• 제목/요약/키워드: Molecular thin film

검색결과 337건 처리시간 0.024초

표면효과를 고려한 박막구조의 멀티스케일 해석 (Multi-scale Analysis of Thin film Considering Surface Effects)

  • 조맹효;최진복;정광섭
    • 한국전산구조공학회논문집
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    • 제20권3호
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    • pp.287-292
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    • 2007
  • 일반적으로 고전적인 탄성이론에서 매크로 스케일의 구조물의 물성은 구조물의 사이즈에 영향을 받지 않는다. 그 이유는 구조물 전체 체적에 대한 표면의 비율이 매우 작기 때문에 표면의 효과를 무시할 수 있기 때문이다. 그러나, 구조물 전체의 부피에 대한 표면의 비율이 커지게 되면 표면의 효과가 매우 중요한 역할을 하게 되며 지배적으로 나타나게 된다. 특히 나노 박막이나 나노 빔 등 나노 스케일의 구조물에서는 표면효과의 영향을 반드시 고려하여야만 한다. 분자 동역학 시뮬레이션은 이러한 나노 스케일의 구조물 역학적 해석을 위해서 그간 사용되어 온 일반적인 방법이었으나, 과도하게 요구되는 계산시간과 전산자원의 한계로 인해 여전히 수 나노 초 동안에 $10^6{\sim}10^9$개의 원자들에 대한 시뮬레이션이 가능한 정도이다. 따라서 실제적으로 MEMS/NEMS 분야에서 사용되는 서브마이크 스케일에서 마이크로 스케일의 구조물의 분자동역학 시뮬레이션을 통한 해석은 가능하나 설계를 목적으로 했을 때는 현실적이지 못하다. 따라서 본 연구에서는 이러한 분자 동역학 시뮬레이션 기법의 단점을 보완하고자 나노 스케일의 매우 작은 구조물에서 지배적으로 나타나는 표면효과를 고려할 수 있는 연속체 기반의 모델을 제시하고자 한다. 특히 본 논문에서는 박막구조물의 해석을 위하여 고전적인 Kirchhoff 평판이론을 바탕으로 표면효과를 고려할 수 있도록 하는 연속체 모델을 제안하고 이를 바탕으로 유한요소해석을 수행하여 그 해석 결과를 분자 동역학 시뮬레이션 결과와 비교하였다.

Study on Charge Transport in Nanoscale Organic Monolayers for Molecular Electronics Using Liquid Phase Electrodes

  • Hwang, Jin-Ha
    • 마이크로전자및패키징학회지
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    • 제12권3호
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    • pp.235-241
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    • 2005
  • Incorporation of solid electrodes frequently involves plasma-based processing. The effect of plasma can influence the physical characteristics, depending on the magnitude in plasma. The undesired feature of plasma-induced damage should be prevented in characterizing the ultra-thin materials, such as ultra-thin films and organic monolayers. The current work at first proves the applicability of a liquid phase electrode in the electrical/dielectric properties through comparative work using Al and Hg on ultrathin $Al_2O_3$ films deposited through atomic layer deposition at low temperature: Two types of metals such as Aluminum (Al) and mercury (Hg) were used as electrodes in $Al_2O_3$ thin films in order to investigate the effect of electrode preparation on the current-voltage characteristics and impedance features as a function of thickness in $Al_2O_3$ film thickness. The success of Hg in $Al_2O_3$ thin films is applied to the AC and DC characterization of the organic monolayers obtained using the Langmuir-Blodgett method. From the DC current-voltage characteristics, the diode-like response is found to originate from the bulk response of the organic materials, evidenced by the fact and the capacitance is inversely related to the absolute thickness of organic layers.

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Plastic Electronics and Optoelectronics: Advances in Materials and Devices

  • Jenekhe Samson A.;Kulkarni Abhishek P.;Zhu Yan
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.9-10
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    • 2006
  • Recent work in our laboratory has focused on the molecular and supramolecular engineering of conjugated polymers and oligomers for device applications, including light emitting diodes for displays and lighting, photovoltaic cells, and thin film transistors. A central finding is that the supramolecular structure of conjugated polymers can have a dominant influence on their properties and the performance of devices. Some major results include: highly efficient RGB light-emitting diodes from polymers and oligomers; high mobility n-channel polymer field effect transistors; ambipolar thin film transistors from copolymer semiconductors; and self-assembly and ambipolar charge transport in polymer nanowires.

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Light emitting thin film structures based on organic luminophors embedded in porous alumina matrixes

  • Gorokh, G.G.;Labunov, V.A.;Smirnov, A.G.;Kukhta, A.V.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.315-318
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    • 2002
  • Light emitting thin film structures based on organic luminophors embedded in porous alumina matrixes are discussing. The optical properties of the luminophors in a matrix differ greatly from their properties in usual crystalline state or in a solution and they depend on the concentration of luminophors molecules of up to 10-2 mol/l. Successful experiments on filling of pores with organic luminophors and the investigation of their luminescent and optical properties were carried out.

