• Title/Summary/Keyword: Molecular vibration

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Influence of Chemical composition of Ethylene-Vinyl Acetate Copolymers on Impact Noise Damping of Composites (에틸렌-초산비닐 공중합체의 공중합 조성이 복합체의 충격음 흡수성능에 미치는 영향)

  • 이현종
    • Journal of Korea Foresty Energy
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    • v.18 no.2
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    • pp.55-61
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    • 1999
  • This study was carried out to investigate the influence of viscoelastic properties(or chemical composition) of a series of ethylen-viny1 acetate copolymers on impact noise and vibration damping of wood/polymer/wood sandwich composites. The impact noise and vibration damping of composites were very sensitive to the state of molecular motion of polymer. The noise and vibration damping of composites were maximum when the polymer was under the glass transition(vinylacetate 55~75%) at the test-temperature, and minimum rubbery state(vinyl-acetate 47~20%) or glassy state(vinylacetate 100~87%). The polymer under glass transition reduced the impact noise by 6~12 dB.

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Proteomic Changes in the Sound Vibration-Treated Arabidopsis thaliana Facilitates Defense Response during Botrytis cinerea Infection

  • Ghosh, Ritesh;Choi, Bosung;Kwon, Young Sang;Bashir, Tufail;Bae, Dong-Won;Bae, Hanhong
    • The Plant Pathology Journal
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    • v.35 no.6
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    • pp.609-622
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    • 2019
  • Sound vibration (SV) treatment can trigger various molecular and physiological changes in plants. Previously, we showed that pre-exposure of Arabidopsis plants to SV boosts its defense response against Botrytis cinerea fungus. The present study was aimed to investigate the changes in the proteome states in the SV-treated Arabidopsis during disease progression. Proteomics analysis identified several upregulated proteins in the SV-infected plants (i.e., SV-treated plants carrying Botrytis infection). These upregulated proteins are involved in a plethora of biological functions, e.g., primary metabolism (i.e., glycolysis, tricarboxylic acid cycle, ATP synthesis, cysteine metabolism, and photosynthesis), redox homeostasis, and defense response. Additionally, our enzyme assays confirmed the enhanced activity of antioxidant enzymes in the SV-infected plants compared to control plants. Broadly, our results suggest that SV pre-treatment evokes a more efficient defense response in the SV-infected plants by modulating the primary metabolism and reactive oxygen species scavenging activity.

Influence of porosity and axial preload on vibration behavior of rotating FG nanobeam

  • Ehyaei, Javad;Akbarshahi, Amir;Shafiei, Navvab
    • Advances in nano research
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    • v.5 no.2
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    • pp.141-169
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    • 2017
  • In this paper, a nanobeam connected to a rotating molecular hub is considered. The vibration behavior of rotating functionally graded nanobeam based on Eringen's nonlocal theory and Euler-Bernoulli beam model is investigated. Furthermore, axial preload and porosity effect is studied. It is supposed that the material attributes of the functionally graded porous nanobeam, varies continuously in the thickness direction according to the power law model considering the even distribution of porosities. Porosity at the nanoscopic length scale can affect on the rotating functionally graded nanobeams dynamics. The equations of motion and the associated boundary conditions are derived through the Hamilton's principle and generalized differential quadrature method (GDQM) is utilized to solve the equations. In this paper, the influences of some parameters such as functionally graded power (FG-index), porosity parameter, axial preload, nonlocal parameter and angular velocity on natural frequencies of rotating nanobeams with pure ceramic, pure metal and functionally graded materials are examined and some comparisons about the influence of various parameters on the natural frequencies corresponding to the simply-simply, simplyclamped, clamped-clamped boundary conditions are carried out.

