• 제목/요약/키워드: Molecular Weight Properties

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Mechanical Properties of Rice Noodles When Adding Cellulose Ethers (셀룰로오스 에테르를 첨가한 쌀면의 기계적 물성)

  • Um, In Chul;Yoo, Young Jin
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.3
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    • pp.177-181
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    • 2013
  • This study examined the effect of the molecular weight, substitution degree, and substitution type of cellulose ether on the mechanical properties of dried rice noodles. When increasing the molecular weight of the hydroxypropyl methylcellulose (HPMC), the bending strength of the dried rice noodles also increased. However, the bending strength of the rice noodles with added HPMCs was still lower than that of the wheat noodles. Meanwhile, the bending elongation of the dried rice noodles was higher than that of the wheat noodles and was increased when decreasing the molecular weight of the HPMC. In conclusion, the bending strength and elongation of dried rice noodles is affected by the substitution degree and type of cellulose ether.

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Monitoring of Changes in Molecular Weight Distribution and Fluorescence Properties of Dissolved Matter (DOM) in Water Treatment Processes (정수처리공정 중 자연유기물질의 분자량 분포 및 형광특성 변화 모니터링)

  • Park, Min-Hye;Hur, Jin
    • Journal of Korean Society on Water Environment
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    • v.23 no.6
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    • pp.843-849
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    • 2007
  • Monitoring of NOM characteristics is important for improving removal efficiency of natural organic matter (NOM) in water treatment processes. In this study, several NOM characteristics, which include specific UV absorbance (SUVA), total carbonate content, molecular weight distribution, and fluorescence properties, were measured using samples collected from a pilot-scale water treatment plant consisting of coagulation/flocculation (C/F), filtration, ozonation and granular activated carbon (GAC) processes. The highest removal of NOM was observed in C/F and filtration processes as demonstrated by the reduction of dissolved organic carbon (DOC) by 25% and 21%, respectively. Despite nearly no change in DOC, however, the lowest SUVA value and the highest total carbohydrate content were observed in the sample from ozonation process. This indicates that non-degradable aromatic compounds become depleted and biodegradable organic compounds are enriched during the process. Comparison of synchronous fluorescence spectra of the samples showed that ozoation process increased protein-like fluorescence while it decreased fulvic-like and terrestrial humic-like fluorescence. Consistently, a slight peak of protein-like fluorescence was observed in the sample from ozonation process. The greatest change in molecular weight distributions of the samples was observed in C/F process. Comparison of size exclusion chromatogram of the samples revealed that NOM fractions with the molecular weight greater than 2000 Da were reduced by over 90% after C/F process. SUVA values and total carbohydrate content of the samples were well correlated with a ratio of protein-like fluorescence and terrestrial humic-like fluorescence intensities with the correlation coefficients of 0.99 and 0.91, respectively. This suggests that synchronous fluorescence properties of NOM could be used as useful tolls for monitoring changes of some NOM characteristics during water treatment processes.

The Effect of Molecular Weight and the Linear Velocity of Drum Surface on the Properties of Electrospun Poly(ethylene terephthalate) Nonwovens

  • Kim, Kwan-Woo;Lee, Keun-Hyung;Khil, Myung-Seob;Ho, Yo-Seung;Kim, Hak-Yong
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.122-127
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    • 2004
  • In this study, we evaluated the effect of the molecular weight of the polymer on electrospun poly(ethylene terephthalate) (PET) nonwovens, and their mechanical properties as a function of the linear velocity of drum surface. Polymer solutions and electrospun PET nonwovens were characterized by means of viscometer, tensiometer, scanning electron microscope(SEM), wide angle X-ray diffraction measurement (WAXD) and universal testing machine (UTM). By keeping the uniform solution viscosity, regardless of molecular weight differences, electrospun PET nonwovens with similar average diameter could be obtained. In addition, the mechanical properties of the electrospun PET nonwovens were strongly dependent on the linear velocity of drum surface. From the results of the WAXD scan, it was found that the polymer took on a particular molecular orientation when the linear velocity of drum surface was increased. The peaks became more definite and apparent, evolving from an amorphous pattern at 0 m/min to peaks and signifying the presence of crystallinity at 45 m/min.

