• Title/Summary/Keyword: Molecular Characteristics

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A study on properties optical transparency effect and Hysteresis of transparent PLZT (투광성 PLZT의 HYSTERESIS와 광투과 효과에 과한 연구)

  • Lee, H.G.;Kim, S.Y.;Song, J.T.
    • Proceedings of the KIEE Conference
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    • 1993.07a
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    • pp.21-23
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    • 1993
  • In this study PLZT was selected which has the excellent quadratic electro-optic property and slim-loop. It was fabricated by the methods of vacuum hot-pressing and sintering. The electrode of color filter was evaporated using the interdigital type masks. Through XRD have we investigated the molecular structure composition formular. Hysteresis and transmission characteristics were measured, The transmission of RGB was envestigated. We are going to study the correlation of coercive field and the nontransmited field.

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Comparative Studies on Morphology of Low Temperature Ar-Plasma-treated Polymer Surfaces (알곤저온플라즈마처리된 고분자표면의 모폴로지에 대한 비교연구)

  • Seo Eun-Deock
    • Textile Coloration and Finishing
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    • v.16 no.5
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    • pp.35-41
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    • 2004
  • Poly(ethylene terephthalate), polyimide(Kapton), and polypropylene surfaces were modified with argon low temperature plasma by RF glow discharge at 240m Torr, 40W to investigate the surface morphological changes due to the plasma treatment using atomic force microscopy(AFM). Analysis of the AFM images and Ra(average roughness) revealed that the plasma treatment resulted in significant ablation on the surfaces. The morphological changes and surface roughness, however, were different depending on material characteristics such as heat stability, presence of amorphous region, swelling phenomenon, and molecular structure of repeating unit. It was assumed that polypropylene due to its tertiary hydrogen was ablated easily compared to poly(ethylene terephthalate), and that polyimide was more resistant to the ablation than PET due to rigid skeleton of imide and stable phenyl ring structure.

Characterization of a Thermostable Protease from Thermophilic Bacillus amyloliquefaciens NS 15-4 (고온성 Bacillus amyloliquefaciens NS 15-4가 생산하는 내열성 Protease의 특성)

  • Kim, Hyung-Kwoun;Kim, Kee-Hyun;Lee, Jung-Kee;Kim, Young-Ok;Nam, Hee-Sop;Oh, Tae Kwang
    • Microbiology and Biotechnology Letters
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    • v.23 no.3
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    • pp.322-328
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    • 1995
  • A thermophilic bacteria showing proteolytic activity against defatted soybean was isolated from soil. It was identified as Bacillus amyloliquefaciens based on its morphological and physiological characteristics. The Bacillus amyloliquefaciens NS 15-4 was cultivated at 50$\circ$C by rotary shaking in a medium containing defatted soybean. An extracellular protease from this strain was purified to homogeneity by ammonium sulfate precipitation, ion exchange, and hydrophobic interaction chromatographies. The molecular weight of the enzyme was estimated to be approximately 30,000 by SDS-PAGE and the N-terminal amino acid sequence of the enzyme was turned out to be AQSVPYGISQIKAPA. The optimum temperature and pH for the enzyme reaction were 60$\circ$C and 11, respectively, and its thermostability was increased by the addition of calcium ion. The enzyme was inactivated by phenylmethylsulfonylfluoride, suggesting it be a serine protease. Comparing with other commercial proteases, the enzyme showed relatively high proteolytic activity against defatted soybean, a water-insoluble protein substrate.

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FT-IR and XRD Analyses of Commercial Methionine-Mineral Chelates

  • Han, Jae-Hong;Chi, Yong-Seok;Shin, Bok-Kyu;Kim, Sang-Kyu;Paik, In-Kee
    • Journal of Applied Biological Chemistry
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    • v.49 no.1
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    • pp.8-10
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    • 2006
  • Compositions of methionine-metal chelates have been investigated by FT-IR and XRD studies to elucidate their molecular structures. It was concluded that Copamin and Zincamin contain a high percentage of crystalline products, presumably 2:1 Methionine-Cu or Zn complexes. On the contrary, FT-IR and XRD spectra of Ferramin didn't show any characteristics of the chelate and it was concluded to contain major components of starting $FeSO_4$ and methionine without chelation.

A Study on Characteristics of Surface Modified Polyimide Film by Wet Process (습식 표면개질 처리된 폴리이미드 필름 표면의 특성에 관한 연구)

  • Koo, S.B.;Lee, H.K.
    • Journal of Surface Science and Engineering
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    • v.39 no.4
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    • pp.166-172
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    • 2006
  • Metallized Polyimide films are extensively used as base materials in microelectronics, optical and automotive applications. However it is difficult to deposit metals on those because of their structural stabilities. In this work, polyimide films are modified by a wet process with alkalinemetalhydroxide and additives to introduce functional groups. The surface molecular structures of polyimide are investigated using X-ray photoelectron spectroscopy(XPS), fourier transform infrared reflection spectroscopy(FTIR-ATR), atomic force micro-scopic(AFM). XPS spectra and FTIR spectra show that the surface structure of polyimide is converted into potassium polyamate. AFM image and AFM cross-sectional analyses reveal the increased roughness on the modified surface of polyimide films. As a result, it is shown that the adhesion strength between polyimide surface and electroless nickel layer is increased by the nano-anchoring effect.