Torsional vibration analysis of bi-directional FG nano-cone with arbitrary cross-section based on nonlocal strain gradient elasticity

  • Noroozi, Reza;Barati, Abbas;Kazemi, Amin;Norouzi, Saeed;Hadi, Amin
    • Advances in nano research
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    • v.8 no.1
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    • pp.13-24
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    • 2020
  • In this paper, for the first time based on the nonlocal strain gradient theory the effect of size dependency in torsional vibration of bi-direction functionally graded (FG) nonlinear nano-cone is study. The material properties were assumed to vary according to the arbitrary function in radial and axial directions. The Navier equation and boundary conditions of the size-dependent bidirectional FG nonlinear nano-cone were derived by Hamilton's principle. These equations were solved by employing the generalized differential quadrature method (GDQM). The presented model can turn into the classical model if the material length scale parameters are taken to be zero. The effects of some parameters, such as inhomogeneity constant, cross-sectional area parameter and small-scale parameters, were studied. As an essential result of this study can be stated that an FG nano-cone model based on the nonlocal elasticity theory behaves softer and based on the strain gradient theory behaves harder.

Adhesive Area Detection System of Single-Lap Joint Using Vibration-Response-Based Nonlinear Transformation Approach for Deep Learning (딥러닝을 이용하여 진동 응답 기반 비선형 변환 접근법을 적용한 단일 랩 조인트의 접착 면적 탐지 시스템)

  • Min-Je Kim;Dong-Yoon Kim;Gil Ho Yoon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.1
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    • pp.57-65
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    • 2023
  • A vibration response-based detection system was used to investigate the adhesive areas of single-lap joints using a nonlinear transformation approach for deep learning. In industry or engineering fields, it is difficult to know the condition of an invisible part within a structure that cannot easily be disassembled and the conditions of adhesive areas of adhesively bonded structures. To address these issues, a detection method was devised that uses nonlinear transformation to determine the adhesive areas of various single-lap-jointed specimens from the vibration response of the reference specimen. In this study, a frequency response function with nonlinear transformation was employed to identify the vibration characteristics, and a virtual spectrogram was used for classification in convolutional neural network based deep learning. Moreover, a vibration experiment, an analytical solution, and a finite-element analysis were performed to verify the developed method with aluminum, carbon fiber composite, and ultra-high-molecular-weight polyethylene specimens.

Damping Properties and Transmlission Loss of Polyurethane. II. PU Layer and Copolymer Effect

  • Yoon, kwan-Han;Kim, Ji-Gon;Bang, Dae-Suk
    • Fibers and Polymers
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    • v.4 no.2
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    • pp.49-53
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    • 2003
  • Polyurethane (PU) layer and copolymer consisted of the different molecular weights (1000 and 2000 g/mol) of poly(propylene glycol) (PPG) were prepared. The damping and mechanical properties of these materials were compared with PU 1000 made by PPG having the molecular weight of 1000 g/mol. The optimum composition of PU2000 used for PU layer and copolymer was diphenylmethane diioscynate (MDI)/propylene glycol (PPG)/butanediol (BD) (1/0.3/0.7) based on the damping and mechanical properties. The damping peak of PU copolymer was higher than those of PU layer and PUI 1000 in low temperature range (-30- $10^{\circ}C$). For application in noise reduction, the transmission loss of the mechanical vibration through solid structure was measured. PU layer and copolymer were used as a damping layer. The transmission loss of PU copolymer was more effective than those of PU layer and PU 1000 in the experimental frequency range.

Local and Normal Modes of OH Stretching Vibration in Hydrogen-Bonded Water Molecules (수소 결합한 물 분자에서 OH 신축 진동의 국소모드와 정규모드)

  • Kwon, Seeun;Yang, Mino
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.350-353
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    • 2020
  • The validity of the calculation method based on the local mode in hydrogen-bonded water molecules was investigated by comparing the frequencies of the local and normal modes of OH stretching vibration in water molecules. By calculating a monomer, dimer, and trimer of water molecules using a quantum chemical ab initio theory, we examined how the frequencies of the local and normal modes and the anharmonicity of local modes vary with molecular cluster size. It was shown that, as the number of molecules increases from monomer to trimer, the anharmonicity of OH bonds increases and the difference between local and normal mode frequencies decreases. This confirms that local-mode-based calculations that can easily handle the anharmonicity can be appropriate for the calculation of the OH stretching frequency of water molecules in the condensed phase.

