• Title/Summary/Keyword: Molecular structures

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Rabrication of 4.7 V Operation GaAs power MESFETs and its characteristics at 900 MHz (900MHz 대역 4.7 V 동작 전력소자 제작 및 특성)

  • 이종람;김해천;문재경;권오승;이해권;황인덕;박형무
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.10
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    • pp.71-78
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    • 1994
  • We have developed GaAs power metal semiconductor field effect transistors (MESFETs) for 4.7V operation under 900 MHz using a low-high deped structures grown by molecular beam epitaxy (MBE). The fabricted MESFETs with a gate widty of 7.5 mm and a gate length of 1.0.mu.m show a saturated drain current (Idss) of 1.7A and an uniform transconductance (Gm) of around 600mS, for gate bias ranged from -2.4 V to 0.5 V. The gate-drain breakdown voltage is measured to be higher than 25 V. The measured rf characteristics of the MESFETs at a frequency of 900 MHz are the output power of 31.4 dBm and the power added efficiency of 63% at a drain bias of 4.7 V.

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Applications of Tandem Mass Spectrometry in the Structure Determination of Permethylated Sialic Acid-containing Oligosaccharides

  • Yoo, Eun-Sun;Yoon, In-Mo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1347-1353
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    • 2005
  • Sets of sialic acid-containing trisaccharides having different internal and terminal linkages have been synthesized to develop a sensitive method for analysis of the reducing terminal linkage positions. The trisaccharides, sialyl($\alpha$ 2-3)Gal($\beta$ 1-3)GalNAc and sialyl($\alpha$ 2-3)Gal($\beta$ 1-X)GlcNAc where X=3, 4 and 6, were synthesized and examined using electrospray ionization (ESI)-collision induced dissociation (CID) tandem mass spectrometry (MS/MS). The compounds chosen for this study are related to terminal groups likely to be found on polylactosamine-like glycoproteins and glycolipids which occur on the surface of mammalian cells. The purpose of this study is to develop tandem mass spectrometral methods to determine detailed carbohydrate structures on permethylated or partially methylated oligosaccharides for future applications on biologically active glycoconjugates and to exploit a faster method of synthesizing a series of structural isomeric oligosaccharides to be used for further mass spectrometry and instrumental analysis.

DFT Study for p-tert-Butylcalix[4]arene Crown Ether Bridged at the Lower Rim with Pyridyl Unit Complexed with Potassium Ion

  • Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2310-2314
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    • 2007
  • Stable molecular conformations were calculated for the p-tert-butylcalix[4]arene crown ether bridged at the lower rim with pyridyl unit (1) in the various conformers and their potassium-ion complexes. The structures of three distinct conformations have been optimized using DFT B3LYP/6-31G(d,p) method. Relative stability of free host 1 is in following order: cone (most stable) > partial-cone > 1,3-alternate conformer. For two different kinds of complexation mode, the potassium cation in the crown-ether moiety (cr) has much better complexation efficiency than in the benzene-rings (bz) pocket for all three kinds of conformation of host molecule 1. The relative stability of complex (1+K+) in the cr-binding mode is in following order: partial-cone (most stable) ~ cone > 1,3-alternate conformer.

RECENT PROGRESS IN HIGH-MASS STAR-FORMATION STUDIES WITH ALMA

  • Hirota, Tomoya
    • Publications of The Korean Astronomical Society
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    • v.33 no.2
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    • pp.21-30
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    • 2018
  • Formation processes of high-mass stars have been long-standing issues in astronomy and astrophysics. This is mainly because of major difficulties in observational studies such as a smaller number of high-mass young stellar objects (YSOs), larger distances, and more complex structures in young high-mass clusters compared with nearby low-mass isolated star-forming regions (SFRs), and extremely large opacity of interstellar dust except for centimeter to submillimeter wavelengths. High resolution and high sensitivity observations with Atacama Large Millimeter/Submillimeter Array (ALMA) at millimeter/submillimeter wavelengths will overcome these observational difficulties even for statistical studies with increasing number of high-mass YSO samples. This review will summarize recent progresses in high-mass star-formation studies with ALMA such as clumps and filaments in giant molecular cloud complexes and infrared dark clouds (IRDCs), protostellar disks and outflows in dense cores, chemistry, masers, and accretion bursts in high-mass SFRs.

Synthesis and Properties of Banana-Shaped Mesogen Containing Isomeric Naphthalene Central Unit

  • Cui, Xin;Choi, E-Joon;Kim, Young-Chul;Paek, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.850-853
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    • 2006
  • Four bent-core compounds were synthesized introducing ester linking group into mesogenic unit, varying the central unit with 1,6-, 1,7-, 2,3-, and 2,7-naphthylenes, and placing the dodecyloxy group in the terminal flexible unit. The structures of four compounds were identified by FT-IR and $^1H$ NMR spectroscopy, and the results were in accordance with expected molecular formula. The mesomorphic properties were investigated by differential scanning calorimetry and polarizing optical microscopy.

