipment is resistant to high temperature and Zn fume, it is expected to improve equipment life and performance. In this study, the manufactured Ni alloy was tested for its corrosion resistance against Zn fume when it was used in the hot dip galvanizing equipment in the steel plant. Two kinds of materials currently used in the equipment, new Ni alloy and Inconel(typical corrosion-resistant Ni alloy), were selected as the reference groups. Two kinds of molten metal were used to confirm the corrosion of each alloy according to the molten metal. Zn fume was generated by bubbling Ar gas from molten Zn in a furnace($500{\sim}700^{\circ}C$) and the samples were analyzed after 30 days. After 30 days, the specimens were taken out, the oxide layer on the surface was confirmed with an optical microscope and SEM, and the corrosion was confirmed using a potentiodynamic polarization test. Corrosion depends on the type of molten metal.

• Journal of Welding and Joining
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• v.18 no.3
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• pp.51-59
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• 2000

Sink roll has been used in molten 55%Al-Zn alloy bath of continuous galvanizing line for sinking and stabilizing working steel strip in molten metal bath. In the process, the sink roll body inevitably build up dross compounds and pitting on the sink roll surface during 55%Al-Zn alloy coated strip production, and the life time of the sink roll is shorten by build up dross compounds and pitting. The present study examined the application of thermally sprayed ceramic coatings method on sink roll body for improving erosion resistance at molten 55% Al-Zn pool. In this experiment, the stainless steels such as STS 316L and STS 430F were used as the substrate materials. The CoNiCr and WE-Co powder were selected as bond coating materials. Moreover $Al_2O_3-ZrO_2-SiO_2 and ZrO_2-SiO_2$ powders selected as the top coating materials. Appearances of the specimens before and after dipping to molten 55%Al-Zn pool were compared and analyzed. As a result of this study, STS430F of substrate, WC-Co of bond spray coatings, $ZrO_2-SiO_2$ power of top spray coatings is the best quality in erosion resistance test at molten 55%Al-Zn pool

• Journal of Korea Foundry Society
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• v.26 no.3
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• pp.129-132
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• 2006

In the present study the new method was proposed by using the real-time X-ray observation and metal die in order to evaluate fluidity and viscosity of the molten metal during pouring into the mold. The special mold for the present experiment was introduced since X-ray could not transmit thick mold wall and scatter the image of the molten metal during pouring. The present study also discussed for evaluation of viscosities by using the flow data from radioscopy images, and the viscosities of six commercial aluminum alloys were evaluated and compared.

• Journal of the Korean Ceramic Society
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• v.19 no.1
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• pp.24-34
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• 1982

The effect of the several variables on wetting of AISIB1113 steel by molten glass was studied by Sessible-drop method. Experimental variables were temperature, firing atmospheres, Fe2O3 addition to the sealing glass and steel surface conditions. The degree of wetting in terms of contact angles between molten glass and metal tested at different test conditions was analyzed by using Young's equation. The results showed that contact angles in H2 atmosphere in the glass metal systems were high but in N2 atmosphere, were small for studied glass metal systems. Especially, when the glass drop was in contact with oxidized steel in N2 atmosphere, The best adherence with contact angle of approximately 9°was obtained. In the case of Fe2O3 addition in glass contact angles subtantially increased due to the increase of surface tension of glass. Wetting phenomena were also discussed under the basis of these experimental results.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.9
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• pp.2368-2373
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• 1994

The advancement of the mechanical properties of metal materials caused by a recent high technology contributes to the stability and productivity of mechanical structures. However, the advanced mechanical properties depends on the conditions of crystal boundaries and the improvement of the texture. Although the tensile strength and a hardness of a steel would be increased by the adding B, it seems to be a marked decreases of the toughness which caused in the weaken workability. This study is concerned with a characteristics of the B compound which will be mixed with $H_3BO_3$ and the metallic magnesium. What affected in the mechanical property and texture is checked by the strength and the texture test. As a result, it is shown that the improvement of the mechanical property and the texture homogeneity. In addition, it seems that a molten metal which is added by the B compound is deoxized and cleansed.

• Proceedings of the KWS Conference
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• 1996.10a
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• pp.148-152
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• 1996

A transient two-dimensional (2D) model was developed for investigating the heat and fluid flow in old pools and determining velocity profile and temperature distribution for the Gas Metal Arc (GMA) welding process. The mathematical formulation deals with the driving farces (electromagnetic, buoyancy, surface tension and plasma drag forces) as well as energy exchange between the molten filler metal droplet and weld pools. A general thermofluid-mechanics computer program, PHOENICS, was employed to numerically solve the governing equation with the associated source terms. The results of computation have shown that the electromagnetic and surface tension farces as will as the molten filler metal droplet have major influence in shaping the weld pool geometry.

• Journal of the Korean Society for Precision Engineering
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• v.18 no.7
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• pp.167-173
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• 2001

The simulated die-casting process in which the traditional plaster casting process is combined with Rapid Prototyping technology is being used to produce AI, Mg, and Zn die-casting prototypes. Unlike in the die-casting process, molten metal in the conventional plaster casting process is fed via a gravity pour into a mold and the mold does not cool as quickly as a die-casting mold. The plaster castings have much larger and grosser grain structure as compared with the normal die-castings and the thin walls of the plaster mold cavity may not be completely filled. Because of lower mechanical properties induced by the large grain structure and incomplete filling, the conventional plaster casting process is not suitable for the trial die-casting process to obtain quality prototypes. In this work, an enhanced trial die-casting process has been developed in which molten metal in the plaster mold cavity is vibrated and pressurized simultaneously. Patterns for the casting are made by Rapid Prototyping technologies and then plaster molds, which have a runner system, are made using these patterns. Pressurized vibration to imparted molten metal has made grain structure of castings much finer and improved fluidity of the molten enough to obtain complete filling at thin walls which may not be filled in the conventional plaster casting process..

• Journal of the Korean Ceramic Society
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• v.17 no.4
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• pp.188-196
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• 1980

To investigate the corrosion behavior of the clay-bonded kaolin chamotte by molten aluminum, the mixture of 20 wt% fire clay and 80 wt% kaolin chamotte was prepared and fired in the temperature range 900~120$0^{\circ}C$. The specimens fired at each temperature were reacted with molten aluminum at 90$0^{\circ}C$. The results obtained in this experiment are as followed. 1) It was confirmed through X-ray diffraction analysis that the clay-bonded kaolin chamotte exposed to molten aluminum suffered penetration by the reaction of aluminum with silica forming alumina and metallic silicon. 2) Penetration was independent whether the silica existed as free or one component of mullite. 3) Penetration of the specimen fired at 90$0^{\circ}C$ was negligible while the others fired above 100$0^{\circ}C$ showed remarkable penetration. 4) Penetration rate at 90$0^{\circ}C$ was parabolically increased with the holding time as in the case of metal oxidation.