Forward and backward whirling of a spinning nanotube nano-rotor assuming gyroscopic effects

  • Ouakad, Hassen M.;Sedighi, Hamid M.;Al-Qahtani, Hussain M.
    • Advances in nano research
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    • v.8 no.3
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    • pp.245-254
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    • 2020
  • This work examines the fundamental vibrational characteristics of a spinning CNT-based nano-rotor assuming a nonlocal elasticity Euler-Bernoulli beam theory. The rotary inertia, gyroscopic, and rotor mass unbalance effects are all taken into consideration in the beam model. Assuming a nonlocal theory, two coupled 6th-order partial differential equations governing the vibration of the rotating SWCNT are first derived. In order to acquire the natural frequencies and dynamic response of the nano-rotor system, the nonlinear equations of motion are numerically solved. The nano-rotor system frequency spectrum is shown to exhibit two distinct frequencies: one positive and one negative. The positive frequency is known as to represent the forward whirling mode, whereas the negative characterizes the backward mode. First, the results obtained within the framework of this numerical study are compared with few existing data (i.e., molecular dynamics) and showed an overall acceptable agreement. Then, a thorough and detailed parametric study is carried out to study the effect of several parameters on the nano-rotor frequencies such as: the nanotube radius, the input angular velocity and the small scale parameters. It is shown that the vibration characteristics of a spinning SWCNT are significantly influenced when these parameters are changed.

Free vibrations analysis of arbitrary three-dimensionally FGM nanoplates

  • Dehshahri, Kasra;Nejad, Mohammad Zamani;Ziaee, Sima;Niknejad, Abbas;Hadi, Amin
    • Advances in nano research
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    • v.8 no.2
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    • pp.115-134
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    • 2020
  • In this paper, the free vibrations analysis of the nanoplates made of three-directional functionally graded material (TDFGM) with small scale effects is presented. To study the small-scale effects on natural frequency, modified strain gradient theory (MSGT) has been used. Material properties of the nanoplate follow an arbitrary function that changes in three directions along the length, width and thickness of the plate. The equilibrium equations and boundary conditions of nanoplate are obtained using the Hamilton's principle. The generalized differential quadrature method (GDQM) is used to solve the governing equations and different boundary conditions for obtaining the natural frequency of nanoplate made of three-directional functionally graded material. The present model can be transformed into a couple stress plate model or a classic plate model if two or all parameters of the length scales set to zero. Finally, numerical results are presented to study the small-scale effect and heterogeneity constants and the aspect ratio with different boundary conditions on the free vibrations of nanoplates. To the best of the researchers' knowledge, in the literature, there is no study carried out into MSGT for free vibration analysis of FGM nanoplate with arbitrary functions.

Bonding And Anti-bonding Nature of Magnetic Semiconductor Thin Film of Fe(TCNQ:tetracyanoquinodimethane)

  • Jo, Junhyeon;Jin, Mi-jin;Park, Jungmin;Modepalli, Vijayakumar;Yoo, Jung-Woo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.294-294
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    • 2014
  • Developing magnetic thin films with desirable physical properties is a key step to promote research in spintronics. Organic-based magnetic material is a relatively new kind of materials which has magnetic properties in a molecular and microscopic level. These materials have been constructed by the coordination between 3d transition metal and organic materials producing long-range magnetic orders with a relatively high transition temperature. However, these materials were mostly synthesized as a form of powder, which is difficult to study for their physical properties as well as apply for electronic/spintronic devices. In this study, we have employed physical vapor deposition (PVD) to develop a new organic-based hybrid magnetic film that is achieved by the coordination of Fe and tetracyanoquinodimethane (TCNQ). The IR spectra of the grown film show modified CN vibration modes in TCNQ, which suggest a strong bonding between Fe and TCNQ. The thin film has both ferromagnetic and semiconducting behaviors, which is suitable for molecular spintronic applications. The high resolution photoemission (HRPES) spectra also show shift of 1s peak point of nitrogen and the carbon 1s peaks display traces of charge transfer from Fe to TCNQ as well as shake-up features, which suggest strong bonding and anti-bonding nature of coordination between Fe and TCNQ.

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