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The prospects of highly power efficient OLEDs using molecular dopants for display and lighting applications

  • Werner, Ansgar;Blochwitz-Nimoth, Jan;Birnstock, Jan;Wellmann, Philipp;Romainczyk, Tilmann;Lux, Andrea;Limmert, Michael;Zeika, Olaf
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1692-1696
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    • 2006
  • Dopant and host molecules for charge transport layer in OLED have been developed. They enable implementation of the PIN OLED technology in mass production. We review the status of PIN OLED with main focus on top-emission structures and operation stability at elevated temperatures. A green phosphorescent top-emission device with 2.5 V operating voltage and 90 lm/W at 1000 $cd/m^2$ is presented. For a red top-emission device, lifetime exceeding 100,000 h at 500 $cd/m^2$ initial brightness is reported. Operational stability at $80^{\circ}C$ has been investigated. A lifetime of 17,000 h at 500 $cd/m^2$ has been achieved. Finally, we comment on further reduction of the operating voltage in OLED.

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A qualitative study of photomemory characteristics of the LB monolayer films of merocyanine dye (메로시아닌 색소 LB 단분자막의 광메모리 특성에 관한 정성적 연구)

  • 박태곤;권영수;강도열
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.44 no.7
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    • pp.889-894
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    • 1995
  • The structural changes of the merocyanine monolayer LB (Langmuir Blodgett) films were investigated. These changes were compared with the typical changes of the molecular structures of merocyanine solutions. The structural changes of quinoid/benzenoid were attained by exposure to atmosphere gases (HCl gas, N $H_{3}$ gas). The photoisomerization was not observed for the monolayer LB film due to their state of $M_{trans}$. But we could obtain the cis/trans photoisomerization characteristics reversibly, after the films were changed to M $H^{+}$$_{trans}$ structure by exposure to HCl gas. We also found that the cis/trans photoisomerization of the LB monolayer films show the memory characteristics.s.

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Report on the Current Status of EAO/JCMT

  • Dempsey, Jessica;Ho, Paul
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.58.3-59
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    • 2017
  • The JCMT is now in its third year of operations under EAO management. During this past year, we continued with calls for regular PI programs as well as the second call for Large Programs. The performance of SCUBA-2 has been improved by replacing internal optical filters. The 230GHz Receiver A is in the process of being replaced by a new closed-cycle system. The SCUBA-2 polarimeter, POL-2, commissioned during the past year, has been working very well in measuring the magnetic field structures in molecular clouds. The JCMT successfully participated in the Event Horizon Telescope experiment during April 2017, which utilized the phased-up ALMA for the first time. The first round of Large Programs are nearing completion, with first publications beginning to be published. The JCMT continues to welcome inputs from the community, and the next users meeting will be held in Seoul in January 2018.

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Characterization of Peptide Deformylase2 from B. cereus

  • Park, Joon-Kyu;Kim, Kook-Han;Moon, Jin-Ho;Kim, Eunice Eun-Kyeong
    • BMB Reports
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    • v.40 no.6
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    • pp.1050-1057
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    • 2007
  • Peptide deformylase (PDF) is a metalloenzyme that removes the N-terminal formyl groups from newly synthesized proteins. It is essential for bacterial survival, and is therefore-considered as a potential target for antimicrobial chemotherapy. However, some bacteria including medically relevant pathogens possess two or more def-like genes. Here we have examined two PDFs from Bacillus cereus. The two share only 32% sequence identity and the crystal structures show overall similarity with PDF2 having a longer C-terminus. However, there are differences at the two active sites, and these differences appear to contribute to the activity difference seen between the two. BcPDF2 is found as a dimer in the crystal form with two additional actinonin bound at that interface.

The role of lipid binding for the targeting of synaptic proteins into synaptic vesicles

  • Jang, Deok-Jin;Park, Soo-Won;Kaang, Bong-Kiun
    • BMB Reports
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    • v.42 no.1
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    • pp.1-5
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    • 2009
  • Synaptic vesicles (SVs) are key structures for synaptic transmission in neurons. Numerous membrane-associated proteins are sorted from the Golgi complex to the axon and the presynaptic terminal. Protein-protein and protein-lipid interactions are involved with SV targeting in neurons. Interestingly, many SV proteins have lipid binding capability, primarily with either cholesterol or phosphoinositides (PIs). As examples, the major SV protein synaptophysin can bind to cholesterol, a major lipid component in SVs, while several other SV proteins, including synaptotagmin, can bind to PIs. Thus, lipid-protein binding plays a key role for the SV targeting of synaptic proteins. In addition, numerous SV proteins can be palmitoylated. Palmitoylation is thought to be another synaptic targeting signal. Here, we briefly describe the relationship between lipid binding and SV targeting.