A study on properties optical transparency effect and Hysteresis of transparent PLZT (투광성 PLZT의 HYSTERESIS와 광투과 효과에 관한 연구)

  • Lee, H.G.;Kim, S.Y.;Song, J.T.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.555-557
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    • 1993
  • In this study PLZT was selected which has the excel lent quadratic electro-optic property and slim-loop. It was fabricated by the methods of vacuum hot-pressing and sintering. The electrode of color filter was evaporated using the interdigital type masks. Through XRD have we investigated the molecular structure composition formular. Hysteresis and transmission characteristics were measured. The transmission of RGB was envestigated. We are going to study the correlation of coercive field and the nontransmited field.

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Electrical Characteristics of Self-Assembled Organic Thin Films Using Ultra-High Vacuum Scanning Tunneling Microscopy (UHV STM을 이용한 유기 초박막의 전기적 특성 연구)

  • Kim, Seung-Un;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.108-111
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    • 2003
  • Currently, molecular devices are reported utilizing active self-assembled monolayers containing the nitro group as the active component, which has active redox centers[1]. We confirm the electrical properties of 4,4-di(ethynylphenyl)-2'-nitro-1-benzenethiolate. To deposit the SAM layer onto gold electrode, we transfer the prefabricated Au(111) substrates into a 1mM self-assembly molecules in THF solution. Au(111) substrates were prepared by ion beam sputtering method of gold onto the silicon wafer. As a result, we measured current-voltage curve using ultra high vacuum scanning tunneling microscopy (UHV STM), I-V curve also clearly shows several current peaks between the negative bias region (-0.3958V) and the positive bias region (0.4658V), respectively.

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Characteristics of Electrical Conduction Mechanism of OLED with Various Temperature (유기 발광 다이오드의 온도에 따른 전도특성)

  • Lee, Dong-Gyu;Kim, Tae-Wan;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.197-200
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    • 2005
  • We have studied conduction mechanism that is interpreted in terms of space charge limited current (SCLC) region and tunneling region. The OLEDs are based on the molecular compounds, N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) as a hole transport, tris (8-hydroxyquinolinoline) aluminum(III) $(Alq_3)$ as an electron injection and transport and emitting layer. We manufactured reference structure that has in $ITO/TPD/Alq_3/Al$. Buffer layer effects were compared to reference structure. And we have analyzed out electrical conduction mechanism in $ITO/Alq_3/Al$ device with various temperature.

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Studies on Properties of Polyaniline-Dodecylbenzene Sulfonic Acid Composite Films Synthesized Using Different Oxidants

  • Basavaraja, C.;Pierson, R.;Huh, Do-Sung;Venkataraman, A.;Basavaraja, S.
    • Macromolecular Research
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    • v.17 no.8
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    • pp.609-615
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    • 2009
  • Two types of nano composite were obtained by in situ chemical method in polyaniline (PANI)/dodecyl-benzenesulfonic acid (DBSA) system depending on the use of either ammonium persulfate (APS) or ferric chloride ($FeCl_3$) as the oxidant. In order to study the difference of the two composites in the surface characteristics, thermal stability, and electric properties, the composite films were studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and temperature dependent DC electrical conductivity. The results revealed a large difference in the surface morphology, thermal stability, and the microstructure properties between the two composites, and these differences were considered responsible for the molecular order and conductivity.

Molecular and Epidemiological Characteristics of Infectious Bronchitis Virus Isolated in Korea (닭 전염성 기관지염 바이러스 한국분리주의 분자생물학적, 역학적 특성)

  • 송창선;이윤정
    • Korean Journal of Poultry Science
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    • v.27 no.2
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    • pp.91-98
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    • 2000
  • Phylogenetic tree constructed from the nucleotide sequences of the S1 gene showed that the 15 Korean strains of infectious bronchitis virus(IBV) examined were classified into 2 genetically distinct groups, except one respiratory strain, RB86, which was clustered with Massachusetts group. All the 5 respiratory strains belonged to Korean group I and the rest 9 nephropathogenic strains belonged to Korean group II according to the analysis, based on S1 gene sequences. Like previous classifications corresponded with the geographic origin, Korean stains were discriminated from geographically distinct reference strains of IBV. The nephropathogenic strains within Korean group IIsharing 96% homology were continuously isolated since 1990, and seemed to be genetically stable. Whereas the respiratory strains within Korean group Ⅰ sharing 88% homology were sporadically isolate since 1986m and seemed to be genetically unstable. Because we found putative accumulated point mutation as well as recombination events in Korean group Ⅰ, we discussed why genetic variations have often occurred in respiratory strains rather than nephropathognic strains.

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