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유기금속의 첨가에 따른 전자빔 레지스트 특성조사 (A study on the characteristics of electron beam resist with addition of organometallic monomer)

  • 박종관;이덕출;우호환;이종태;김보열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 추계학술대회 논문집
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    • pp.152-155
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    • 1994
  • The purpose of this paper is to develope an electron beam resist by the plasma polymerization. Plasma co-polymerized resist was prepared using an interelectrode gas-flow-type reactor. And then delineated pattern in the resist was developed with gas flow type reactor using Ar and O$_2$ gas as etching gas. We study about the effects of discharge power and mixing rate of the copolymerized thin film. The characteristics of molecular structure of thin film was investigated by FT-lR, DSC and GPC, and then was discussed in relation to its quality as a resist.

Low Hysteresis Organic Thin Film Transistors with Modified Photocrosslinkable Poly (4-vinylphenol)

  • Kim, Doo-Hyun;Kim, Hyoung-Jin;Kim, Byung-Uk;Kim, We-Yong;Kim, Ho-Jin;Hong, Mun-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.563-565
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    • 2009
  • We introduce the new modification approaches of photocrosslinkable poly (4-vinylphenol) (PVP) for low hysteresis organic thin film transistors (OTFTs). The dielectric layers were composed of different PVP resin, low molecular melamine, and halogen free photo-initiator. The low hysteresis OTFT from one of the organic gate dielectrics has been realized. The electrical performance of low hysteresis OTFT with photocrosslinkable PVP exhibited a field-effect mobility of 0.2 cm2/Vs, a threshold voltage of - 0.04V, hysteresis of 0.4V.

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유기 TFT 재작을 위한 $\alpha$&$-67 박막의 접촉 및 전기적 특성 (Contact and Electrical Characteristics of $\alpha$-67 Thin-Film for the fabrication of organic Thin-Film Transistor)

  • 오세운;김대엽;최종선;박미경;김영관;신동명
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.313-316
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    • 1998
  • Conjugated oligomers have been already used as active layers in field effect transistors, photodiodes and electroluminescent devices. Particularly thiophene oligomers such $\alpha$ -sexithiophene($\alpha$-6T) attract great interest for its prospective app1ications in large-area flexible displays. In this study, we investigated the contact properties between the organic semiconductor $\alpha$-6T and metals such as Au(Gold), Ag(Silver), Cr(Chromium), Al(Aluminum), Cr(Chromium). Using the Transmission Line Model(TLM) method, specific contact resistances of the metal lines in contact with the $\alpha$-6T were determined. From the current-voltage characteristics, electrical conductivity of the $\alpha$-6T films is found.

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Early Stage of Pentacene Growth on the CYTOP Doped Graphene Surface

  • Yang, Mi-Hyun;Lee, Kyoung-Jae;Kumar, Yogesh;Ihm, Kyuwook;Kang, Tai-Hee;Ahn, Joung-Real
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.142.1-142.1
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    • 2013
  • The patterning and doping technique enables graphene to replace the metal electrode as a charge injection layer in the pentacene based thin film transistor. However, it is known that pentacene molecules form lying-down coordination on the graphene surface. Pentacene thin film showed that the highly occupied molecular orbital is 0.2~0.4 eV lower in the standing up coordination than in the lying down coordination. Here, we report the formation of standing-up coordination and lowered HOMO level of the pentacene layer grown on the graphene layer doped with CYTOP.

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Langmuir-Blodgett법을 이용한 (N-docosyl quinolinium)-TCNQ(1:2) 착물의 초박막 제작 (Fabrication of Ultra Thin Films with (N-docosyl quinolinium)-TCNQ(1:2) complex by the Langmuir -Blodgett Technique)

  • 정순욱;정회걸
    • 한국재료학회지
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    • 제9권12호
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    • pp.1229-1233
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    • 1999
  • 본 연구에서는 (N-docosyl quinolinium)-TCNQ (1:2) 착물의 LB초박막을 제작하였다. LB막의 누적을 위한 최적조건을 구하기 위하여 subphase 온도, barrier 압축속도 및 분산량을 변화시키면서 표면압-면적(${\pi}$-A) 등온선 특성을 측정하였다. 그리고 전이비, UV-vis의 최대 흡광도, 정전용량 및 두께를 측정하여 LB막의 누적상태를 확인하였다. 그 결과 분자수준으로 잘 제어된 양호한 LB막이 제작되었음을 알 수 있었다..

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UV 조사에 의한 메로시아닌 색소 LB박막의 J-aggregation 특성 (J-aggregation Property of Merocyanine Dye LB Thin Film by UV Irradiation)

  • 양창헌;이지윤;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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    • pp.123-124
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    • 2008
  • We investigate characteristics of J-aggregation as take advantage of LB technic. In order to confirm the applications possible for the molecular electronic device, the morphological properties of merocyanine dye were investigated by AFM. $\pi$-A curves investigated the surface pressure of the LB film from a liquid to a solid state ranged between 90 and 100 mN/m. We observed aggregation and it's characteristics by using visible reflection spectroscopy. This paper focuses on results obtained in mercocyanide dye. When LB films of merocyanine dye are mixed with arachidic acid, J-aggregate formation is exhibited. J-aggregate formation has been serving as typical systems in revealing the physical and structural aspects of nano-sized molecular aggregates constructed as muiltilayers.

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