Partial purification and some properties of Guanosine Triphosphate Cyclohydrolase from Pseudomonas putida : GTP cyclohydrolase from pseudomonas (Pseudomonas putida에서 부분정제한 Guanosine Triphosphate Cyclohydrolase 의 특성에 관한 연구)

  • 김완기;임정빈
    • Korean Journal of Microbiology
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    • v.20 no.4
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    • pp.201-209
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    • 1982
  • An enzyme, named GTP cyclohydorlase, that catalizes the hydrolytic removal of carbon No.S of GTP has been partially purified from extracts of Pseudomonas putida (IAM 1506). The enzyme exists in two molecuar weight forms : a high molecular weight form (150,000) and a low molecular weight from (40,000). The high molecular weight form has been purified 25-fold. Some of the properties of the enzyme are as follows : It functions optimally at pH8.0, and at $52^{\circ}C$. The Km value for GTP is $20{\mu}M$. Divalent cations $(Cd^{2+}\;and\;Hg^{2+})$ 2+/) at a concentration of 5mM inhibit completely the enzyme activity. No metal ion including $Mg^{2+}$ is needed for the catalysis. The enzyme is heat labile ; its half at $57^{\circ}C$ is 1.5 min. Of a number of nucleotides tested, only GDP was used to any extent as substrbte in place of GTP. One of the products of the enzyme is determined to be a dihydro-neopterin compound.

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The efect of freeness and paper physical properties treated with high and low molecular weight cellulase in the different surface pore sized fibers (Cellulase의 분자량과 섬유소의 표면공극 상이성이 여수도 및 종이의 강도적 특성에 미치는 영향)

  • 김병현;신종순;강영립;어영호
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.141-155
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    • 2000
  • To examine how the difference of molecular weight distribution of cellulase influenced the beating process according to surface pore size of the fiber, high molecular weight enzyme and low one were applied to soft wood pulp, hard wood pulp, cotton linter pulp. Some enzymes with the distribution of low molecular weight penetrated into cellulose in the proportion of surface pore size and the results were negative as like : the low viscosity, decrease of refining Yield, decrease of fine fibers content and so on. But in cotton linter pulp in the small surface area, the fiber softness was increased and it had a positive result that the paper intensity was high. Other enzymes with the distribution of high molecular weight had an enzyme reaction on the most surfaces of cellulose. They were effective in eliminating the fuzz of hydrophile fine fibers and the freeness was increased.

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Effects of Culture Conditions on the Molecular Weight of Poly-hydroxybutyric acid (PH B) Produced by Alcaligenes sp. K-912

  • Yeom, Sung-Ho;Yoo, Young-Je
    • Journal of Microbiology and Biotechnology
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    • v.4 no.3
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    • pp.210-214
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    • 1994
  • The molecular weight of poly-hydroxybutyric acid (PHB) produced by Alcaligenes sp. K-912 is an important parameter characterizing the physical properties of the polymer. The effects of temperature and the levels of glucose, ammonium, phosphate and amino acids on the molecular weight of PHB were investigated. Molecular weight of PHB by temperature varied in the range of 380,000 to 550,000, 400,000 to 600,000 by glucose, 300,000 to 380,000 by phosphate, 400,000 to 1,000,000 by amino acids, respectively under the experimental conditions.

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Effect of PVA Polymerization on Synthesis of YAG:Ce3+ Phosphor Powders Prepared by a Solid-liquid Hybrid Route (PVA 중합도가 고상-액상 혼합 방식에 의한 YAG:Ce3+ 형광체 분말 합성에 미치는 영향)

