• Title/Summary/Keyword: Molecule

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The Binding of 5-Iodopyrimidines by Human serum albumin (5-Iodopyrimidines와 Human serum albumin과의 결합(結合))

  • Lee, Jong-Jin
    • Applied Biological Chemistry
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    • v.1
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    • pp.48-54
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    • 1960
  • Studing the binding of the 5-Iodopyrimdines by human serum albumin we obtained the following conclusions; 1. The more strong electron donating groups in the molecule of 5-Iodopyrimidines, the larger the binding force with human serum albumin. This trend seems to be attributed by increase of polarization of the electron donating groups in 5-Iodopyrimidines molecule. 2. The binding force of 5-Iodopyrimidines by human serum albumin is increased with the pH increasing could be occurred the configurational changes of human albumin molecule, and this new binding sites of human serum albumin molecule would form the intermolecular complex with 5-Iodopyrimidines molecule more strongly.

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Studies on the Crystal Structure of Benzidine Perchlorate by X-ray Diffraction Method (I) Relation between the Space Group and the Composition of the Diamine Salt Crystal (X-線 廻折法을 利用한 벤지딘過鹽素酸鹽의 結晶構造에 關한 硏究 (I) 空間群과 Diamine 鹽 結晶의 組成과 關係)

  • Koo, Chung-Hoe;Sa Kong, Yul;Kang, Man-Hyong;Shin, Hyun-So
    • Journal of the Korean Chemical Society
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    • v.14 no.1
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    • pp.119-122
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    • 1970
  • In those six kinds of diamine salt crystal of which their structures had already been determined up to date, commonly one molecule of diamine and two molecules of acid were combined; although the crystal of benzidine perchlorate, only one molecule each of benzidine and perchloric acid were combined. At the case of benzidine perchlorate, one molecule acts as the role of two molecules by coincidence of the center of symmetry point of both the lattice and molecule, and perchlorate ion is locating symmetrically between two -$NH_2$ groups of different benzidine molecule, therefore benzidine and acid could be combined together with 1:1 by mole ratio. When forming the salt with diamine and acid, the combining mole ratio would be determined in accordance with the relationship between the symmetry element that presented by the space group and the symmetry element of diamine salt melecule.

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Study on the separation of large ionic-molecules by electrofiltration (전기여과에 의한 거대이온성 분자체 분리현상연구)

  • Park Young-Gyu
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.18-23
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    • 1998
  • Theoretical model has been derived in the electrophoretic separation system where an electric potential is applied to the system in the axial direction. The effect of electrophoretic convection in the polymeric media is significantly contributed to separate large ionic-molecules because the conformation of large ionic-molecule quickly orients in the field direction. The dependence of the transport in the polymeric media upon field intensity and molecular size aids in understanding the transport of large ionic-molecule in the system, since the convective velocity of large ionic-molecule is accelerated inside a porous material. The separation of two different large ionic-molecules is predicted with a value of $(Pe_t/Pe_g)$ of individual large ionic-molecule using an operator and the reptation theories.

Electrical and Morphology Properties of Self-Assembled Dendrimer on Au (111) Substrate (Au (111)기판에 자기조립된 덴드리머 분자의 형태와 전기적 특성에 관한 연구)

  • Jung, Kyung-Han;Shin, Hoon-Kyu;Kim, Chung-Kyun;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.120-123
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    • 2003
  • To investigate the characteristics of the single dendrimer molecule, we attempt to measure morphology and electrical properties of the self-assembled dendrimer on Au (111)substrate with SPM(scanning probe microscopy). The same self-assembly procedure was used for two different concentrations, $10{\mu}mol/ml$ and $100{\mu}mol/ml$. The case of lower concentration, we can measure the diameter and the height of the single molecule with the tapping mode AFM image. The imaged single molecules were dome shaped and the average diameter and height were 15.6 nm, 1.2 nm respectively. From these sizes, we can calculate the volume of the single molecule. The volume of the single molecule was estimated about $116nm^3$. However, that of higher concentration, it is difficult to obtain obvious image of the single molecule. To add to, I-V characteristics were investigated using STM, on which the phenomenon of negative differential resistance (NDR)was observed between 0.14 V and 0.24 V reproductively.

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Voronoi Diagram Computation for a Molecule Using Graphics Hardware (그래픽 하드웨어를 이용한 분자용 보로노이 다이어그램 계산)

  • Lee, Jung-Eun;Baek, Nak-Hoon;Kim, Ku-Jin
    • The KIPS Transactions:PartA
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    • v.19A no.4
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    • pp.169-174
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    • 2012
  • We present an algorithm that computes a 3 dimensional Voronoi diagram for a protein molecule in this paper. The molecule is represented as a set of spheres with van der Waals radii. The Voronoi diagram is constructed in the 3D space by finding the voxels containing it. For the feasibility of the computation, we represent the molecule as a BVH (bounding volume hierarchy), and our system is accelerated by modern graphics hardware with CUDA programming support. Compared to single-core CPU implementations, experimental results show 323 times faster performance in the computation time, when the space is partitioned into $2^{24}$ voxels.

Novel Fabrication of Nanoporous Alumina Membrane Microtubes: 2-Dimensional Nanoporous Arrays on Every Facets of Microtubes

  • Chae, Weon-Sik;Im, Sung-Jae;Lee, Jin-Kyu;Kim, Yong-Rok
    • Bulletin of the Korean Chemical Society
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    • v.26 no.3
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    • pp.409-412
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    • 2005
  • Free-standing nanoporous alumina membrane microtubes with different shapes (rectangular and cylindrical tubes) and variable dimensions were easily fabricated by direct anodization of the aluminum templates of the specified shapes (strip and wire) and dimensions during the electrochemical reaction.

Determination of energetically preferable Au-S contact atomic structure in stretched single-molecule junctions

  • Ko, Kwan Ho
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.409-411
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    • 2014
  • Based on the first-principles computations, the nature of the microscopic geometry of the molecule-electrode contacts was addressed. The single-molecule junction was prepared by connecting hexanediothiolate (HDT) to Au(111) electrodes via one, two, and three Au adatoms having coordination number of one (CN1), two (CN2), and, three (CN3), respectively. The contact atomic structure and energy of the stretched Au-HDT-Au junction was observed. The analysis revealed that the contact geometry with lowest coordination number (CN1) is energetically more stable than CN2 and CN3.

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White-Light-Emitting Molecule

  • Park, Soo-Young;Park, Sang-Hyuk
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.481-481
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    • 2009
  • For a new generation of white light sources, we present the first example of a concentration-independent ultimate white-light-emitting molecule based on excited-state intramolecular proton transfer materials. Our molecule is composed of covalently linked blue- and orange-light-emitting moieties between which energy transfer is entirely frustrated, leading to the production of reproducible, stable white photo- and electroluminescence.

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