  • Kim, A-Reum;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.424-429
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    • 2014
  • YAG:$Ce^{3+}$ phosphor powders were synthesized using $Al(OH)_3$ seeds by means of a PVA-polymer-solution route. Various types of PVA with different molecular weights (different polymerization) were used. All dried precursor gels were calcined at $500^{\circ}C$ and then heated at $1500^{\circ}C$ in a mix of nitrogen and hydrogen gases. The final powders were characterized via XRD, SEM, PSA, PL, and PKG analyses. The phosphor properties and morphologies of the synthesized powders were dependent on the PVA type. As the molecular weight of the PVA was increased, the particle size gradually decreased with agglomeration, and the luminous intensity of the phosphor increased. However, the phosphor powder prepared from the PVA exhibiting very high molecular weight, showed a 531 nm (blue) shift from the 541 nm (yellow) wavelength of the YAG:$Ce^{3+}$ phosphor. Finally, the synthesized YAG:$Ce^{3+}$ phosphor powder prepared from the PVA with 89,000 - 98,000 molecular weight showed phosphor properties similar to those of a commercial phosphor powder, but without a post-treatment process.

Effect of Polyethylene Glycol Molecular Weight and NCO Index on Properties of the Hydrophilic Reactive Hotmelt Polyurethane Adhesives (Polyethylene Glycol의 분자량 및 NCO index의 변화에 따른 Hydrophilic Reactive Hotmelt Polyurethane의 물성 변화)

  • Han, Young Chul;Kim, Dack Han;Oh, Kyung Seok;Shin, Hyeon Jeong;Yang, Jeong Han;Jeong, Han Mo
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.90-97
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    • 2018
  • Hydrophilic reactive hot-melt polyurethane adhesive(HRHA) using a hydrophilic polyol having different molecular weight and NCO index was synthesized. This HRHA was synthesized using Polyethylene glycol(PEG) as a hydrophilic polyol, Polypropylene glycol(PPG) and Polycaprolactone diol(PCL) as hydrophobic polyols, and Methylene diphenyl diisocyanate(MDI) as an isocyanate. The changes in IR spectrum, viscosity and thermal properties of HRHA with different PEG molecular weights and NCO index were investigated, and the tensile strength and elongation of the HRHA casting film and the peel strength, moisture permeability and water pressure of the HRHA coated fabric were confirmed. In this experiment, as the molecular weight of PEG and NCO index increased, the adhesive strength, tensile strength, elongation and moisture permeability was increased but viscosity and Tg was decreased.

Rejection Properties of Aromatic Pesticides by a Hollow Fiber NF Membrane (중공사 나노여과막을 이용한 방향족 농약의 배제 특성)

  • Jung, Yong-Jun;Kiso, Yoshiaki;Park, Soon-Gil;Kim, Jong-Yong;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.296-300
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    • 2004
  • The rejection properties of 6 aromatic pesticides were evaluated by a continuous flow system equipped with a hollow fiber NF membrane. Different from the separation experiment of batch cell, the rejection and the removal could be calculated exactly because the concentration of feed, permeate and retentate was separately obtained. The lowest and the highest rejection were found in carbaryl(54.8%) and methoxychlor(99.2%), respectively, and the removals were always shown higher than rejections. This may be caused by some reasons such as the solute adsorption on the membrane, the variation of feed concentration. Although molecular weight, molecular width regarded as solute characteristics and log P(n-octanol/water partition coefficient) as hydrophobicity could be applied to explain the rejection property, these factors should be considered together for better analysis. According to the higher relationship between log B(solute permeability) and molecular weight, it was revealed that the solute separation with this membrane was influenced more by molecular weight.

Synthesis of Various Molecular Weight Polyaniline by Controlled Nucleation Site Number (핵심성장자리 수 조절을 통한 다양한 분자량을 갖는 폴리아닐린 합성)

  • Hong, Jang Hoo;Jang, Kwan Sik;Moon, Woo Yeon
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.504-508
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    • 2006
  • Molecular weight of polyaniline is controlled in the range of oligomer to low molecular weight by controlling the ratio of aniline dimer (p-aminodiphenylamine) to monomer. Aniline dimers act as nucleation sites in chain growth during the polymerization of aniline. The molecular weights of polyanilines are estimated by GPS and relative viscosity measurement. The physical and chemical properties of polyanilines with various molecular weights are studied by UV-Vis, FT-IR, and electrical conductivity measurements.